Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Two major energy-related problems confront the world in the next 50 years. First, increased worldwide competition for gradually depleting fossil fuel reserves (derived from past photosynthesis) will lead to higher costs, both monetarily and politically. Second, atmospheric CO_2 levels are at their highest recorded level since records began. Further increases are predicted to produce large and uncontrollable impacts on the world climate. These projected impacts extend beyond climate to ocean acidification, because the ocean is a major sink for atmospheric CO2.1 Providing a future energy supply that is secure and CO_2-neutral will require switching to nonfossil energy sources such as wind, solar, nuclear, and geothermal energy and developing methods for transforming the energy produced by these new sources into forms that can be stored, transported, and used upon demand.

[1]  Etsuko Fujita,et al.  Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes , 2013 .

[2]  Emily A. Carter,et al.  Electrochemical reactivities of pyridinium in solution: consequences for CO2 reduction mechanisms , 2013 .

[3]  R Morris Bullock,et al.  An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen. , 2013, Nature chemistry.

[4]  Stefan Wiese,et al.  High catalytic rates for hydrogen production using nickel electrocatalysts with seven-membered cyclic diphosphine ligands containing one pendant amine. , 2013, Journal of the American Chemical Society.

[5]  D. Spasyuk,et al.  Replacing phosphorus with sulfur for the efficient hydrogenation of esters. , 2013, Angewandte Chemie.

[6]  Jean-Michel Savéant,et al.  Catalysis of the electrochemical reduction of carbon dioxide. , 2013, Chemical Society reviews.

[7]  Victor S Batista,et al.  Functional Role of Pyridinium during Aqueous Electrochemical Reduction of CO2 on Pt(111). , 2013, The journal of physical chemistry letters.

[8]  Samantha Horvath,et al.  Theoretical Design of Molecular Electrocatalysts with Flexible Pendant Amines for Hydrogen Production and Oxidation. , 2013, The journal of physical chemistry letters.

[9]  Donghai Mei,et al.  Mechanistic studies of methanol synthesis over Cu from CO/CO2/H2/H2O mixtures: The source of C in methanol and the role of water , 2013 .

[10]  R. Thauer,et al.  Energy conservation via electron bifurcating ferredoxin reduction and proton/Na(+) translocating ferredoxin oxidation. , 2013, Biochimica et biophysica acta.

[11]  Jens K Nørskov,et al.  Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO2 Reduction to CO. , 2013, The journal of physical chemistry letters.

[12]  D. Byrne,et al.  Observation of the Fe-CN and Fe-CO vibrations in the active site of [NiFe] hydrogenase by nuclear resonance vibrational spectroscopy. , 2013, Angewandte Chemie.

[13]  R. Morris,et al.  Ester Hydrogenation Catalyzed by a Ruthenium(II) Complex Bearing an N-Heterocyclic Carbene Tethered with an “NH2” Group and a DFT Study of the Proposed Bifunctional Mechanism , 2013 .

[14]  M. Beller,et al.  Well-defined iron catalyst for improved hydrogenation of carbon dioxide and bicarbonate. , 2012, Journal of the American Chemical Society.

[15]  T. Rauchfuss,et al.  Synthetic models for the active site of the [FeFe]-hydrogenase: catalytic proton reduction and the structure of the doubly protonated intermediate. , 2012, Journal of the American Chemical Society.

[16]  H. Holden,et al.  The enzymes of biotin dependent CO2 metabolism: What structures reveal about their reaction mechanisms , 2012, Protein science : a publication of the Protein Society.

[17]  H. Jia,et al.  Nickel(II) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO , 2012 .

[18]  J. Savéant,et al.  A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst , 2012, Science.

[19]  Xiaofeng Zhang,et al.  Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-bridged complexes with divalent ions: anatomical variation of ligand features. , 2012, Inorganic chemistry.

[20]  Wesley H. Bernskoetter,et al.  Reductive functionalization of carbon dioxide to methyl acrylate at zerovalent tungsten. , 2012, Dalton transactions.

[21]  J. Bercaw,et al.  A versatile ligand platform that supports Lewis acid promoted migratory insertion. , 2012, Angewandte Chemie.

[22]  B. Hoffman,et al.  Modeling the signatures of hydrides in metalloenzymes: ENDOR analysis of a Di-iron Fe(μ-NH)(μ-H)Fe core. , 2012, Journal of the American Chemical Society.

[23]  Elizabeth L. Zeitler,et al.  Comparative Study of Imidazole and Pyridine Catalyzed Reduction of Carbon Dioxide at Illuminated Iron Pyrite Electrodes , 2012 .

[24]  R. Morris,et al.  The mechanism of efficient asymmetric transfer hydrogenation of acetophenone using an iron(II) complex containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 ligand: partial ligand reduction is the key. , 2012, Journal of the American Chemical Society.

[25]  R. Masel,et al.  In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide , 2012 .

[26]  E. Fujita,et al.  Second-coordination-sphere and electronic effects enhance iridium(III)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure , 2012 .

[27]  Y. Diskin‐Posner,et al.  Iron borohydride pincer complexes for the efficient hydrogenation of ketones under mild, base-free conditions: synthesis and mechanistic insight. , 2012, Chemistry.

[28]  S. Fukuzumi,et al.  Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure , 2012 .

[29]  J. Nørskov,et al.  The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts , 2012, Science.

[30]  R. Thauer,et al.  Electron Bifurcation Involved in the Energy Metabolism of the Acetogenic Bacterium Moorella thermoacetica Growing on Glucose or H2 plus CO2 , 2012, Journal of bacteriology.

[31]  Thomas F. Jaramillo,et al.  New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces , 2012 .

[32]  E. Carter,et al.  Theoretical insights into pyridinium-based photoelectrocatalytic reduction of CO2. , 2012, Journal of the American Chemical Society.

[33]  Matthew W Kanan,et al.  CO2 reduction at low overpotential on Cu electrodes resulting from the reduction of thick Cu2O films. , 2012, Journal of the American Chemical Society.

[34]  D. Dubois,et al.  Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic. , 2012, Angewandte Chemie.

[35]  C. Kubiak,et al.  Formate oxidation via β-deprotonation in [Ni(PR2NR′2)2(CH3CN)]2+ complexes , 2012 .

[36]  C. Kubiak,et al.  Homogeneous CO2 reduction by Ni(cyclam) at a glassy carbon electrode. , 2012, Inorganic chemistry.

[37]  Etsuko Fujita,et al.  Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures , 2012, Nature Chemistry.

[38]  T. Meyer,et al.  Selective electrocatalytic reduction of CO2 to formate by water-stable iridium dihydride pincer complexes. , 2012, Journal of the American Chemical Society.

[39]  Nigel S Scrutton,et al.  Good vibrations in enzyme-catalysed reactions. , 2012, Nature chemistry.

[40]  Adrian J Mulholland,et al.  Taking Ockham's razor to enzyme dynamics and catalysis. , 2012, Nature chemistry.

[41]  H. Jia,et al.  Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2 reduction catalysts. , 2012, Chemical Society reviews.

[42]  Yilin Hu,et al.  ATP-independent formation of hydrocarbons catalyzed by isolated nitrogenase cofactors. , 2012, Angewandte Chemie.

[43]  Kenji Sumida,et al.  Carbon dioxide capture in metal-organic frameworks. , 2012, Chemical reviews.

[44]  A. Brik,et al.  Targeting deubiquitinases enabled by chemical synthesis of proteins. , 2012, Journal of the American Chemical Society.

[45]  G. Parkin,et al.  Low temperature NMR spectroscopic investigation of a zinc bicarbonate compound: Thermodynamics of bicarbonate formation by insertion of CO2 into the zinc hydroxide bond of [TpBut,Me]ZnOH , 2012 .

