Tire Pyrolysis: Evolution of Volatile and Semivolatile Compounds

The formation/decomposition of several compounds from the pyrolysis of tire wastes is compared in three different types of equipment. The types of laboratory equipment consist of a Pyroprobe, where the secondary reactions are minimized, and a horizontal pyrolysis furnace, where the cracking is severe. The yields obtained in both types of equipment are compared with those previously obtained in a fluidized bed reactor. On the other hand, the kinetic severity function (KSF) has been proposed as a measure of the cracking undergone by the tars produced. This paper focuses on the production of semivolatiles from tire wastes.

[1]  C. Rostad,et al.  Kovats and lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest , 1986 .

[2]  Desmond Radlein,et al.  Liquid products from the continuous flash pyrolysis of biomass , 1985 .

[3]  José A. Caballero,et al.  Kinetic model for the combustion of tyre wastes , 1998 .

[4]  A. M. Mastral,et al.  Assessment of PAH emissions as a function of coal combustion variables , 1996 .

[5]  M. Antal Effects of reactor severity on the gas-phase pyrolysis of cellulose- and kraft lignin-derived volatile matter , 1983 .

[6]  Angela N. García,et al.  Kinetic studies of the primary pyrolysis of municipal solid waste in a Pyroprobe 1000 , 1992 .

[7]  P. L. Silveston,et al.  Product distribution in pyrolysis of cellulose in a microfluidized bed , 1986 .

[8]  Angela N. García,et al.  Pyrolysis of Polyethylene in a Fluidized Bed Reactor , 1994 .

[9]  F. Berruti,et al.  A KINETIC MODEL FOR THE PRODUCTION OF LIQUIDS FROM THE FLASH PYROLYSIS OF BIOMASS , 1988 .

[10]  A. Marcilla,et al.  Gaseous hydrocarbons from flash pyrolysis of almond shells , 1988 .

[11]  P. L. Silveston,et al.  Product yield correlations for cellulose flash pyrolysis , 1988 .

[12]  J. A. Conesa,et al.  Kinetic model of the pyrolysis of polyethylene in a fluidized bed reactor , 1994 .

[13]  Rafael Font,et al.  Kinetic study of the flash pyrolysis of almond shells in a fluidized bed reactor at high temperatures , 1993 .

[14]  Curt M. White,et al.  Retention indices for programmed-temperature capillary-column gas chromatography of polycyclic aromatic hydrocarbons , 1979 .

[15]  A. Marcilla,et al.  Mass spectrometry validation of a kinetic model for the thermal decomposition of tyre wastes , 1997 .

[16]  J. A. Conesa,et al.  Gas from the pyrolysis of scrap tires in a fluidized bed reactor , 1996 .

[17]  J. Caballero,et al.  Flash pyrolysis of Klason lignin in a Pyroprobe 1000 , 1993 .

[18]  Paul T. Williams,et al.  Composition of oils derived from the batch pyrolysis of tyres , 1998 .

[19]  A. Marcilla,et al.  Kinetic study of the thermogravimetric behavior of different rubbers , 1996 .

[20]  P. L. Silveston,et al.  Correlation of volatile products from fast cellulose pyrolysis , 1986 .