A novel process of biomass gasification for hydrogen-rich gas with solid heat carrier : Preliminary experimental results

A new process of biomass gasification with a catalytic solid heat carrier is proposed that is called the ECCMB (external circulating concurrent moving bed) gasification system. The system is composed of a moving-bed gasification zone and a combustion zone. A circulation loop of bed material, which acts as catalyst and heat carrier, is achieved between these two zones. The char circulated with the bed material and the cokes deposited on the catalyst are burned off in the combustion zone to regenerate the catalyst and provide the energy for the endothermic gasification reactions with steam in the gasification zone. A lab-scale facility was established to demonstrate this process concept, where steam gasification of biomass and combustion of the produced char can occur simultaneously. The H2 content of 53.3 mol % in dry gas and the tar yield of 0.7 g/Nm3 dry gas can be obtained at a bed height of 400 mm and an S/B ratio (steam/biomass mass ratio) of 0.4 g/g at 800 °C with calcined olivine as the catalyst. Th...

[1]  Kj Krzysztof Ptasinski,et al.  Olivine as tar removal catalyst for biomass gasifiers: Catalyst characterization , 2005 .

[2]  M. Aznar,et al.  Biomass gasification in atmospheric and bubbling fluidized bed: effect of the type of gasifying agent on the product distribution , 1999 .

[3]  Isabel Cabrita,et al.  The study of reactions influencing the biomass steam gasification process , 2003 .

[4]  Toshiyuki Suda,et al.  The Superior Technical Choice for Dual Fluidized Bed Gasification , 2006 .

[5]  Tomoaki Minowa,et al.  Fundamental design of a continuous biomass gasification process using a supercritical water fluidized bed , 2004 .

[6]  Javier Herguido,et al.  Steam gasification of lignocellulosic residues in a fluidized bed at a small pilot scale. Effect of the type of feedstock , 1992 .

[7]  I. Bari,et al.  Air Gasification of Biomass in a Downdraft Fixed Bed: A Comparative Study of the Inorganic and Organic Products Distribution , 2000 .

[8]  Adnan Midilli,et al.  Hydrogen production from hazelnut shell by applying air-blown downdraft gasification technique , 2001 .

[9]  J. T. Riley,et al.  A novel biomass air gasification process for producing tar-free higher heating value fuel gas , 2006 .

[10]  Peter McKendry,et al.  Energy production from biomass (Part 3): Gasification technologies. , 2002, Bioresource technology.

[11]  Shaoping Xu,et al.  Steam gasification of apricot stones with olivine and dolomite as downstream catalysts , 2006 .

[12]  S. K. Bej,et al.  Steam Gasification of Biomass-Derived Char for the Production of Carbon Monoxide-Rich Synthesis Gas , 2001 .

[13]  C. M. Kinoshita,et al.  An experimental investigation of hydrogen production from biomass gasification , 1998 .

[14]  José Corella,et al.  Biomass gasification in fluidized bed : where to locate the dolomite to improve gasification? , 1999 .

[15]  Hermann Hofbauer,et al.  In-Bed Catalytic Tar Reduction in a Dual Fluidized Bed Biomass Steam Gasifier , 2004 .

[16]  Jie Chang,et al.  Biomass air-steam gasification in a fluidized bed to produce hydrogen-rich gas , 2003 .

[17]  Charlotte K. Williams,et al.  The Path Forward for Biofuels and Biomaterials , 2006, Science.

[18]  Kj Krzysztof Ptasinski,et al.  A review of the primary measures for tar elimination in biomass gasification processes , 2003 .

[19]  S. Rapagnà Steam-gasification of biomass in a fluidised-bed of olivine particles. , 2000 .

[20]  Sachio Ohta,et al.  Effect of Superficial Velocity on Tar from Downdraft Gasification of Biomass , 2005 .

[21]  H. Spliethoff,et al.  Biomass gasification integrated with pyrolysis in a circulating fluidised bed , 2004 .