Manganese octahedral molecular sieves catalyzed tandem process for synthesis of quinoxalines

An efficient environmentally benign tandem synthetic route to prepare quinoxalines leading to 100% yields using reusable manganese oxide octahedral molecular sieves (OMS-2) is described.

[1]  Ranjit Kumar,et al.  Tandem catalysis: Direct catalytic synthesis of imines from alcohols using manganese octahedral molecular sieves , 2008 .

[2]  C. Cho,et al.  Copper-catalyzed oxidative cyclization of α-hydroxyketones with o-phenylenediamines leading to quinoxalines , 2007 .

[3]  C. Frost,et al.  A New Method for Constructing Quaternary Carbon Centres: Tandem Rhodium‐Catalysed 1,4‐Addition/Intramolecular Cyclisation , 2007 .

[4]  C. Yao,et al.  Cerium (IV) ammonium nitrate (CAN) as a catalyst in tap water: A simple, proficient and green approach for the synthesis of quinoxalines , 2006 .

[5]  C. Cho,et al.  A new ruthenium-catalyzed approach for quinoxalines from o-phenylenediamines and vicinal-diols , 2006 .

[6]  Ranjit Kumar,et al.  Manganese oxide octahedral molecular sieve catalysts for synthesis of 2-aminodiphenylamine , 2005 .

[7]  Ranjit Kumar,et al.  Synthesis and Catalytic Activity of Cryptomelane-Type Manganese Dioxide Nanomaterials Produced by a Novel Solvent-Free Method , 2005 .

[8]  K. Park,et al.  Manganese(IV) dioxide-catalyzed synthesis of quinoxalines under microwave irradiation. , 2005, Chemical communications.

[9]  S. Obrey,et al.  Concurrent tandem catalysis. , 2005, Chemical reviews.

[10]  J. L. Gleason,et al.  Two birds with one metallic stone: single-pot catalysis of fundamentally different transformations. , 2004, Angewandte Chemie.

[11]  C. Lindsley,et al.  General microwave-assisted protocols for the expedient synthesis of quinoxalines and heterocyclic pyrazines , 2004 .

[12]  C. D. Wilfred,et al.  Tandem oxidation processes for the preparation of nitrogen-containing heteroaromatic and heterocyclic compounds. , 2004, Organic & biomolecular chemistry.

[13]  C. D. Wilfred,et al.  Preparation of quinoxalines, dihydropyrazines, pyrazines and piperazines using tandem oxidation processes. , 2003, Chemical communications.

[14]  R. Reynolds,et al.  Synthesis and antimycobacterial activity of pyrazine and quinoxaline derivatives. , 2002, Journal of medicinal chemistry.

[15]  S. Antoniotti,et al.  Direct and catalytic synthesis of quinoxaline derivatives from epoxides and ene-1,2-diamines , 2002 .

[16]  R. Schoevaart,et al.  Combined Catalytic Reactions: Nature′s Way. , 2002 .

[17]  S. Suib,et al.  Efficient, Catalytic, Aerobic Oxidation of Alcohols with Octahedral Molecular Sieves. , 2001, Angewandte Chemie.

[18]  Guanguang Xia,et al.  Synthesis and characterization of nanofibrous sodium manganese oxide with a 2 x 4 tunnel structure , 2001 .

[19]  I. Sage,et al.  Synthesis and device characterisation of side-chain polymer electron transport materials for organic semiconductor applications , 2001 .

[20]  S. Suib,et al.  A Review of Porous Manganese Oxide Materials , 1998 .

[21]  S. Suib Microporous Manganese Oxides , 1998 .

[22]  Edward J. Neth,et al.  Synthesis and characterization of octahedral molecular sieves (OMS-2) having the hollandite structure , 1994 .

[23]  S. Suib,et al.  Manganese Oxide Octahedral Molecular Sieves: Preparation, Characterization, and Applications , 1993, Science.

[24]  R. G. Browne,et al.  4-Amino[1,2,4]triazolo[4,3-a]quinoxalines. A novel class of potent adenosine receptor antagonists and potential rapid-onset antidepressants. , 1990, Journal of medicinal chemistry.