[46]  S. Chakraborty,et al.  Catalytic properties of nickel bis(phosphinite) pincer complexes in the reduction of CO2 to methanol derivatives , 2012 .

[47]  Yihong Chen,et al.  Tin oxide dependence of the CO2 reduction efficiency on tin electrodes and enhanced activity for tin/tin oxide thin-film catalysts. , 2012, Journal of the American Chemical Society.

[48]  Yilin Hu,et al.  Vanadium nitrogenase: a two-hit wonder? , 2012, Dalton transactions.

[49]  B. Dennis,et al.  Electrocatalytic Reduction of Carbon Dioxide Using Pt/C-TiO2 Nanocomposite Cathode , 2012 .

[50]  C. Casey,et al.  Trimethylsilyl-Substituted Hydroxycyclopentadienyl Ruthenium Hydrides as Benchmarks to Probe Ligand and Metal Effects on the Reactivity of Shvo Type Complexes. , 2012, Organometallics.

[51]  n-Butyl isocyanide oxidation at the [NiFe4S4OHx] cluster of CO dehydrogenase , 2012, JBIC Journal of Biological Inorganic Chemistry.

[52]  D. Rees,et al.  Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor , 2011, Science.

[53]  Javier J. Concepcion,et al.  Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes. , 2011, Chemical communications.

[54]  P. Kenis,et al.  Ionic Liquid–Mediated Selective Conversion of CO2 to CO at Low Overpotentials , 2011, Science.

[55]  J. Fierro,et al.  Catalytic effects of ruthenium particle size on the Fischer–Tropsch Synthesis , 2011 .

[56]  Chelsea A. Huff,et al.  Cascade catalysis for the homogeneous hydrogenation of CO2 to methanol. , 2011, Journal of the American Chemical Society.

[57]  S. Bergens,et al.  A highly active catalyst for the hydrogenation of amides to alcohols and amines. , 2011, Angewandte Chemie.

[58]  Jeanne A. Stuckey,et al.  Hydrolytic catalysis and structural stabilization in a designed metalloprotein , 2011, Nature chemistry.

[59]  G. Fuchs.  Alternative pathways of carbon dioxide fixation: insights into the early evolution of life? , 2011, Annual review of microbiology.

[60]  Monte L. Helm,et al.  Electrocatalytic oxidation of formate by [Ni(P(R)2N(R')2)2(CH3CN)]2+ complexes. , 2011, Journal of the American Chemical Society.

[61]  Yilin Hu,et al.  Extending the Carbon Chain: Hydrocarbon Formation Catalyzed by Vanadium/Molybdenum Nitrogenases , 2011, Science.

[62]  Thomas Schaub,et al.  A process for the synthesis of formic acid by CO2 hydrogenation: thermodynamic aspects and the role of CO. , 2011, Angewandte Chemie.

[63]  Qi‐Lin Zhou,et al.  An additional coordination group leads to extremely efficient chiral iridium catalysts for asymmetric hydrogenation of ketones. , 2011, Angewandte Chemie.

[64]  G. Sawers,et al.  The respiratory molybdo-selenoprotein formate dehydrogenases of Escherichia coli have hydrogen: benzyl viologen oxidoreductase activity , 2011, BMC Microbiology.

[65]  Donghai Mei,et al.  Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O , 2011 .

[66]  David Milstein,et al.  Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO , 2011, Nature Chemistry.

[67]  N. M. Cerqueira,et al.  The mechanism of formate oxidation by metal-dependent formate dehydrogenases , 2011, JBIC Journal of Biological Inorganic Chemistry.

[68]  G. Olah,et al.  Anthropogenic chemical carbon cycle for a sustainable future. , 2011, Journal of the American Chemical Society.

[69]  Tao Wang,et al.  Moisture swing sorbent for carbon dioxide capture from ambient air. , 2011, Environmental science & technology.

[70]  M. Mavrikakis,et al.  Microkinetic analysis and mechanism of the water gas shift reaction over copper catalysts , 2011 .

[71]  O. Ishitani,et al.  Photochemical reduction of CO₂ using TiO₂: effects of organic adsorbates on TiO₂ and deposition of Pd onto TiO₂. , 2011, ACS applied materials & interfaces.

[72]  R. Morris,et al.  Low-valent ene-amido iron complexes for the asymmetric transfer hydrogenation of acetophenone without base. , 2011, Journal of the American Chemical Society.

[73]  N. Hazari,et al.  Secondary coordination sphere interactions facilitate the insertion step in an iridium(III) CO2 reduction catalyst. , 2011, Journal of the American Chemical Society.

[74]  M. Beller,et al.  Homogeneous catalysis using iron complexes: recent developments in selective reductions. , 2011, Chemical communications.

[75]  T. Rauchfuss,et al.  Mild redox complementation enables H2 activation by [FeFe]-hydrogenase models. , 2011, Journal of the American Chemical Society.

[76]  H. Dobbek.  Structural aspects of mononuclear Mo/W-enzymes , 2011 .

[77]  Lifen Yan,et al.  Photolysis of Hi-CO Nitrogenase - Observation of a Plethora of Distinct CO Species using Infrared Spectroscopy. , 2011, European journal of inorganic chemistry.

[78]  J. Bercaw,et al.  Heterobimetallic Complexes of Rhenium and Zinc: Potential Catalysts for Homogeneous Syngas Conversion , 2011 .

[79]  Gang Wu,et al.  High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt , 2011, Science.

[80]  D. Dubois,et al.  Incorporating peptides in the outer-coordination sphere of bioinspired electrocatalysts for hydrogen production. , 2011, Inorganic chemistry.

[81]  Howard J. Herzog,et al.  Electrochemically mediated separation for carbon capture , 2011 .

[82]  Peng Wang,et al.  CO2 separation using bipolar membrane electrodialysis , 2011 .

[83]  L. Seefeldt,et al.  Molybdenum Nitrogenase Catalyzes the Reduction and Coupling of CO to Form Hydrocarbons*♦ , 2011, The Journal of Biological Chemistry.

[84]  Masato M. Ito,et al.  Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand. , 2011, Journal of the American Chemical Society.

[85]  Manos Mavrikakis,et al.  Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation , 2011 .

[86]  Eric J. Dufek,et al.  Bench-scale electrochemical system for generation of CO and syn-gas , 2011 .

[87]  R. Langer,et al.  Efficient hydrogenation of ketones catalyzed by an iron pincer complex. , 2011, Angewandte Chemie.

[88]  Robert T McGibbon,et al.  Electrocatalytic carbon dioxide activation: the rate-determining step of pyridinium-catalyzed CO2 reduction. , 2011, ChemSusChem.

[89]  Garth J. Williams,et al.  Single mimivirus particles intercepted and imaged with an X-ray laser , 2011, Nature.

[90]  C. Kerfeld,et al.  Comparative analysis of carboxysome shell proteins , 2011, Photosynthesis Research.

[91]  Anne-Kristin Kaster,et al.  Coupling of ferredoxin and heterodisulfide reduction via electron bifurcation in hydrogenotrophic methanogenic archaea , 2011, Proceedings of the National Academy of Sciences.

[92]  A. Volbeda,et al.  Carbon monoxide dehydrogenase reaction mechanism: a likely case of abnormal CO2 insertion to a Ni-H(-) bond. , 2011, Inorganic chemistry.

[93]  S. Ragsdale,et al.  Evidence that ferredoxin interfaces with an internal redox shuttle in Acetyl-CoA synthase during reductive activation and catalysis. , 2011, Biochemistry.

