论文信息 - Epidemiological Experience with the Magos' Reagents in the Determination of Different Forms of Mercury in Biological Samples by Flameless Atomic Absorption

Epidemiological Experience with the Magos' Reagents in the Determination of Different Forms of Mercury in Biological Samples by Flameless Atomic Absorption

Total mercury was determined by the introduction of CdCl/sub 2/ in the presence of SnCl/sub 2/ to break the mercury to carbon bond with subsequent reduction of Hg/sup 2 +/ to Hg/sup 0/ which is determined by a flameless atomic absorption method. Inorganic mercury is determined in the absence of CdCl/sub 2/, and the organic mercury is calculated by the difference between total and inorganic mercury. The preparation of samples of whole blood, hair, urine, tissue, fish, and sediment samples is described in detail. Results obtained by this cold vapor atomic absorption method are shown to be in good agreement with results obtained for mercury content of samples analyzed by gas chromatography, proton microprobe, and x-ray fluorescence.

[1] T W Clarkson,et al. Determination of total and inorganic mercury in hair by flameless atomic absorption, and of methylmercury by gas chromatography. , 1974, Clinical chemistry.

[2] T. Clarkson,et al. THE EXCRETION OF VOLATILE MERCURY BY RATS INJECTED WITH MERCURIC SALTS. , 1964, Health Physics.

[3] J. C. Smith,et al. Gas-chromatographic determination of inorganic mercury and organomercurials in biological materials. , 1977, Analytical chemistry.

[4] P. Horowitz,et al. Elemental analysis of biological specimens in air with a proton microprobe. , 1976, Science.

[5] L. Friberg,et al. Mercury in the environment: a toxicological and epidemiological appraisal , 1972 .

[6] T W Clarkson,et al. Methylmercury poisoning in Iraq. , 1973, Science.

[7] W. R. Smythe,et al. Medical Applications of a Small Sample X-Ray Fluorescence System , 1975 .

[8] T. Giovanoli-Jakubczak,et al. Measurement of mercury in human hair. , 1974, Archives of environmental health.

[9] S. Jc,et al. A simple and rapid procedure for the gas-chromatographic determination of methylmercury in biological samples , 1978 .

[10] T W Clarkson,et al. Atomic absorption determination of total, inorganic, and organic mercury in blood. , 1972, Journal - Association of Official Analytical Chemists.