Linear and second-order nonlinear optical dielectric behaviors of lithium niobate single crystals at high temperatures

Dielectric properties - linear and second-order nonlinear optical properties - of lithium niobate ferroelectric crystals are quantitatively studied from the crystallographic structures at different temperatures. On the basis of constituent chemical bonds of lithium niobate, the temperature dependent nature of dielectric properties of such crystals has been concluded. Dielectric responses increase with temperature increasing in a wide range from room temperature to the Curie temperature.

[1]  Dongfeng Xue,et al.  Dielectric properties of I-III- VI 2 -type chalcopyrite semiconductors , 2000 .

[2]  I. Brown The Bond Valence Model as a Tool for Teaching Inorganic Chemistry: The Ionic Model Revisited , 2000 .

[3]  A. Brenier,et al.  New structural transformations in congruent ferroelectric LiNbO3 fibres evidenced by Raman spectroscopy , 2000 .

[4]  D. Xue,et al.  Chemical bond analysis of the correlation between crystal structure and nonlinear optical properties of complex crystals , 1999 .

[5]  D. Xue,et al.  The effect of stoichiometry on nonlinear optical properties of LiNbO3 , 1997 .

[6]  Schlarb,et al.  Refractive indices of lithium niobate as a function of temperature, wavelength, and composition: A generalized fit. , 1993, Physical review. B, Condensed matter.

[7]  R. P. Edwin,et al.  Refractive indices of lithium niobate , 1976 .

[8]  B. F. Levine,et al.  Bond-Charge Calculation of Nonlinear Optical Susceptibilities for Various Crystal Structures , 1973 .

[9]  J. C. Phillips Ionicity of the Chemical Bond in Crystals , 1970 .

[10]  Van Vechten,et al.  Quantum Dielectric Theory of Electronegativity in Covalent Systems. I. Electronic Dielectric Constant , 1969 .

[11]  Tomoaki Yamada,et al.  Piezoelectric and Elastic Properties of Lithium Niobate Single Crystals , 1967 .

[12]  R. C. Miller,et al.  TEMPERATURE DEPENDENCE OF THE OPTICAL PROPERTIES OF FERROELECTRIC LiNbO3 AND LiTaO3 , 1966 .

[13]  K. Nassau,et al.  Ferroelectric lithium niobate. 2. Preparation of single domain crystals , 1966 .

[14]  F. Frey,et al.  A neutron powder investigation of the high-temperature structure and phase transition in stoichiometric LiNbO3 , 1997 .

[15]  G. A. Smolenskiǐ,et al.  The Curie Temperature of LiNbO3 , 1966 .