[94]  T. Ikariya.  Chemistry of Concerto Molecular Catalysis Based on the Metal/NH Bifunctionality , 2011 .

[95]  M. Lutz,et al.  Remote supramolecular control of catalyst selectivity in the hydroformylation of alkenes. , 2011, Angewandte Chemie.

[96]  C. Drennan,et al.  A role for nickel-iron cofactors in biological carbon monoxide and carbon dioxide utilization. , 2010, Current opinion in chemical biology.

[97]  R. Crabtree.  Multifunctional ligands in transition metal catalysis , 2011 .

[98]  T. Rauchfuss,et al.  Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase. , 2011, Nature chemistry.

[99]  Howard J. Herzog,et al.  Feasibility of air capture , 2011 .

[100]  J. Mayer,et al.  Thermochemistry of proton-coupled electron transfer reagents and its implications. , 2010, Chemical reviews.

[101]  P. Kenis,et al.  Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction , 2010 .

[102]  R. Morris,et al.  The hydrogenation of molecules with polar bonds catalyzed by a ruthenium(II) complex bearing a chelating N-heterocyclic carbene with a primary amine donor. , 2010, Chemical communications.

[103]  T. Rauchfuss,et al.  Hydride-containing models for the active site of the nickel-iron hydrogenases. , 2010, Journal of the American Chemical Society.

[104]  K. Hardcastle,et al.  Redox-active ligand-mediated oxidative addition and reductive elimination at square planar cobalt(III): multielectron reactions for cross-coupling. , 2010, Journal of the American Chemical Society.

[105]  M. Beller,et al.  Ruthenium-catalyzed hydrogenation of bicarbonate in water. , 2010, ChemSusChem.

[106]  C. Kubiak,et al.  Re(bipy-tBu)(CO)3Cl-improved catalytic activity for reduction of carbon dioxide: IR-spectroelectrochemical and mechanistic studies. , 2010, Inorganic chemistry.

[107]  S. Ragsdale,et al.  Infrared and EPR spectroscopic characterization of a Ni(I) species formed by photolysis of a catalytically competent Ni(I)-CO intermediate in the acetyl-CoA synthase reaction. , 2010, Biochemistry.

[108]  C. Peden,et al.  Non)formation of Methanol by Direct Hydrogenation of Formate on Copper Catalysts , 2010 .

[109]  Matthew Thorum,et al.  A carbon-supported copper complex of 3,5-diamino-1,2,4-triazole as a cathode catalyst for alkaline fuel cell applications. , 2010, Journal of the American Chemical Society.

[110]  B. Smit,et al.  Carbon dioxide capture: prospects for new materials. , 2010, Angewandte Chemie.

[111]  F. Woodward,et al.  Terrestrial Gross Carbon Dioxide Uptake: Global Distribution and Covariation with Climate , 2010, Science.

[112]  Ping Liu,et al.  Fundamental studies of methanol synthesis from CO(2) hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001). , 2010, Physical chemistry chemical physics : PCCP.

[113]  Yilin Hu,et al.  Vanadium Nitrogenase Reduces CO , 2010, Science.

[114]  Emily Barton Cole,et al.  Using a one-electron shuttle for the multielectron reduction of CO2 to methanol: kinetic, mechanistic, and structural insights. , 2010, Journal of the American Chemical Society.

[115]  E. Peris,et al.  '(eta(6)-arene)Ru(bis-NHC)' complexes for the reduction of CO(2) to formate with hydrogen and by transfer hydrogenation with iPrOH. , 2010, Dalton transactions.

[116]  E. Hegg,et al.  Bisamidate and mixed amine/amidate NiN2S2 complexes as models for nickel-containing acetyl coenzyme A synthase and superoxide dismutase: an experimental and computational study. , 2010, Inorganic chemistry.

[117]  Manos Mavrikakis,et al.  CO activation pathways and the mechanism of Fischer–Tropsch synthesis , 2010 .

[118]  G. Mul,et al.  Artificial photosynthesis over crystalline TiO2-based catalysts: fact or fiction? , 2010, Journal of the American Chemical Society.

[119]  S. Stahl.  Organotransition Metal Chemistry: From Bonding to Catalysis , 2010 .

[120]  A. Bard.  Inner-sphere heterogeneous electrode reactions. Electrocatalysis and photocatalysis: the challenge. , 2010, Journal of the American Chemical Society.

[121]  F. Matthias Bickelhaupt,et al.  Catalyst selection based on intermediate stability measured by mass spectrometry , 2010, Nature Chemistry.

[122]  Deguang Huang,et al.  Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged site. , 2010, Journal of the American Chemical Society.

[123]  P. Silver,et al.  Spatially Ordered Dynamics of the Bacterial Carbon Fixation Machinery , 2010, Science.

[124]  Paul Alivisatos,et al.  Basic Research Needs for Carbon Capture: Beyond 2020 , 2010 .

[125]  Yuji Koga,et al.  A new aspect of nickel-catalyzed Grignard cross-coupling reactions: selective synthesis, structure, and catalytic behavior of a T-shape three-coordinate nickel(I) chloride bearing a bulky NHC ligand. , 2010, Chemical communications.

[126]  R. Hille,et al.  Kinetic and Spectroscopic Studies of the Molybdenum-Copper CO Dehydrogenase from Oligotropha carboxidovorans* , 2010, The Journal of Biological Chemistry.

[127]  M. Aresta.  Carbon dioxide as chemical feedstock , 2010 .

[128]  G. Jensen,et al.  Organization, structure, and assembly of alpha-carboxysomes determined by electron cryotomography of intact cells. , 2010, Journal of Molecular Biology.

[129]  Somnath C. Roy,et al.  Toward solar fuels: photocatalytic conversion of carbon dioxide to hydrocarbons. , 2010, ACS nano.

[130]  R. McKenna,et al.  Sequestration of carbon dioxide by the hydrophobic pocket of the carbonic anhydrases. , 2010, Biochimica et biophysica acta.

[131]  A. Majumdar,et al.  Reactions of monodithiolene tungsten(VI) sulfido complexes with copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase. , 2010, Inorganic chemistry.

[132]  J. Ferry.  The gamma class of carbonic anhydrases. , 2010, Biochimica et biophysica acta.

[133]  Cheryl A Kerfeld,et al.  Carboxysomal carbonic anhydrases: Structure and role in microbial CO2 fixation. , 2010, Biochimica et biophysica acta.

[134]  Erwin Reisner,et al.  Efficient and clean photoreduction of CO(2) to CO by enzyme-modified TiO(2) nanoparticles using visible light. , 2010, Journal of the American Chemical Society.

[135]  Andrew B. Bocarsly,et al.  Photochemical, Electrochemical, and Photoelectrochemical Reduction of Carbon Dioxide , 2010 .

[136]  Stephane E. Castel,et al.  Structural basis of the oxidative activation of the carboxysomal γ-carbonic anhydrase, CcmM , 2010, Proceedings of the National Academy of Sciences.

[137]  T. Williams,et al.  Discovery, applications, and catalytic mechanisms of Shvo's catalyst. , 2010, Chemical reviews.

[138]  Douglas W Stephan,et al.  Room temperature reduction of CO2 to methanol by Al-based frustrated Lewis pairs and ammonia borane. , 2010, Journal of the American Chemical Society.

[139]  A. Spek,et al.  Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex , 2010, Science.

[140]  Devin T. Whipple.  Microfluidic reactor for the electrochemical reduction of carbon dioxide , 2010 .

[141]  Dermot O'Hare,et al.  Non-metal-mediated homogeneous hydrogenation of CO2 to CH3OH. , 2009, Angewandte Chemie.

[142]  J. Hartwig.  Organotransition Metal Chemistry: From Bonding to Catalysis , 2009 .

