The Effect of Cooling Conditions on Martensite Transformation Temperature and Hardness of 15% Cr Chromium Cast Iron

The research reported in the paper concerned the conditions of cooling high-chromium cast iron with about 15% Cr content capable to ensure completeness of transformation of supercooled austenite into martensite in order to obtain high hardness value of the material and thus its high resistance to abrasive wear. For testing, castings were prepared with dimensions 120 mm × 100 mm × 15 mm cast in sand molds in which one of cavity surfaces was reproduced with chills. From the castings, specimens for dilatometric tests were taken with dimensions 4 mm × 4 mm × 16 mm and plates with dimensions 50 mm × 50 mm × 15 mm for heat treatment tests. The dilatometric specimens were cut out from areas subject to interaction with the chill. The austenitizing temperature and time were 1000 °C and 30 min, respectively. Dilatograms of specimens quenched in liquid nitrogen were used to determine martensite transformation start and finish temperatures TMs and TMf, whereas from dilatograms of specimens quenched in air and in water, only TMs was red out. To secure completeness of the course of transformation of supercooled austenite into martensite and reveal the transformation finish temperature, it was necessary to continue cooling of specimens in liquid nitrogen. It has been found that TMs depended strongly on the quenching method whereas TMf values were similar for each of the adopted cooling conditions. The examined cooling variants were used to develop a heat treatment process allowing to obtain hardness of 68 HRC.

[1]  D. Kopyciński,et al.  Analysis of the High Chromium Cast Iron Microstructure after the Heat Treatment , 2014 .

[2]  J. Pearce,et al.  A Microstructural Study of Destabilised 30wt%Cr-2.3wt%C High Chromium Cast Iron , 2004 .

[3]  I. Mejía,et al.  Niobium Additions to a 15%Cr–3%C White Iron and Its Effects on the Microstructure and on Abrasive Wear Behavior , 2019 .

[4]  G. Laird,et al.  Structure, nucleation, growth and morphology of secondary carbides in high chromium and Cr-Ni white cast irons , 1992 .

[5]  C. Boher,et al.  Effect of molybdenum and chromium contents in sliding wear of high-chromium white cast iron: The relationship between microstructure and wear , 2009 .

[6]  T. N. Durlu Effects of high austenitizing temperature and austenite deformation on formation of martensite in Fe-Ni-C alloys , 2001 .

[7]  G. Laird,et al.  Solidification and solid-state transformation mechanisms in Si alloyed high-chromium white cast irons , 1993 .

[8]  G. Faria,et al.  Austenitizing Temperature and Cooling Rate Effects on the Martensitic Transformation in a Microalloyed-Steel , 2020, Materials Research.

[9]  Liang Zhihua,et al.  Sintering of a hypoeutectic high chromium cast iron as well as its microstructure and properties , 2018 .

[10]  M. Gómez,et al.  Modelling of Phase Transformation Kinetics by Correction of Dilatometry Results for a Ferritic Nb-microalloyed Steel , 2003 .

[11]  Yu. G. Chabak,et al.  Kinetic Parameters of Secondary Carbide Precipitation in High-Cr White Iron Alloyed by Mn-Ni-Mo-V Complex , 2013, Journal of Materials Engineering and Performance.

[12]  A. Lekatou,et al.  Microstructural Modifications of As-Cast High-Chromium White Iron by Heat Treatment , 2009 .

[13]  Yu. G. Chabak,et al.  Effect of Destabilizing Heat Treatment on Solid-State Phase Transformation in High-Chromium Cast Irons , 2013, Metallurgical and Materials Transactions A.

[14]  Alternative Heat Treatments for Complex-Alloyed High-Cr Cast Iron Before Machining , 2018, Metallurgical and Materials Transactions A.

[15]  D. Kopyciński,et al.  The Abrasive Wear Resistance of Chromium Cast Iron , 2014 .

[16]  H. Gasan,et al.  Effects of a Destabilization Heat Treatment on the Microstructure and Abrasive Wear Behavior of High-Chromium White Cast Iron Investigated Using Different Characterization Techniques , 2013, Metallurgical and Materials Transactions A.

[17]  K. Bouhamla,et al.  Improving Wear Properties of High-Chromium Cast Iron by Manganese Alloying , 2016, International Journal of Metalcasting.

[18]  F. Mücklich,et al.  High Chromium Cast Irons: Destabilized-Subcritical Secondary Carbide Precipitation and Its Effect on Hardness and Wear Properties , 2018, Journal of Materials Engineering and Performance.

[19]  V. Kuokkala,et al.  The role of microstructure in high stress abrasion of white cast irons , 2017 .

[20]  M. Guerrero-Mata,et al.  Effect of the High-Temperature Deformation on the Ms Temperature in a Low C Martensitic Stainless Steel , 2013, Journal of Materials Engineering and Performance.

[21]  J. Coronado,et al.  Abrasive wear study of white cast iron with different solidification rates , 2009 .

[22]  J. Asensio-Lozano,et al.  Influence of Thermal Parameters Related to Destabilization Treatments on Erosive Wear Resistance and Microstructural Variation of White Cast Iron Containing 18% Cr. Application of Design of Experiments and Rietveld Structural Analysis , 2019, Materials.

[23]  M. Kondracki,et al.  Influence of Titanium on Crystallization and Wear Resistance of High Chromium Cast Iron , 2016 .

[24]  Z. Qiao,et al.  Martensite transformation kinetics in 9Cr–1.7W–0.4Mo–Co ferritic steel , 2014 .

[25]  H. Bhadeshia,et al.  Uncertainties in dilatometric determination of martensite start temperature , 2007 .

[26]  A. W. Orłowicz,et al.  Effect of rapid solidification on sliding wear of iron castings , 2003 .

[27]  J. Coronado,et al.  Tempering temperature effects on abrasive wear of mottled cast iron , 2009 .

[28]  R. Sisson,et al.  A Model for Converting Dilatometric Strain Measurements to the Fraction of Phase Formed during the Transformation of Austenite to Martensite in Powder Metallurgy Steels , 2009 .

[29]  I. Hutchings,et al.  Design and selection of materials for tribological applications , 2017 .

[30]  L. Soos,et al.  Abrasion Wear Behavior of High-chromium Cast Iron , 2016 .