Observation of near interface oxide traps in single crystalline Nd2O3 on Si(111) by quasistatic C-V method

Single crystalline Nd2O3 based capacitors with proper forming gas annealing treatment are fabricated. By elevating the temperature of substrate to 100°C, near interface oxide traps are observed according to the quasistatic C-V obtained at low frequency. Two types of traps, interface traps and near interface oxide traps, are demonstrated in this gate stack. Using the low-high frequency method, the interface trap density at flatband voltage condition and the near interface oxide trap density are estimated to be 5.17×1011eV−1cm−2 and 3.75×1012cm−2, respectively. The interface trap density is then further confirmed by the conductance method.

[1]  Marvin H. White,et al.  Observation and characterization of near-interface oxide traps with C-V techniques , 1995 .

[2]  V. Narayanan,et al.  Growth and characterization of epitaxial Si/(LaxY1−x)2O3/Si heterostructures , 2003 .

[3]  H. Osten,et al.  Integration of functional epitaxial oxides into silicon: From high-K application to nanostructures , 2007 .

[4]  Eduard A. Cartier,et al.  Materials characterization of ZrO2–SiO2 and HfO2–SiO2 binary oxides deposited by chemical solution deposition , 2001 .

[5]  K. Saraswat,et al.  Crystallization kinetics and microstructure-dependent leakage current behavior of ultrathin HfO2 dielectrics: In situ annealing studies , 2004 .

[6]  R. Wallace,et al.  High-κ gate dielectrics: Current status and materials properties considerations , 2001 .

[7]  H. Osten,et al.  Influence of interface layer composition on the electrical properties of epitaxial Gd2O3 thin films for high-K application , 2007 .

[8]  H. Kumigashira,et al.  Crystallization in HfO2 gate insulators with in situ annealing studied by valence-band photoemission and x-ray absorption spectroscopy , 2005 .

[9]  Soon-Gil Yoon,et al.  Structural and electrical characterizations of ultrathin HfO2 gate dielectrics treated by nitrogen-plasma atmosphere , 2006 .

[10]  D. Schroder Semiconductor Material and Device Characterization , 1990 .

[11]  Apurba Laha,et al.  Epitaxial multi-component rare earth oxide for high-K application , 2007 .

[12]  Luigi Colombo,et al.  Application of HfSiON as a gate dielectric material , 2002 .

[13]  J.C. Lee,et al.  The electrical and material characterization of hafnium oxynitride gate dielectrics with TaN-gate electrode , 2004, IEEE Transactions on Electron Devices.

[14]  David-Wei Zhang,et al.  Effective passivation of slow interface states at the interface of single crystalline Gd2O3 and Si(100) , 2008 .

[15]  O. Gluschenkov,et al.  Performance dependence of CMOS on silicon substrate orientation for ultrathin oxynitride and HfO2 gate dielectrics , 2003, IEEE Electron Device Letters.