[143]  Mei Wang,et al.  Preparation, facile deprotonation, and rapid H/D exchange of the mu-hydride diiron model complexes of the [FeFe]-hydrogenase containing a pendant amine in a chelating diphosphine ligand. , 2009, Inorganic chemistry.

[144]  E. Fujita,et al.  Molecular approaches to the photocatalytic reduction of carbon dioxide for solar fuels. , 2009, Accounts of chemical research.

[145]  K. Polyakov,et al.  Atomic Resolution Crystal Structure of NAD+-Dependent Formate Dehydrogenase from Bacterium Moraxella sp. C-1 , 2009, Acta naturae.

[146]  M. Yamashita,et al.  Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes. , 2009, Journal of the American Chemical Society.

[147]  Cheryl A Kerfeld,et al.  Identification and structural analysis of a novel carboxysome shell protein with implications for metabolite transport. , 2009, Journal of molecular biology.

[148]  K. Lackner.  Capture of carbon dioxide from ambient air , 2009 .

[149]  R. Fröhlich,et al.  Reversible metal-free carbon dioxide binding by frustrated Lewis pairs. , 2009, Angewandte Chemie.

[150]  Patricia Amara,et al.  Structure–function relationships of anaerobic gas-processing metalloenzymes , 2009, Nature.

[151]  Daniel L DuBois,et al.  Development of molecular electrocatalysts for CO2 reduction and H2 production/oxidation. , 2009, Accounts of chemical research.

[152]  H. Dobbek,et al.  Structural basis of cyanide inhibition of Ni, Fe-containing carbon monoxide dehydrogenase. , 2009, Journal of the American Chemical Society.

[153]  B. Wenk,et al.  (14)N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge. , 2009, Physical chemistry chemical physics : PCCP.

[154]  Robert H Morris,et al.  Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes. , 2009, Chemical Society reviews.

[155]  David W. Keith,et al.  Low-energy sodium hydroxide recovery for CO2 capture from atmospheric air—Thermodynamic analysis , 2009 .

[156]  K. Djinović-Carugo,et al.  Structural study of X-ray induced activation of carbonic anhydrase , 2009, Proceedings of the National Academy of Sciences.

[157]  L. Seefeldt,et al.  Mechanism of Mo-dependent nitrogenase. , 2009, Annual review of biochemistry.

[158]  L. Seefeldt,et al.  Climbing nitrogenase: toward a mechanism of enzymatic nitrogen fixation. , 2009, Accounts of chemical research.

[159]  C. Pickett,et al.  Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases. , 2009, Chemical reviews.

[160]  M. Fujita,et al.  Functional molecular flasks: new properties and reactions within discrete, self-assembled hosts. , 2009, Angewandte Chemie.

[161]  Scott C. Doney,et al.  Ocean acidification: the other CO2 problem. , 2009, Annual review of marine science.

[162]  C. Casey,et al.  Cyclopentadienone iron alcohol complexes: synthesis, reactivity, and implications for the mechanism of iron-catalyzed hydrogenation of aldehydes. , 2009, Journal of the American Chemical Society.

[163]  K. Sowers,et al.  The archetype gamma-class carbonic anhydrase (Cam) contains iron when synthesized in vivo. , 2009, Biochemistry.

[164]  P. Lindahl.  4:Nickel-Carbon Bonds in Acetyl-Coenzyme A Synthases/Carbon Monoxide Dehydrogenases , 2009 .

[165]  K. Karlin,et al.  Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. , 2009, Metal ions in life sciences.

[166]  R. Morris,et al.  Efficient asymmetric transfer hydrogenation of ketones catalyzed by an iron complex containing a P-N-N-P tetradentate ligand formed by template synthesis. , 2009, Journal of the American Chemical Society.

[167]  T. Rauchfuss,et al.  Small molecule mimics of hydrogenases: hydrides and redox. , 2009, Chemical Society reviews.

[168]  Aaron J. Sathrum,et al.  Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels. , 2009, Chemical Society reviews.

[169]  T. Rauchfuss,et al.  Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases. , 2008, Journal of the American Chemical Society.

[170]  S. Ragsdale,et al.  Acetogenesis and the Wood-Ljungdahl pathway of CO(2) fixation. , 2008, Biochimica et biophysica acta.

[171]  Chae Un Kim,et al.  Entrapment of Carbon Dioxide in the Active Site of Carbonic Anhydrase II*♦ , 2008, Journal of Biological Chemistry.

[172]  W. Dougherty,et al.  Binuclear complexes containing a methylnickel moiety: relevance to organonickel intermediates in acetyl coenzyme A synthase catalysis. , 2008, Journal of the American Chemical Society.

[173]  J. Bercaw,et al.  Reductive coupling of carbon monoxide in a rhenium carbonyl complex with pendant Lewis acids. , 2008, Journal of the American Chemical Society.

[174]  Donghai Mei,et al.  Isotope Effects in Methanol Synthesis and the Reactivity of Copper Formates on a Cu/SiO2 Catalyst , 2008 .

[175]  T. Reda,et al.  Reversible interconversion of carbon dioxide and formate by an electroactive enzyme , 2008, Proceedings of the National Academy of Sciences.

[176]  I. Rayment,et al.  Structure, mechanism and regulation of pyruvate carboxylase. , 2008, The Biochemical journal.

[177]  J. Savéant.  Molecular catalysis of electrochemical reactions. Mechanistic aspects. , 2008, Chemical reviews.

[178]  S. Ragsdale,et al.  13C NMR Characterization of an Exchange Reaction between CO and CO2 Catalyzed by Carbon Monoxide Dehydrogenase† , 2008, Biochemistry.

[179]  C. Schofield,et al.  Mechanisms and structures of crotonase superfamily enzymes – How nature controls enolate and oxyanion reactivity , 2008, Cellular and Molecular Life Sciences.

[180]  M. Badger,et al.  Advances in understanding the cyanobacterial CO2-concentrating-mechanism (CCM): functional components, Ci transporters, diversity, genetic regulation and prospects for engineering into plants. , 2008, Journal of experimental botany.

[181]  Andrew B. Bocarsly,et al.  Selective solar-driven reduction of CO2 to methanol using a catalyzed p-GaP based photoelectrochemical cell. , 2008, Journal of the American Chemical Society.

[182]  S. Ragsdale,et al.  Xenon in and at the end of the tunnel of bifunctional carbon monoxide dehydrogenase/acetyl-CoA synthase. , 2008, Biochemistry.

[183]  Michael R. Thompson,et al.  Basic Research Needs: Catalysis for Energy , 2008 .

[184]  David W Keith,et al.  Carbon dioxide capture from atmospheric air using sodium hydroxide spray. , 2008, Environmental science & technology.

[185]  I. Andersson,et al.  Structure and function of Rubisco. , 2008, Plant physiology and biochemistry : PPB.

[186]  S. Ragsdale.  Enzymology of the Wood–Ljungdahl Pathway of Acetogenesis , 2008, Annals of the New York Academy of Sciences.

[187]  H. Drake,et al.  Old Acetogens, New Light , 2008, Annals of the New York Academy of Sciences.

[188]  R. Morris,et al.  Highly efficient catalyst systems using iron complexes with a tetradentate PNNP ligand for the asymmetric hydrogenation of polar bonds. , 2008, Angewandte Chemie.

[189]  Joost N H Reek,et al.  Reactivity within a confined self-assembled nanospace. , 2008, Chemical Society reviews.

[190]  Y. Hori,et al.  Electrochemical CO 2 Reduction on Metal Electrodes , 2008 .

[191]  Timothy E. Fout,et al.  Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program ☆ , 2008 .

