One-step conversion to tertiary amines : InBr3/Et3SiH-mediated reductive deoxygenation of tertiary amides

[1]  A. Charette,et al.  Highly chemoselective metal-free reduction of tertiary amides. , 2008, Journal of the American Chemical Society.

[2]  Yukihiro Motoyama,et al.  The ruthenium-catalyzed reduction and reductive N-alkylation of secondary amides with hydrosilanes: practical synthesis of secondary and tertiary amines by judicious choice of hydrosilanes. , 2007, The Journal of organic chemistry.

[3]  T. Konakahara,et al.  An efficient one-pot synthesis of unsymmetrical ethers: a directly reductive deoxygenation of esters using an InBr3/Et3SiH catalytic system. , 2007, The Journal of organic chemistry.

[4]  Yusuke Yamada,et al.  Indium-catalyzed radical reductions of organic halides with hydrosilanes. , 2007, The Journal of organic chemistry.

[5]  M. Kamiya,et al.  Reduction of Carboxylic Acid Derivatives Using Diphenylsilane in the Presence of a Rh–PPh3 Complex , 2005 .

[6]  Yukihiro Motoyama,et al.  Self-encapsulation of homogeneous catalyst species into polymer gel leading to a facile and efficient separation system of amine products in the Ru-catalyzed reduction of carboxamides with polymethylhydrosiloxane (PMHS). , 2005, Journal of the American Chemical Society.

[7]  A. Baba,et al.  Triethylsilane-indium(III) chloride system as a radical reagent. , 2004, Organic letters.

[8]  Yusuke Yamada,et al.  Indium(III) Acetate-Catalyzed 1,4-Reduction and Reductive Aldol Reactions of α-Enones with Phenylsilane , 2004 .

[9]  M. Yasuda,et al.  Direct substitution of the hydroxy group in alcohols with silyl nucleophiles catalyzed by indium trichloride. , 2004, Angewandte Chemie.

[10]  M. Yasuda,et al.  Catalytic generation of indium hydride in a highly diastereoselective reductive aldol reaction. , 2004, Angewandte Chemie.

[11]  H. Nagashima,et al.  A triruthenium carbonyl cluster bearing a bridging acenaphthylene ligand: an efficient catalyst for reduction of esters, carboxylic acids, and amides by trialkylsilanes. , 2002, The Journal of organic chemistry.

[12]  M. Yasuda,et al.  Direct reduction of alcohols: highly chemoselective reducing system for secondary or tertiary alcohols using chlorodiphenylsilane with a catalytic amount of indium trichloride. , 2001, The Journal of organic chemistry.

[13]  Mamoru Igarashi,et al.  Transition-metal complex-catalyzed reduction of amides with hydrosilanes: a facile transformation of amides to amines , 2001 .

[14]  W. Bowman,et al.  Radical cyclisation onto nitriles , 2000 .

[15]  A. Baba,et al.  Novel Synthetic Usage of Indium Compounds as Catalyst: Reductive Deoxygenation of Aryl Ketones and sec-Benzylic Alcohols , 1999 .

[16]  R. Kuwano,et al.  REDUCTION OF AMIDES TO AMINES VIA CATALYTIC HYDROSILYLATION BY A RHODIUM COMPLEX , 1998 .

[17]  S. Buchwald,et al.  A Mild General Procedure for the One‐Pot Conversion of Amides to Aldehydes , 1996 .

[18]  C. Pedregal,et al.  Highly chemoselective reduction of N-Boc protected lactams , 1994 .

[19]  M. Yamashita,et al.  Azetidines and bisazetidines. Their synthesis and use as the key intermediates to enantiomerically pure diamines, amino alcohols, and polyamines , 1991 .

[20]  B. Giese,et al.  Hydrosilylation and Cyclization Reactions of Alkenes and Ketones with Tris(trimethylsilyl)silane , 1990 .

[21]  N. Yoon,et al.  Reaction of diisobutylaluminum hydride with selected organic compounds containing representative functional groups , 1985 .

[22]  E. Sugino,et al.  Reduction of Some Functional Groups with Titanium(IV) Chloride/Sodium Borohydride , 1980 .

[23]  D. Griller,et al.  Free-radical clocks , 1980 .

[24]  N. Itoh,et al.  Sodium acyloxyborohydride as new reducing agents. I. Reduction of carboxamides to the corresponding amines , 1976 .

[25]  J. Glasby.  Encyclopedia of the Alkaloids , 1975, Springer US.

[26]  T. Satoh,et al.  [Reduction of organic compounds with sodium borohydride-transition metal salt systems. 3. Preparation of 2-aminomethyl-1,1-diphenyl-1-butene]. , 1970, Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan.

[27]  P. Krusic,et al.  Homoallylic rearrangement and electron spin resonance of cyclopropylcarbinyl radicals , 1969 .

[28]  P. Krusic,et al.  Electron spin resonance of free radicals from alkylcyclopropanes , 1969 .

[29]  M. Kornet,et al.  Borane reduction of amido esters , 1968 .

[30]  R. Borch.  A new method for the reduction of secondary and tertiary amides , 1968 .

[31]  H. Brown,et al.  Selective Reductions. X. Reaction of Aluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups. Comparison of the Reducing Characteristics of Lithium Aluminum Hydride and Its Derivatives , 1966 .

[32]  H. Brown,et al.  Diborane as a Mild Reducing Agent for the Conversion of Primary, Secondary, and Tertiary Amides into the Corresponding Amines , 1964 .

[33]  H. Brown,et al.  Hydroboration. III. The Reduction of Organic Compounds by Diborane, an Acid-type Reducing Agent , 1960 .

[34]  V. Mićović,et al.  The Reduction of Acid Amides with Lithium Aluminum Hydride , 1953 .

[35]  R. Long,et al.  213. Reduction of amides with lithium aluminium hydride , 1951 .

[36]  A. Stoll,et al.  Die Konstitution der Mutterkornalkaloide. Struktur des Peptidteils. III. 24. Mitteilung über Mutterkornalkaloide , 1951 .

[37]  W. G. Brown,et al.  Reduction of organic compounds by lithium aluminum hydride; halides, quinones, miscellaneous nitrogen compounds. , 1948, Journal of the American Chemical Society.