The rapid growth of vertically aligned carbon nanotubes using laser heating

Growth of densely packed vertically aligned carbon nanotubes (VA-CNTs) using laser-induced chemical vapor deposition with visible laser (lambda = 532 nm) irradiation at room temperature is reported. Using a multiple-catalyst layer (Fe/Al/Cr) on quartz as the substrate and an acetylene-hydrogen mixture as the precursor gas, VA-CNT pillars with 60 microm height and 4 microm diameter were grown at a high rate of around 1 microm s(-1) with good reproducibility. It is demonstrated that the fabrication of uniform pillar arrays of VA-CNTs can be achieved with a single irradiation for each pillar using LCVD with no annealing or preprocessing of the substrate. Here, laser fast heating is considered the primary mechanism facilitating the growth of VA-CNT pillars. Field emission characteristics of an array of VA-CNT pillars were then examined to investigate their potential application in vacuum electronic devices.

[1]  Y. C. Kim,et al.  Printed Carbon Nanotube Field Emitters for Backlight Applications , 2005 .

[2]  H. Sugie,et al.  Carbon nanotubes as electron source in an x-ray tube , 2001 .

[3]  B. Wei,et al.  Rapid growth of well-aligned carbon nanotube arrays , 2002 .

[4]  Anastasios John Hart,et al.  Rapid growth and flow-mediated nucleation of millimeter-scale aligned carbon nanotube structures from a thin-film catalyst. , 2006, The journal of physical chemistry. B.

[6]  Wonbong Choi,et al.  Vertically aligned carbon nanotube probes for monitoring blood cholesterol , 2006, Nanotechnology.

[7]  H. Ohno,et al.  Growth of Vertically Aligned Single-Walled Carbon Nanotubes on Alumina and Sapphire Substrates , 2008 .

[8]  J. Park,et al.  Hybrid LCVD of micro-metallic lines for TFT-LCD circuit repair , 2006 .

[9]  J. Gan,et al.  Field emission from a composite structure consisting of vertically aligned single-walled carbon nanotubes and carbon nanocones , 2006 .

[10]  K. Ishida,et al.  Efficient field emission from an individual aligned carbon nanotube bundle enhanced by edge effect , 2007 .

[11]  Growth and field emission properties of carbon nanotubes on rapid thermal annealed Ni catalyst using PECVD , 2005 .

[12]  Liwei Lin,et al.  Rapid synthesis of carbon nanotubes via inductive heating , 2006 .

[13]  P. Couturier Japan , 1988, The Lancet.

[14]  Y. S. Lin,et al.  Synthesis of suspended carbon nanotubes on silicon inverse-opal structures by laser-assisted chemical vapour deposition , 2006 .

[15]  Pulickel M. Ajayan,et al.  Carbon nanotube-based synthetic gecko tapes , 2007, Proceedings of the National Academy of Sciences.

[16]  J. Robertson,et al.  Submicron patterning of Co colloid catalyst for growth of vertically aligned carbon nanotubes , 2005 .

[17]  I. Ivanov,et al.  Pulsed laser CVD investigations of single-wall carbon nanotube growth dynamics , 2008 .

[18]  Michael L. Simpson,et al.  Vertically Aligned Carbon Nanofibers and Related Structures: Controlled Synthesis and Directed Assembly , 2005 .

[19]  S. Honda,et al.  High-Density Growth of Vertically Aligned Carbon Nanotubes with High Linearity by Catalyst Preheating in Acetylene Atmosphere , 2008 .

[20]  Anne Claire Dupuis,et al.  The catalyst in the CCVD of carbon nanotubes—a review , 2005 .

[21]  S. Lim,et al.  Origin of enhanced field emission characteristics postplasma treatment of multiwalled carbon nanotube array , 2008 .

[22]  N. Kishi,et al.  An efficient fabrication of vertically aligned carbon nanotubes on flexible aluminum foils by catalyst-supported chemical vapor deposition , 2008, Nanotechnology.

[23]  Shoushan Fan,et al.  Nanotechnology: Spinning continuous carbon nanotube yarns , 2002, Nature.

[24]  J. Miao,et al.  Effect of ion bombardment on the synthesis of vertically aligned single-walled carbon nanotubes by plasma-enhanced chemical vapor deposition , 2008, Nanotechnology.