[192]  T. Smejkal,et al.  A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids. , 2008, Angewandte Chemie.

[193]  Jae-Hun Jeoung,et al.  Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase , 2007, Science.

[194]  S. Ragsdale,et al.  Nickel and the carbon cycle. , 2007, Journal of inorganic biochemistry.

[195]  C. Saudan,et al.  Dihydrogen reduction of carboxylic esters to alcohols under the catalysis of homogeneous ruthenium complexes: high efficiency and unprecedented chemoselectivity. , 2007, Angewandte Chemie.

[196]  John Newman,et al.  Design of an Electrochemical Cell Making Syngas ( CO + H2 ) from CO2 and H2O Reduction at Room Temperature , 2007 .

[197]  Frank Zeman,et al.  Energy and material balance of CO2 capture from ambient air. , 2007, Environmental science & technology.

[198]  Grant J Jensen,et al.  The structure of isolated Synechococcus strain WH8102 carboxysomes as revealed by electron cryotomography. , 2007, Journal of molecular biology.

[199]  Yvain Nicolet,et al.  Structure/function relationships of [NiFe]- and [FeFe]-hydrogenases. , 2007, Chemical reviews.

[200]  W. Lubitz,et al.  [NiFe] and [FeFe] hydrogenases studied by advanced magnetic resonance techniques. , 2007, Chemical reviews.

[201]  Y. Himeda.  Conversion of CO2 into Formate by Homogeneously Catalyzed Hydrogenation in Water: Tuning Catalytic Activity and Water Solubility through the Acid–Base Equilibrium of the Ligand , 2007 .

[202]  Scott R. Wilson,et al.  Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenase. , 2007, Angewandte Chemie.

[203]  Takao Saito,et al.  Developments in asymmetric hydrogenation from an industrial perspective. , 2007, Accounts of chemical research.

[204]  F. Armstrong,et al.  Rapid and efficient electrocatalytic CO2/CO interconversions by Carboxydothermus hydrogenoformans CO dehydrogenase I on an electrode. , 2007, Journal of the American Chemical Society.

[205]  Martin A. J. Parry,et al.  Discoveries in Rubisco (Ribulose 1,5-bisphosphate carboxylase/oxygenase): a historical perspective , 2007, Photosynthesis Research.

[206]  C. Creutz,et al.  Rapid transfer of hydride ion from a ruthenium complex to C1 species in water. , 2007, Journal of the American Chemical Society.

[207]  M. Aresta,et al.  Utilisation of CO2 as a chemical feedstock: opportunities and challenges. , 2007, Dalton transactions.

[208]  W. Dougherty,et al.  Methyl transfer from methylcobaloxime to (triphos)Ni(PPh(3)): relevance to the mechanism of acetyl coenzyme A synthase. , 2007, Journal of the American Chemical Society.

[209]  Hiroyuki Yasuda,et al.  Transformation of carbon dioxide. , 2007, Chemical reviews.

[210]  T. Yeates,et al.  Structural Analysis of CsoS1A and the Protein Shell of the Halothiobacillus neapolitanus Carboxysome , 2007, PLoS Biology.

[211]  T. Liu,et al.  A mixed-valent, Fe(II)Fe(I), diiron complex reproduces the unique rotated state of the [FeFe]hydrogenase active site. , 2007, Journal of the American Chemical Society.

[212]  Wei Chu,et al.  Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. , 2007, Chemical reviews.

[213]  M. Korbas,et al.  Interaction of Potassium Cyanide with the [Ni-4Fe-5S] Active Site Cluster of CO Dehydrogenase from Carboxydothermus hydrogenoformans* , 2007, Journal of Biological Chemistry.

[214]  W. Chiu,et al.  Structure of Halothiobacillus neapolitanus carboxysomes by cryo-electron tomography. , 2006, Journal of molecular biology.

[215]  J. Reek,et al.  High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes. , 2006, Journal of the American Chemical Society.

[216]  G. Brudvig,et al.  Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst , 2006, Science.

[217]  I. Surovtsev,et al.  Mössbauer and EPR study of recombinant acetyl-CoA synthase from Moorella thermoacetica. , 2006, Biochemistry.

[218]  D. Dubois,et al.  Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex , 2006 .

[219]  T. Rauchfuss,et al.  Synthetic Models for Bioorganometallic Reaction Centers , 2006 .

[220]  C. G. Young,et al.  Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. , 2006, Journal of the American Chemical Society.

[221]  G. Olah.  Beyond oil and gas: the methanol economy. , 2006, Angewandte Chemie.

[222]  T. Harrop,et al.  Structural and spectroscopic models of the A-cluster of acetyl coenzyme a synthase/carbon monoxide dehydrogenase: Nature's Monsanto acetic acid catalyst , 2005 .

[223]  A. Volbeda,et al.  Structural bases for the catalytic mechanism of Ni-containing carbon monoxide dehydrogenases. , 2005, Dalton transactions.

[224]  K. Polyakov,et al.  Structure of a new crystal modification of the bacterial NAD-dependent formate dehydrogenase with a resolution of 2.1 Å , 2005 .

[225]  S. Ragsdale,et al.  EPR and infrared spectroscopic evidence that a kinetically competent paramagnetic intermediate is formed when acetyl-coenzyme A synthase reacts with CO. , 2005, Journal of the American Chemical Society.

[226]  Martin Phillips,et al.  Protein Structures Forming the Shell of Primitive Bacterial Organelles , 2005, Science.

[227]  Y. Ohki,et al.  Sulfido-bridged dinuclear molybdenum-copper complexes related to the active site of CO dehydrogenase: [(dithiolate)Mo(O)S2Cu(SAr)]2- (dithiolate = 1,2-S2C6H4, 1,2-S2C6H2-3,6-Cl2, 1,2-S2C2H4). , 2005, Inorganic chemistry.

[228]  I. Andersson,et al.  Chimeric small subunits influence catalysis without causing global conformational changes in the crystal structure of ribulose-1,5-bisphosphate carboxylase/oxygenase. , 2005, Biochemistry.

[229]  Per E. M. Siegbahn,et al.  Quantum chemical modeling of CO oxidation by the active site of molybdenum CO dehydrogenase , 2005, J. Comput. Chem..

[230]  M. Hofmann,et al.  The mechanism of Mo-/Cu-dependent CO dehydrogenase , 2005, JBIC Journal of Biological Inorganic Chemistry.

[231]  F. Morel,et al.  Biochemistry: A cadmium enzyme from a marine diatom , 2005, Nature.

[232]  D. Dubois,et al.  Concentration of carbon dioxide by electrochemically modulated complexation with a binuclear copper complex. , 2005, Inorganic chemistry.

[233]  Alexander Zapf,et al.  Homogeneous Catalysis. Understanding the Art. Von Piet W. N. M. van Leeuwen. , 2005 .

[234]  D. Fiedler,et al.  Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels. , 2004, Accounts of chemical research.

[235]  R. Morris,et al.  Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes , 2004 .

[236]  K. Kakiuchi,et al.  Evolution of carbonylation catalysis: no need for carbon monoxide. , 2004, Angewandte Chemie.

[237]  James M Mayer,et al.  Proton-coupled electron transfer: a reaction chemist's view. , 2004, Annual review of physical chemistry.

[238]  S. Ragsdale,et al.  Evidence that NiNi acetyl-CoA synthase is active and that the CuNi enzyme is not. , 2004, Biochemistry.

[239]  E. Álvarez,et al.  CO Insertion Reactions into the M−OH Bonds of Monomeric Nickel and Palladium Hydroxides. Reversible Decarbonylation of a Hydroxycarbonyl Palladium Complex , 2004 .

