Evaluation of Nanosized Iron in Slurry-Phase Fischer−Tropsch Synthesis

The Fischer−Tropsch (F−T) activity of three α-Fe2O3-based materials, two unsupported nanosized, NANOCAT (3 nm) and BASF (20−80 nm), and a supported micrometer-sized (32.5 μm) UCI, were measured wit...

[1]  B. Davis,et al.  Iron Fischer-Tropsch catalysis: Properties of an ultrafine iron oxide catalyst. Quarterly progress report, July--September 1992 , 1992 .

[2]  A. Bell,et al.  Influence of particle size on carbon monoxide hydrogenation over silica- and lanthana-supported rhodium , 1987 .

[3]  B. Jager,et al.  Low temperature Fischer–Tropsch synthesis from a Sasol perspective , 1999 .

[4]  Hiroaki Takahashi,et al.  Catalytic performances of cobalt-based ultrafine particles prepared by chemical reduction in slurry-phase Fischer–Tropsch synthesis , 1999 .

[5]  Hans Schulz,et al.  Short history and present trends of Fischer–Tropsch synthesis , 1999 .

[6]  H. Itoh,et al.  Liquid phase hydrogenation of carbon monoxide over potassium-promoted ultrafine particles of iron and copper , 1990 .

[7]  H. Itoh,et al.  Properties and product selectivities of iron ultrafine particles as a catalyst for liquid phase hydrogenation of carbon monoxide , 1988 .

[8]  M. Dry,et al.  Factors influencing the formation of carbon on iron Fischer-Tropsch catalysts: I. The influence of promoters , 1970 .

[9]  Barry M. Trost,et al.  Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way , 1995 .

[10]  A. Datye,et al.  Characterization of slurry phase iron catalysts for Fischer-Tropsch synthesis , 1999 .

[11]  B. Davis,et al.  FISCHER-TROPSCH SYNTHESIS: MOSSBAUER STUDIES OF PRETREATED ULTRAFINE IRON OXIDE CATALYSTS , 1993 .

[12]  D. Mahajan,et al.  Selective synthesis of mixed alcohols catalyzed by dissolved base-activated highly dispersed slurried iron , 1999 .

[13]  Paul J. Flory,et al.  Molecular Size Distribution in Linear Condensation Polymers1 , 1936 .

[14]  V. Ponec,et al.  Promoters and Supports, Their Importance in the Synthesis Gas Reactions by Metals , 1991 .

[15]  H. Arakawa,et al.  Effect of metal dispersion on the activity and selectivity of Rh/SiO2 catalyst for high pressure CO hydrogenation. , 1984 .

[16]  Abhaya K. Datye,et al.  Activation of Precipitated Iron Fischer-Tropsch Synthesis Catalysts , 1995 .

[17]  H. Itoh,et al.  Liquid phase Fischer—Tropsch synthesis on ultrafine particles of iron: Effect of preoxidation treatment , 1990 .

[18]  Gerald P. Huffman,et al.  Pretreatment effect studies with a precipitated iron Fischer-Tropsch catalyst , 1995 .

[19]  A. Kiennemann,et al.  Mechanistic Aspects of the Formation of Hydrocarbons and Alcohols from CO Hydrogenation , 1993 .

[20]  N. Shah,et al.  Structure of a nanophase iron oxide catalyst , 1993 .

[21]  R. D. Sproull,et al.  Kinetic modeling of homogeneous methanol synthesis catalyzed by base-promoted nickel complexes , 2001 .

[22]  H. Pennline,et al.  Activation and promotion studies in a mixed slurry reactor with an iron-manganese Fischer-Tropsch catalyst , 1987 .

[23]  N. Shah,et al.  Structure and dispersion of iron-based catalysts for direct coal liquefaction , 1993 .

[24]  D. Bukur,et al.  Activation studies with a precipitated iron catalyst for Fischer-Tropsch synthesis. I. Characterization studies , 1995 .

[25]  A. Bastein,et al.  Role of impurities in the enhancement of C2-oxygenates activity , 1990 .

[26]  G. Huffman,et al.  Agglomeration and Phase Transition of a Nanophase Iron Oxide Catalyst , 1993 .

[27]  B. Gates Supported Metal Clusters: Synthesis, Structure, and Catalysis , 1995 .

[28]  Lech Nowicki,et al.  Activation studies with a precipitated iron catalyst for Fischer-Tropsch synthesis. II. Reaction studies , 1995 .

[29]  B. Davis,et al.  FISCHER-TROPSCH SYNTHESIS: IMPACT OF PRETREATMENT OF ULTRAFINE IRON OXIDE UPON CATALYST STRUCTURE AND SELECTIVITY , 1993 .