Rembrandt’s An Old Man in Military Costume: the underlying image re-examined

The painting An Old Man in Military Costume in the J. Paul Getty Museum, by Rembrandt Harmensz van Rijn, was studied using two complementary, element-specific imaging techniques—neutron activation autoradiography (NAAR) and macro-X-ray fluorescence (MA-XRF) mapping—to reveal the second, hidden painting. NAAR provided a strong image of the face and cloak of the underlying figure, along with an indication of the chemical composition. The single-element distribution maps produced by MA-XRF mapping provided additional details into the shape of the underlying image and the composition of the pigments used. The underlying figure’s face is richer in mercury, indicative of the pigment vermilion, than the face of the figure on the surface. Likewise, the cloak of the underlying figure is richer in copper than the surface figure though the identity of the copper-containing pigment cannot be determined from these data. The use of iron earth pigments, specifically Si-rich umbers, is indicated through the complementary information provided by the NAAR and MA-XRF maps. These data are used to create a false color digital reconstruction, yielding the most detailed representation of the underlying painting to date.

[1]  Koen Janssens,et al.  A mobile instrument for in situ scanning macro-XRF investigation of historical paintings , 2013 .

[2]  Giacomo Chiari,et al.  Saving art in situ , 2008, Nature.

[3]  Koen Janssens,et al.  Revealing hidden paint layers in oil paintings by means of scanning macro-XRF: a mock-up study based on Rembrandt's “An old man in military costume” , 2013 .

[4]  K. Perez Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment , 2014 .

[5]  D. Scott The Application of Scanning X‐ray Fluorescence Microanalysis in the Examination of Cultural Materials , 2001 .

[6]  Maryan Wynn Ainsworth Art and autoradiography: Insights into the genesis of paintings by Rembrandt, Van Dyck, and Vermeer , 1982 .

[7]  J. Bruyn,et al.  A corpus of Rembrandt paintings , 1982 .

[8]  M. D. de Jonge,et al.  High-definition X-ray fluorescence elemental mapping of paintings. , 2012, Analytical chemistry.

[9]  Ning Gao,et al.  Development of confocal X-ray fluorescence (XRF) microscopy at the Cornell high energy synchrotron source , 2006 .

[10]  Marc Walton,et al.  The Examination of Works of Art using in Situ XRF Line and Area Scans , 2010 .

[11]  Edward V. Sayre,et al.  NEUTRON ACTIVATION AUTORADIOGRAPHY OF OIL PAINTINGS , 1968 .

[12]  B. Sartowska,et al.  Neutron autoradiography : working-out method and application in investigations of test paintings , 2001 .

[13]  George L. Stout,et al.  Painting Materials: A Short Encyclopedia , 2011 .

[14]  Koen Janssens,et al.  Optimization of mobile scanning macro-XRF systems for the in situ investigation of historical paintings , 2011 .

[15]  Koen Janssens,et al.  Use of microscopic XRF for non‐destructive analysis in art and archaeometry , 2000 .

[16]  Koen Janssens,et al.  Visualization of a lost painting by Vincent van Gogh using synchrotron radiation based X-ray fluorescence elemental mapping. , 2008, Analytical chemistry.

[17]  J. Susini,et al.  Photon-based techniques for nondestructive subsurface analysis of painted cultural heritage artifacts. , 2010, Accounts of chemical research.

[18]  J. Schmalz,et al.  ArtTAX – a new mobile spectrometer for energy-dispersive micro X-ray fluorescence spectrometry on art and archaeological objects , 2001, Fresenius' journal of analytical chemistry.