[240]  Gerard Parkin,et al.  Synthetic analogues relevant to the structure and function of zinc enzymes. , 2004, Chemical reviews.

[241]  J. Reek,et al.  Encapsulation of transition metal catalysts by ligand-template directed assembly. , 2004, Journal of the American Chemical Society.

[242]  S. Ragsdale.  Life with Carbon Monoxide , 2004, Critical reviews in biochemistry and molecular biology.

[243]  A. Portis.  Rubisco activase – Rubisco's catalytic chaperone , 2004, Photosynthesis Research.

[244]  B. Buchanan,et al.  A reverse KREBS cycle in photosynthesis: consensus at last , 2004, Photosynthesis Research.

[245]  Gábor Papp,et al.  Homogeneous hydrogenation of carbon dioxide and bicarbonate in aqueous solution catalyzed by water-soluble ruthenium(II) phosphine complexes , 2003 .

[246]  R. Schenker,et al.  Computational studies on the A cluster of acetyl-coenzyme A synthase: geometric and electronic properties of the NiFeC species and mechanistic implications. , 2003, Journal of the American Chemical Society.

[247]  P. Jessop,et al.  High-pressure combinatorial screening of homogeneous catalysts: hydrogenation of carbon dioxide. , 2003, Inorganic chemistry.

[248]  Zhongyuan Zhou,et al.  Synthesis, characterization and reactivity of heterobimetallic complexes (η5-C5R5)Ru(CO)(μ-dppm)M(CO)2(η5-C5H5)(R = H, CH3; M = Mo, W). Interconversion of hydrogen/carbon dioxide and formic acid by these complexes , 2003 .

[249]  Xiangshi Tan,et al.  Inactivation of acetyl-CoA synthase/carbon monoxide dehydrogenase by copper. , 2003, Journal of the American Chemical Society.

[250]  Scott R. Wilson,et al.  Structural analogues of the bimetallic reaction center in acetyl CoA synthase: a Ni--Ni model with bound CO. , 2003, Journal of the American Chemical Society.

[251]  Y. Kai,et al.  Phosphoenolpyruvate carboxylase: three-dimensional structure and molecular mechanisms. , 2003, Archives of biochemistry and biophysics.

[252]  R. Noble,et al.  Electrochemical Separation and Concentration of <1% Carbon Dioxide from Nitrogen , 2003 .

[253]  Paul A. Lindahl,et al.  Ni-Zn-[Fe4-S4] and Ni-Ni-[Fe4-S4] clusters in closed and open α subunits of acetyl-CoA synthase/carbon monoxide dehydrogenase , 2003, Nature Structural Biology.

[254]  Liang Tong,et al.  Crystal Structure of the Carboxyltransferase Domain of Acetyl-Coenzyme A Carboxylase , 2003, Science.

[255]  R. Huber,et al.  Catalysis at a dinuclear [CuSMo(O)OH] cluster in a CO dehydrogenase resolved at 1.1-Å resolution , 2002, Proceedings of the National Academy of Sciences of the United States of America.

[256]  E. V. Slivinskii,et al.  Hydrogenation of CO2 to formic acid in the presence of the Wilkinson complex , 2002 .

[257]  R. Huber,et al.  Gene sequence and the 1.8 A crystal structure of the tungsten-containing formate dehydrogenase from Desulfovibrio gigas. , 2002, Structure.

[258]  Ryoji Noyori,et al.  Asymmetric catalysis: science and opportunities (Nobel lecture). , 2002, Angewandte Chemie.

[259]  P. Jessop,et al.  Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of certain alcohols and amines. , 2002, Journal of the American Chemical Society.

[260]  E. Fujita,et al.  Reduction of cobalt and iron corroles and catalyzed reduction of CO2 , 2002 .

[261]  D. H. Gibson,et al.  Hydride donor abilities and bond dissociation free energies of transition metal formyl complexes. , 2002, Journal of the American Chemical Society.

[262]  Trevor Platt,et al.  Primary productivity of planet earth: biological determinants and physical constraints in terrestrial and aquatic habitats , 2001 .

[263]  J. Reek,et al.  Assembly of Encapsulated Transition Metal Catalysts. , 2001, Angewandte Chemie.

[264]  G. Kiss.  Palladium-catalyzed Reppe carbonylation. , 2001, Chemical reviews.

[265]  O. Meyer,et al.  Two Membrane-Associated NiFeS-Carbon Monoxide Dehydrogenases from the Anaerobic Carbon-Monoxide-Utilizing EubacteriumCarboxydothermus hydrogenoformans , 2001, Journal of bacteriology.

[266]  J. E. Lyons,et al.  Catalysis research of relevance to carbon management: progress, challenges, and opportunities. , 2001, Chemical reviews.

[267]  V. Fernández,et al.  Crystallographic and FTIR spectroscopic evidence of changes in Fe coordination upon reduction of the active site of the Fe-only hydrogenase from Desulfovibrio desulfuricans. , 2001, Journal of the American Chemical Society.

[268]  E. Dinjus,et al.  Electrochemical synthesis of carboxylic acids from alkenes using various nickel-organic mediators : CO2 as C1-synthon , 2001 .

[269]  H M Holden,et al.  The crotonase superfamily: divergently related enzymes that catalyze different reactions involving acyl coenzyme a thioesters. , 2001, Accounts of chemical research.

[270]  D. Dubois,et al.  Hydricity of transition‐metal hydrides and its role in CO2 reduction , 2000 .

[271]  B. Maden.  Tetrahydrofolate and tetrahydromethanopterin compared: functionally distinct carriers in C1 metabolism. , 2000, The Biochemical journal.

[272]  P. Curmi,et al.  The transition between the open and closed states of rubisco is triggered by the inter-phosphate distance of the bound bisphosphate. , 2000, Journal of molecular biology.

[273]  R. Puddephatt,et al.  The interconversion of formic acid and hydrogen/carbon dioxide using a binuclear ruthenium complex catalyst , 2000 .

[274]  Hans Schulz,et al.  Short history and present trends of Fischer–Tropsch synthesis , 1999 .

[275]  E. Fujita,et al.  P-TERPHENYL-SENSITIZED PHOTOREDUCTION OF CO2 WITH COBALT AND IRON PORPHYRINS. INTERACTION BETWEEN CO AND REDUCED METALLOPORPHYRINS , 1999 .

[276]  G. Waldrop,et al.  Mutations at four active site residues of biotin carboxylase abolish substrate-induced synergism by biotin. , 1999, Biochemistry.

[277]  S. Godtfredsen,et al.  Ullmann ' s Encyclopedia of Industrial Chemistry , 2017 .

[278]  Meyer Steinberg,et al.  Greenhouse gas carbon dioxide mitigation: Science and technology , 1998 .

[279]  R. Thauer.  Biochemistry of methanogenesis: a tribute to Marjory Stephenson. 1998 Marjory Stephenson Prize Lecture. , 1998, Microbiology.

[280]  Lijuan Li,et al.  An electrochemical and spectroelectrochemical (IR) investigation of the reduction of RCo(II)TPP (R=benzyl or butyl; TPP=tetraphenylporphyrin): mechanistic implications in the CoTPP catalyzed electrocarboxylation of alkyl halides , 1998 .

[281]  F. C. Hartman,et al.  Mechanism of Rubisco: The Carbamate as General Base. , 1998, Chemical reviews.

[282]  V. Gladyshev,et al.  Selenium-containing formate dehydrogenase H from Escherichia coli: a molybdopterin enzyme that catalyzes formate oxidation without oxygen transfer. , 1998, Biochemistry.

[283]  C. Colangelo,et al.  X-ray Absorption Spectroscopy of the Molybdenum Site of Escherichia coli Formate Dehydrogenase , 1998 .

