Synthesis and magnetic behavior of nanostructured ferrites for spintronics

Zinc oxide based material systems are considered as promising candidate for spintronic devices if it could be coupled in heterostructure with a suitable ferromagnetic material. We synthesized Zn, Mn and Co substituted iron oxide powders and thin films using solution-based approaches. Structural properties of these materials were studied by X-ray diffraction, FT-IR and closed cycle SQUID for magnetic characterization. These studies indicates that Zn 1-x Co x Fe 2 O 4 , Mn 0.5 Zn 0.5 Fe 2 O 4 and CoFe 2 O 4 exhibited ferrimagnetic and superparamagnetic behavior, respectively, at room temperature. Superparamagnetic behavior in Mn 0.5 Zn 0.5 Fe 2 O 4 and CoFe 2 O 4 is attributed to the extremely small crystal size.