Acid leaching of manganiferous ores by sucrose: Kinetic modelling and related statistical analysis

Abstract This work reports the kinetic study of a manganiferous ore leaching in acid media by sucrose as reducing agent. A shrinking core model with variable activation energy was found to successfully fit experimental data of manganese extraction yields vs leaching time. This model finds a physical confirmation both in the complex reactions that take place during manganese leaching and the different reactivity and accessibility of the mineralogical forms present in the ores. A non linear regression analysis has been performed in order to estimate the adjustable model parameters and a statistical analysis has also been carried out in order to evaluate the significativity of the estimated values.

[1]  David Mautner Himmelblau,et al.  Process analysis by statistical methods , 1970 .

[2]  M. Brittan Variable activation energy model for leaching kinetics , 1975 .

[3]  F. K. Crundwell,et al.  Progress in the mathematical modelling of leaching reactors , 1995 .

[4]  F. Crundwell,et al.  The modelling of particulate leaching reactors— the population balance approach , 1992 .

[5]  Z. Momade,et al.  A study of the kinetics of reductive leaching of manganese oxide ore in aqueous methanol–sulphuric acid medium , 1999 .

[6]  Giuliana Taglieri,et al.  Acid leaching process by using glucose as reducing agent : A comparison among the efficiency of different kinds of manganiferous ores , 2000 .

[7]  F. Beolchini,et al.  Kinetic Modeling of Pyrrothite Ore Leaching by Ferric Iron and Related Statistical Analysis , 1999 .

[8]  Francesco Vegliò,et al.  Fractional factorial experiments in the development of manganese dioxide leaching by sucrose in sulphuric acid solutions , 1994 .

[9]  F. Veglio,et al.  Reductive leaching of a concentrate manganese dioxide ore in acid solution: stoichiometry and preliminary kinetic analysis , 1994 .

[10]  Alan P. Prosser,et al.  Review of uncertainty in the collection and interpretation of leaching data , 1996 .

[11]  Andrea P. Reverberi,et al.  New Procedure for Optimal Design of Sequential Experiments in Kinetic Models , 1994 .

[12]  F. Beolchini,et al.  Bioleaching of a pyrrhotite ore by a sulfooxidans strain: kinetic analysis , 2000 .

[13]  Z. Ma,et al.  Rate processes and mathematical modelling of the acid leaching of a manganese carbonate ore , 1991 .