[284]  A. Deronzier,et al.  Selective Synthesis and Electrochemical Behavior of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)2Cl2] Complexes (bpy = 2,2‘-Bipyridine). Comparative Studies of Their Electrocatalytic Activity toward the Reduction of Carbon Dioxide , 1997 .

[285]  Enrique Iglesia,et al.  Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts , 1997 .

[286]  L. Furenlid,et al.  Direct XANES Evidence for Charge Transfer in Co−CO2 Complexes , 1997 .

[287]  G. Jenner.  Applied homogeneous catalysis with organometallic compounds , 1997 .

[288]  P. Lindahl,et al.  METHYLATION OF CARBON MONOXIDE DEHYDROGENASE FROM CLOSTRIDIUM THERMOACETICUM AND MECHANISM OF ACETYL COENZYME A SYNTHESIS , 1997 .

[289]  and Ryoji Noyori,et al.  Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes , 1997 .

[290]  Kenneth M. Merz,et al.  Binding of Bicarbonate to Human Carbonic Anhydrase II: A Continuum of Binding States , 1997 .

[291]  D. Dubois.  Development of transition metal phosphine complexes as electrocatalysts for CO2 and CO reduction , 1997 .

[292]  R. Eady.  Structure−Function Relationships of Alternative Nitrogenases , 1996 .

[293]  B. Burgess,et al.  Mechanism of Molybdenum Nitrogenase. , 1996, Chemical reviews.

[294]  D. H. Gibson,et al.  The Organometallic Chemistry of Carbon Dioxide. , 1996, Chemical reviews.

[295]  Wolfgang A. Herrmann,et al.  Applied Homogeneous Catalysis with Organometallic Compounds , 1996 .

[296]  C. Campbell,et al.  Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity , 1996 .

[297]  K. Schaber,et al.  Methanol from atmospheric carbon dioxide : A liquid zero emission fuel for the future , 1996 .

[298]  J. Vidal,et al.  PHOSPHOENOLPYRUVATE CARBOXYLASE: A Ubiquitous, Highly Regulated Enzyme in Plants. , 1996, Annual review of plant physiology and plant molecular biology.

[299]  J. Savéant,et al.  Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins: Synergystic Effect of Weak Brönsted Acids , 1996 .

[300]  P. Jessop,et al.  HOMOGENEOUS CATALYSIS IN SUPERCRITICAL FLUIDS : HYDROGENATION OF SUPERCRITICAL CARBON DIOXIDE TO FORMIC ACID, ALKYL FORMATES, AND FORMAMIDES , 1996 .

[301]  Kiyotsuna Toyohara,et al.  Ruthenium Formyl Complexes as the Branch Point in Two- and Multi-Electron Reductions of CO2 , 1995 .

[302]  D. Dubois,et al.  Electrochemical Reduction of CO2 Catalyzed by a Dinuclear Palladium Complex Containing a Bridging Hexaphosphine Ligand: Evidence for Cooperativity , 1995 .

[303]  R. Mitchell,et al.  Engineering Rubisco to change its catalytic properties , 1995 .

[304]  B. Brunschwig,et al.  Mechanistic and kinetic studies of cobalt macrocycles in a photochemical CO2 reduction system: Evidence of Co-CO2 adducts as intermediates , 1995 .

[305]  F. Raushel,et al.  Three-dimensional structure of the binuclear metal center of phosphotriesterase. , 1995, Biochemistry.

[306]  M. Specht,et al.  CO2 recycling for hydrogen storage and transportation —Electrochemical CO2 removal and fixation , 1995 .

[307]  Robert P. Hausinger,et al.  The crystal structure of urease from Klebsiella aerogenes. , 1995, Science.

[308]  C. Kelly,et al.  The Thermodynamics and Kinetics of CO2 and H+ Binding to Ni(cyclam)+ in Aqueous Solution , 1995 .

[309]  D. Dubois,et al.  Exclusion of Six-Coordinate Intermediates in the Electrochemical Reduction of CO2 Catalyzed by [Pd(triphosphine)(CH3CN)](BF4)2 Complexes , 1994 .

[310]  A. Bell,et al.  Infrared Studies of the Mechanism of Methanol Decomposition on Cu/SiO2 , 1994 .

[311]  R. Sanzenbacher,et al.  High Electrocatalytic Activity of RRSS-[NiIIHTIM](ClO4)2 and [NiIIDMC](ClO4)2 for Carbon Dioxide Reduction (HTIM = 2,3,9,10-Tetramethyl-1,4,8,11-tetraazacyclotetradecane, DMC = C-meso-5,12-Dimethyl-1,4,8,11-tetraazacyclotetradecane) , 1994 .

[312]  A. Deronzier,et al.  Formation of Polymeric [{Ru0(bpy)(CO)2}n] Films by Electrochemical Reduction of [Ru(bpy)2(CO)2](PF6)2: Its Implication in CO2 Electrocatalytic Reduction , 1994 .

[313]  Toshio Tsukamoto,et al.  Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media , 1994 .

[314]  Andrew B. Bocarsly,et al.  A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential , 1994 .

[315]  H. Gasteiger,et al.  Temperature‐Dependent Methanol Electro‐Oxidation on Well‐Characterized Pt‐Ru Alloys , 1994 .

[316]  A. Deronzier,et al.  Electrocatalytic Reduction of Carbon Dioxide with Mono(bipyridine)carbonylruthenium Complexes in Solution or as Polymeric Thin Films , 1994 .

[317]  Susumu Kuwabata,et al.  Electrochemical conversion of carbon dioxide to methanol with the assistance of formate dehydrogenase and methanol dehydrogenase as biocatalysts , 1994 .

[318]  J. Savéant,et al.  Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst , 1994 .

[319]  P. Christensen,et al.  Growth and electrochemical behaviour of a poly [tricarbonyl(vinylbipyridyl)rhenium chloride] film. Heterogeneous reduction of CO2 , 1994 .

[320]  M. Badger,et al.  The Role of Carbonic Anhydrase in Photosynthesis , 1994 .

[321]  B. Brunschwig,et al.  Carbon dioxide activation by cobalt macrocycles: evidence of hydrogen bonding between bound CO2 and the macrocycle in solution , 1993 .

[322]  J. C. Smart,et al.  Chapter 4 – ELECTROCHEMICAL CONCENTRATION OF CARBON DIOXIDE , 1993 .

[323]  B. P. Sullivan,et al.  Electrochemical and electrocatalytic reactions of carbon dioxide , 1993 .

[324]  B. P. Sullivan,et al.  Electrocatalytic reduction of carbon dioxide based on 2,2'-bipyridyl complexes of osmium , 1992 .

[325]  A. P. Davis,et al.  Hydrosilylation-allylation sequence for the stereoselective elaboration of .beta.-hydroxy esters. [Erratum to document cited in CA116(15):151863y] , 1992 .

[326]  H. Abruña,et al.  Electrocatalytic reduction of carbon dioxide with iron, cobalt, and nickel complexes of terdentate ligands , 1992 .

[327]  Y. Soong,et al.  Methyl formate hydrogenolysis for low-temperature methanol synthesis , 1992 .

[328]  C. Amatore,et al.  Carbon dioxide as a C1 building block. Mechanism of palladium-catalyzed carboxylation of aromatic halides , 1992 .

[329]  W. Leitner,et al.  Direct formation of formic acid from carbon dioxide and dihydrogen using the [{Rh(cod)Cl}2]–Ph2P(CH2)4PPh2 catalyst system , 1992 .

[330]  A. Gennaro,et al.  Electrochemical reduction of carbon dioxide catalyzed by [CoI(salophen)Li] , 1991 .