[25]  S. Chakrabarti,et al.  Number of Walls Controlled Synthesis of Millimeter-Long Vertically Aligned Brushlike Carbon Nanotubes , 2007 .

[26]  John Robertson,et al.  Catalytic chemical vapor deposition of single-wall carbon nanotubes at low temperatures. , 2006, Nano letters.

[27]  M. Khakani,et al.  The nanostructure and electrical properties of SWNT bundle networks grown by an ‘all-laser’ growth process for nanoelectronic device applications , 2004 .

[28]  K. Jiang,et al.  A growth mark method for studying growth mechanism of carbon nanotube arrays , 2005 .

[29]  W. Chiu,et al.  Growth of carbon nanotubes by open-air laser-induced chemical vapor deposition , 2005 .

[30]  M. Siegal,et al.  Synthesis of large arrays of well-aligned carbon nanotubes on glass , 1998, Science.

[31]  D. Bäuerle Laser Processing and Chemistry , 1996 .

[32]  K. Jiang,et al.  Laser direct writing carbon nanotube arrays on transparent substrates , 2007 .

[33]  N. Tai,et al.  Synthesis of ultra long vertically aligned carbon nanotubes using the rapid heating and cooling system in the thermal chemical vapor deposition process , 2006 .

[34]  Gehan A. J. Amaratunga,et al.  Uniform patterned growth of carbon nanotubes without surface carbon , 2001 .

[35]  M. Dresselhaus Carbon nanotubes , 1995 .

[36]  Young Hee Lee,et al.  Fully sealed, high-brightness carbon-nanotube field-emission display , 1999 .

[37]  A. John Hart,et al.  Abrupt self-termination of vertically aligned carbon nanotube growth , 2008 .

[38]  Sungho Jin,et al.  Nucleation and growth of carbon nanotubes by microwave plasma chemical vapor deposition , 2000 .

[39]  H. Kawarada,et al.  Growth of dense single-walled carbon nanotubes in nano-sized silicon dioxide holes for future microelectronics , 2007 .

[40]  Ado Jorio,et al.  Carbon Nanotubes: Advanced Topics in the Synthesis, Structure, Properties and Applications , 2007 .

[41]  Joseph D. Gong,et al.  Carbon nanotube amplification strategies for highly sensitive immunodetection of cancer biomarkers. , 2006, Journal of the American Chemical Society.

[42]  K. Vecchio,et al.  Growth mechanism of vapor phase CVD-grown multi-walled carbon nanotubes , 2005 .

[43]  Robert F. Richards,et al.  Electrostatic shielding in patterned carbon nanotube field emission arrays , 2007 .

[44]  P. Harris Solid state growth mechanisms for carbon nanotubes , 2007 .

[45]  Li-Yu Daisy Liu,et al.  Controlled Termination of the Growth of Vertically Aligned Carbon Nanotube Arrays , 2007 .

[46]  M. S. Jeong,et al.  Direct writing of carbon nanotube patterns by laser-induced chemical vapor deposition on a transparent substrate , 2009 .

[47]  S. Cronin,et al.  Laser directed growth of carbon-based nanostructures by plasmon resonant chemical vapor deposition. , 2008, Nano letters.

[48]  H. Dai,et al.  Self-oriented regular arrays of carbon nanotubes and their field emission properties , 1999, Science.

[49]  W. Chiu,et al.  Continuous deposition of carbon nanotubes on a moving substrate by open-air laser-induced chemical vapor deposition , 2005 .

[50]  D. Geohegan,et al.  Rapid Growth of Long, Vertically Aligned Carbon Nanotubes through Efficient Catalyst Optimization Using Metal Film Gradients , 2004 .

[51]  F. Rohmund,et al.  Carbon nanotube films grown by laser-assisted chemical vapor deposition , 2002 .

[52]  Luigi Occhipinti,et al.  Growth mechanisms in chemical vapour deposited carbon nanotubes , 2003 .

[53]  Liangti Qu,et al.  Carbon Nanotube Arrays with Strong Shear Binding-On and Easy Normal Lifting-Off , 2008, Science.

[54]  Zhong Lin Wang,et al.  Laser assisted chemical vapor deposition synthesis of carbon nanotubes and their characterization , 2006 .