Effect of Heat-Treat Methods on the Soluble Calcium Levels in the Commercial Milk Products

Milk is well known to be rich in some nutrients such as protein, calcium, phosphorus, and vitamins. In particular, absorptionand bioavailability of calcium receive lots of attention because calcium is very little absorbed until it is changed to the ion-ized form in the intestine. In this study, concentration of the soluble calcium was determined in the commercial bovine milkproducts, which were processed by different heat-treatment methods for pasteurization. As for general constituents, lactose,fat, protein, and mineral were almost same in the liquid milk products by different processors. Ultrafiltration of the skimmedmilk caused little change in the permeate as for lactose content but both fat and protein decreased. pH values ranges from6.57-6.62 at room temperature and slightly increase after centrifugation, 10,000 g, 10 min. Rennet-coagulation activity wasthe lowest in the ultra high temperature (UHT-)milk compared to the low temperature long time (LTLT-) and high tempera-ture short time (HTST-)milk products. Each bovine milk products contains 1056.5-1111.3 mg/kg of Ca. The content of sulf-hydryl group was the lowest in raw milk compared to the commercial products tested. For the skimmed milks after ultrafil-tration with a membrane (Mw cut-off, 3 Kd), soluble Ca in the raw milk was highest at 450.2 mg/kg, followed by LTLT-milk336.4-345.1 mg/kg, HTST-milk 305.5-313.3 mg/kg, UHT-milk 370.3-380.2 mg/kg in the decreasing order. After secondaryultrafiltration with a membrane (Mw cut-off, 1 kD), total calcium in raw milk had a highest of 444.2 mg/kg, and those in themarket milk products. As follow: UHT-milk, 371.3 to 378.2 mg/kg; LTLT-milk, 333.3 to 342.2 mg/kg; HTST-milk 301.9 to311.2 mg/kg in a decreasing order.Key words: bovine milk, heat-treat method, soluble calcium, sulfhydryl group, ultrafiltration (UF)