Modulating the sensing properties of graphene through an eco-friendly metal-decoration process

Abstract Herein we investigate the effect of graphene decoration with metal nanoparticles, namely Ag and Pd, starting from pristine graphene (GR). Decoration is directly made on graphene obtained by Liquid Phase Exfoliation of natural graphite in eco-friendly solvents. The nanoparticles are synthesized in situ via chemical reduction from metal salts promoted by microwave treatment, resulting in metal nanoparticles directly stuck onto the pristine graphene surface. Sensing layers based on graphene and metal decorated graphenes were exposed to hydrogen, nitrogen dioxide and ammonia. Pristine graphene showed a marked specificity towards NO 2 gas. Palladium nanoparticles enhanced graphene response towards hydrogen, while devices based on graphene/silver nanoparticles were highly specific towards ammonia detection. This eco-friendly and straightforward preparation method of graphene and graphene hybrids demonstrates an effective modulation of the sensing properties of graphene with respect to sensitivity and selectivity.

[1]  G. Shi,et al.  Graphene-based gas sensors , 2013 .

[2]  Ahalapitiya H. Jayatissa,et al.  Ammonia gas sensing behavior of graphene surface decorated with gold nanoparticles , 2012 .

[3]  Anran Liu,et al.  High‐Performance NO2 Sensors Based on Chemically Modified Graphene , 2013, Advanced materials.

[4]  T. Paronyan,et al.  Sub-ppt gas detection with pristine graphene , 2012 .

[5]  Andre K. Geim,et al.  Raman spectrum of graphene and graphene layers. , 2006, Physical review letters.

[6]  Ettore Massera,et al.  A study on the physicochemical properties of hydroalcoholic solutions to improve the direct exfoliation of natural graphite down to few-layers graphene , 2015 .

[7]  A. M. van der Zande,et al.  Impermeable atomic membranes from graphene sheets. , 2008, Nano letters.

[8]  Abdulazeez T. Lawal.  Synthesis and utilisation of graphene for fabrication of electrochemical sensors. , 2015, Talanta.

[9]  James Hone,et al.  Graphene nanoelectromechanical systems , 2013, Proceedings of the IEEE.

[10]  Young-Min Choi,et al.  The effect of metal cluster coatings on carbon nanotubes , 2006 .

[11]  Yiu-Wing Mai,et al.  Reduction of silver nanoparticles onto graphene oxide nanosheets with N,N-dimethylformamide and SERS activities of GO/Ag composites , 2011 .

[12]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.

[13]  Anita Lloyd Spetz,et al.  Schottky Junction Methane Sensors Using Electrochemically Grown Nanocrystalline-Nanoporous ZnO Thin Films , 2009, J. Sensors.

[14]  Nikhil Koratkar,et al.  High sensitivity detection of NO2 and NH3 in air using chemical vapor deposition grown graphene , 2012 .

[15]  G. Ramanath,et al.  Microwave-Assisted Single-Step Functionalization and in Situ Derivatization of Carbon Nanotubes with Gold Nanoparticles , 2006 .

[16]  D. Jia,et al.  Noncovalently functionalized pristine graphene/metal nanoparticle hybrid for conductive composites , 2014 .

[17]  E. Massera,et al.  A simple method to recover the graphene-based chemi-resistor signal , 2014 .

[18]  M. Weinert,et al.  Fast and selective room-temperature ammonia sensors using silver nanocrystal-functionalized carbon nanotubes. , 2012, ACS applied materials & interfaces.

[19]  Ulrich Simon,et al.  Metal and metal oxide nanoparticles in chemiresistors: does the nanoscale matter? , 2006, Small.

[20]  Klaus Müllen,et al.  Fast response and recovery of hydrogen sensing in Pd–Pt nanoparticle–graphene composite layers , 2011, Nanotechnology.

[21]  Girolamo Di Francia,et al.  Conductometric Gas Nanosensors , 2009, J. Sensors.

[22]  Wenrong Yang,et al.  Molecularly engineered graphene surfaces for sensing applications: A review. , 2015, Analytica chimica acta.

[23]  Dongho Kim,et al.  Graphene-based gas sensor: metal decoration effect and application to a flexible device , 2014 .

[24]  Stefano Borini,et al.  Optical constants of graphene layers in the visible range , 2009 .

[25]  C. Rao,et al.  A study of graphene decorated with metal nanoparticles , 2010 .

[26]  Guoliang Zhang,et al.  Palladium nanoparticle-graphene hybrids as active catalysts for the Suzuki reaction , 2010 .

[27]  A. Kuzmenko,et al.  Universal optical conductance of graphite. , 2007, Physical review letters.

[28]  J. Robertson,et al.  Interpretation of Raman spectra of disordered and amorphous carbon , 2000 .

[29]  A. Campion,et al.  Surface-enhanced Raman scattering , 1998 .

[30]  I. Lundström,et al.  Chemical reactions on palladium surfaces studied with Pd-MOS structures , 1977 .

[31]  C. N. Lau,et al.  Superior thermal conductivity of single-layer graphene. , 2008, Nano letters.

[32]  K. Novoselov,et al.  Detection of individual gas molecules adsorbed on graphene. , 2006, Nature materials.

[33]  R. Maboudian,et al.  Graphene decoration with metal nanoparticles: towards easy integration for sensing applications. , 2012, Nanoscale.

[34]  S. Khondaker,et al.  Graphene based materials: Past, present and future , 2011 .

[35]  T. Sudarshan,et al.  Functionalized graphene/silicon chemi-diode H2 sensor with tunable sensitivity , 2014, Nanotechnology.

[36]  G. Cuniberti,et al.  Contact dependence of carrier injection in carbon nanotubes: an ab initio study. , 2005, Physical review letters.

[37]  Thomas Hirsch,et al.  Hydrogen sensor based on a graphene - palladium nanocomposite , 2011 .

[38]  Ettore Massera,et al.  A calibrated graphene-based chemi-sensor for sub parts-per-million NO2 detection operating at room temperature , 2014 .

[39]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[40]  Ji-Beom Yoo,et al.  Flexible hydrogen sensors using graphene with palladium nanoparticle decoration , 2012 .

[41]  Junhong Chen,et al.  Controllable synthesis of silver nanoparticle-decorated reduced graphene oxide hybrids for ammonia detection. , 2013, The Analyst.

[42]  Abha Misra.  Carbon nanotubes and graphene-based chemical sensors , 2014 .

[43]  F. Stavale,et al.  Quantifying defects in graphene via Raman spectroscopy at different excitation energies. , 2011, Nano letters.

[44]  Vikas Berry,et al.  Implantation and growth of dendritic gold nanostructures on graphene derivatives: electrical property tailoring and Raman enhancement. , 2009, ACS nano.

[45]  Stephen J. Pearton,et al.  Hydrogen detection using platinum coated graphene grown on SiC , 2011 .

[46]  G. Meng,et al.  A Generic Synthetic Approach to Large‐Scale Pristine‐Graphene/Metal‐Nanoparticles Hybrids , 2013 .

[47]  A. Ferrari,et al.  Inkjet-printed graphene electronics. , 2011, ACS nano.

[48]  Jin Suk Chung,et al.  Reduced graphene oxide as an over-coating layer on silver nanostructures for detecting NH3 gas at room temperature , 2014 .

[49]  A. Mohajeri,et al.  Edge-functionalized graphene nanoflakes as selective gas sensors , 2014 .

[50]  Adarsh Kaniyoor,et al.  Nanostructured Pt decorated graphene and multi walled carbon nanotube based room temperature hydrogen gas sensor. , 2009, Nanoscale.