Modulation of the Copper-Dioxygen Reactivity by Stereochemical Effect of Tetradentate Tripodal Ligands

Dioxygen reactivity of a copper(I) complex having a sterically hindered Me3-tpa and monooxygenase activity of its oxygenated species toward the ligand were significantly modulated by the presence of the 6-methyl group onto pyridyl group.

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