[331]  A. Aramata,et al.  Electrocatalytic activity of CoII TPP-pyridine complex modified carbon electrode for CO2 reduction , 1991 .

[332]  D. Dubois,et al.  Electrochemical reduction of CO2 catalyzed by [Pd(triphosphine)(solvent)](BF4)2 complexes : synthetic and mechanistic studies , 1991 .

[333]  J. Savéant,et al.  Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations , 1991 .

[334]  J. Périchon,et al.  From stoichiometry to catalysis: electroreductive coupling of alkynes and carbon dioxide with nickel-bipyridine complexes. Magnesium ions as the key for catalysis , 1991 .

[335]  W. Cleland,et al.  Secondary 15N isotope effects on the reactions catalyzed by alcohol and formate dehydrogenases. , 1991, Biochemistry.

[336]  J. Wishart,et al.  Thermodynamics and kinetics of carbon dioxide binding to two stereoisomers of a cobalt(I) macrocycle in aqueous solution , 1991 .

[337]  C. Amatore,et al.  Activation of carbon dioxide by electron transfer and transition metals. Mechanism of nickel-catalyzed electrocarboxylation of aromatic halides , 1991 .

[338]  S. Ragsdale,et al.  Characterization of the Ni-Fe-C complex formed by reaction of carbon monoxide with the carbon monoxide dehydrogenase from Clostridium thermoaceticum by Q-band ENDOR. , 1991, Biochemistry.

[339]  E. Fujita,et al.  Carbon dioxide activation by cobalt(I) macrocycles: Factors affecting CO2 and CO binding , 1991 .

[340]  B. P. Sullivan,et al.  Formation of a metal-hydride bond and the insertion of CO2 key steps in the electrocatalytic reduction of carbon dioxide to formate anion , 1991 .

[341]  D. Darensbourg,et al.  Mechanistic studies of carbon dioxide insertion into metal hydrides and extrusion from the corresponding metal formates utilizing Group 6 metal carbonyl derivatives as reaction probes , 1990 .

[342]  D. Darensbourg,et al.  Mechanistic aspects of decarboxylation reactions of Group 10 metal formato hydrido tricyclohexylphosphine [(PCy3)2M(H)O2CH] derivatives , 1990 .

[343]  N. Lewis,et al.  Effects of redox potential, steric configuration, solvent, and alkali metal cations on the binding of carbon dioxide to cobalt(I) and nickel(I) macrocycles , 1990 .

[344]  S. Golunski,et al.  The role of hydrogen in methanol synthesis over copper catalysts , 1990 .

[345]  P. Ludden,et al.  Nickel is required for the transfer of electrons from carbon monoxide to the iron-sulfur center(s) of carbon monoxide dehydrogenase from Rhodospirillum rubrum. , 1989, Biochemistry.

[346]  D. H. Gibson,et al.  Synthesis of alkoxymethyl complexes from metal formyls , 1989 .

[347]  Jean-Pierre Sauvage,et al.  Electrochemical reduction of carbon dioxide mediated by molecular catalysts , 1989 .

[348]  H. Abruña,et al.  Electrocatalytic activity of electropolymerized films of bis(vinylterpyridine)cobalt(2+) for the reduction of carbon dioxide and oxygen , 1989 .

[349]  N. Furuya,et al.  Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines , 1989 .

[350]  J. Knowles.  The mechanism of biotin-dependent enzymes. , 1989, Annual review of biochemistry.

[351]  A. Cutler,et al.  Carbon monoxide and carbon dioxide fixation: relevant C1 and C2 ligand reactions emphasizing (.eta.5-C5H5)Fe-containing complexes , 1988 .

[352]  Y. Kharitonov,et al.  Metal-carboxylic Acids and Their Derivatives , 1988 .

[353]  G. Chinchen,et al.  Mechanism of methanol synthesis from CO2/CO/H2 mixtures over copper/zinc oxide/alumina catalysts: use of14C-labelled reactants , 1987 .

[354]  Koji Tanaka,et al.  Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO- , 1987 .

[355]  M. D. Hatch,et al.  C4 photosynthesis: a unique elend of modified biochemistry, anatomy and ultrastructure , 1987 .

[356]  Raymond Ziessel,et al.  Photochemical and Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (2,2′‐Bipyridine)tricarbonylchlororhenium(I) and Related Complexes as Homogeneous Catalysts , 1986 .

[357]  J. Sauvage,et al.  Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process. , 1986, Journal of the American Chemical Society.

[358]  B. P. Sullivan,et al.  Kinetics and mechanism of CO2 insertion into a metal-hydride bond. A large solvent effect and an inverse kinetic isotope effect , 1986 .

[359]  D. Pletcher,et al.  A study of the mechanism for the electrocatalysis of carbon dioxide reduction by nickel and cobalt square planar complexes in solution , 1986 .

[360]  S. Ragsdale,et al.  Evidence that an iron-nickel-carbon complex is formed by reaction of CO with the CO dehydrogenase from Clostridium thermoaceticum. , 1985, Proceedings of the National Academy of Sciences of the United States of America.

[361]  S. Gambino,et al.  Sacrificial Anodes in the Electrocarboxylation of Organic Chlorides , 1984 .

[362]  S. Gambino,et al.  Electrocarboxylation of styrene through homogeneous redox catalysis , 1984 .

[363]  N. Lewis,et al.  Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine , 1984 .

[364]  J. Fauvarque,et al.  Electrosynthese catalytique d'acides benzoiques para-substitues a partir du derive halogene correspondant et de l'anhydride carbonique , 1984 .

[365]  S. Ragsdale,et al.  Properties of purified carbon monoxide dehydrogenase from Clostridium thermoaceticum, a nickel, iron-sulfur protein. , 1983, The Journal of biological chemistry.

[366]  G. Lorimer,et al.  Carbamate formation on the epsilon-amino group of a lysyl residue as the basis for the activation of ribulosebisphosphate carboxylase by CO2 and Mg2+. , 1980, Biochemistry.

[367]  R. Eisenberg,et al.  Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt , 1980 .

[368]  W. Cleland,et al.  Kinetic and chemical mechanisms of yeast formate dehydrogenase. , 1980, Biochemistry.

[369]  E. M. Holt,et al.  KINETIC AND THERMODYNAMIC CONTROL OF THE METHYL MIGRATION (CARBON MONOXIDE INSERTION) REACTION BY STRONG LEWIS ACIDS , 1979 .

[370]  W. Wong,et al.  Neutral metal formyl complexes: generation, reactivity, and models for Fischer-Tropsch catalyst intermediates , 1979 .

[371]  C. Casey,et al.  Rhenium formyl and carboxyl complexes derived from the (C/sub 5/H/sub 5/)Re(CO)/sub 2/(NO)/sup +/ cation: models for the Fischer--Tropsch and water gas shift reactions , 1979 .

[372]  C. Floriani,et al.  Bifunctional activation of carbon dioxide. Synthesis and structure of a reversible carbon dioxide carrier , 1978 .

[373]  R. Hoffmann,et al.  Organometallic migration reactions , 1978 .

[374]  R. Burris,et al.  Interactions among substrates and inhibitors of nitrogenase , 1975, Journal of bacteriology.

[375]  R. Burris,et al.  Inhibition of nitrogenase-catalyzed reductions. , 1973, Biochimica et biophysica acta.

[376]  B. Buchanan,et al.  A new ferredoxin-dependent carbon reduction cycle in a photosynthetic bacterium. , 1966, Proceedings of the National Academy of Sciences of the United States of America.

[377]  M. Calvin,et al.  THE PATH OF CARBON IN PHOTOSYNTHESIS VIII. THE RÔLE OF MALIC ACID , 1950 .