PREMChlor: Probabilistic Remediation Evaluation Model for Chlorinated Solvents

Abstract : A new probabilistic remediation model, Probabilistic Remediation Evaluation Model for Chlorinated solvents (PREMChlor), has been developed for simultaneously evaluating the effectiveness of source and plume remediation considering the uncertainties in all major parameters. This development was conducted as an Environmental Security Technology Certification Program (ESTCP) research project (ER-0704), which was a joint effort between Clemson University, GSI Environmental Inc., and Purdue University. The technical foundation of PREMChlor is the U.S. Environmental Protection Agency (USUSEPA) REMChlor (for Remediation Evaluation Model for Chlorinated solvents) model [Falta, 2008]. REMChlor is a significant improvement on existing chlorinated solvent transport models, because it can simultaneously account for both source and plume remediation. REMChlor includes a source model based on a power function relationship linking the source mass to the source discharge and an analytical plume model based on one-dimensional advection, with three-dimensional dispersion. The plume model simulates natural attenuation or plume remediation for parent and daughter compounds in the first-order sequential decay chain. Plume model also calculates the cancer risks posed by carcinogenic compounds assuming that the contaminated water is used in a house for drinking, bathing, and other household uses. PREMChlor is developed by linking the analytical model REMChlor to a Monte Carlo modeling package GoldSim via a FORTRAN Dynamic Link Library (DLL) application. In PREMChlor, all of the uncertain input parameters are treated as stochastic parameters represented by probability density functions (PDFs). The outputs from PREMChlor are probability distributions and summary statistics of the distributions. Cost analysis of common technologies for dense non-aqueouse phase liquid (DNAPL) source re

[1]  Huaicheng Guo,et al.  A Simulation-Assessment Modeling Approach for Analyzing Environmental Risks of Groundwater Contamination at Waste Landfill Sites , 2004 .

[2]  J. Kaluarachchi Groundwater contamination by organic pollutants : analysis and remediation , 2001 .

[3]  A. L. Wood,et al.  Technology integration for contaminated site remediation: clean-up goals and performance criteria. , 2002 .

[4]  Jianting Zhu,et al.  Simple screening models of NAPL dissolution in the subsurface. , 2004, Journal of contaminant hydrology.

[5]  Michael D. Annable,et al.  Innovative Subsurface Remediation: Field Testing of Physical, Chemical, and Characterization Technologies , 1999 .

[6]  P. Witherspoon,et al.  Numerical modeling of steam injection for the removal of nonaqueous phase liquids from the subsurface. 1. Numerical formulation , 1992 .

[7]  L. Bodri,et al.  Background and History of the Problem , 2007 .

[8]  M. Pieters,et al.  A Probabilistic Approach for Deriving Acceptable Human Intake Limits and Human Health Risks from Toxicological Studies: General Framework , 1998, Risk analysis : an official publication of the Society for Risk Analysis.

[9]  Lakshmi N. Reddi,et al.  Non-aqueous phase liquids (NAPLs) in subsurface environment : assessment and remediation : proceedings of the specialty conference held in conjunction with the ASCE National Convention, Washington, D.C., November 12-14, 1996 , 1996 .

[10]  L. Abriola,et al.  Soil and Groundwater Contamination: Nonaqueous Phase Liquids , 2006 .

[11]  Charles J. Newell,et al.  Analysis of DNAPL source-depletion costs at 36 field sites , 2005 .

[12]  Charles J. Newell,et al.  Planning-Level Source Decay Models to Evaluate Impact of Source Depletion on Remediation Time Frame , 2005 .

[13]  Charles J. Newell,et al.  BIOSCREEN: Natural Attenuation Decision Support System. User's Manual Version 1.3 , 1996 .

[14]  Eungyu Park,et al.  Evaluation of an upscaled model for DNAPL dissolution kinetics in heterogeneous aquifers , 2005 .

[15]  Bruce A Robinson,et al.  Performance assessment model development and analysis of radionuclide transport in the unsaturated zone, Yucca Mountain, Nevada. , 2003, Journal of contaminant hydrology.

[16]  Hailian Liang,et al.  Probabilistic remediation evaluation model for chlorinated solvents considering uncertainty , 2009 .

[17]  J. Jawitz,et al.  Comment on “Steady state mass transfer from single‐component dense nonaqueous phase liquids in uniform flow fields” by T. C. Sale and D. B. McWhorter , 2003 .

[18]  J. Jawitz,et al.  Groundwater contaminant flux reduction resulting from nonaqueous phase liquid mass reduction , 2005 .

[19]  Michael C Kavanaugh,et al.  The DNAPL Remediation Challenge: Is There a Case for Source Depletion? , 2003 .

[20]  Charles J. Newell,et al.  Performance of DNAPL Source Depletion Technologies at 59 Chlorinated Solvent‐Impacted Sites , 2006 .

[21]  R. Falta,et al.  Assessing impacts of partial mass depletion in DNAPL source zones: II. Coupling source strength functions to plume evolution. , 2005, Journal of contaminant hydrology.

[22]  Gordon H. Huang,et al.  An integrated fuzzy-stochastic modeling approach for risk assessment of groundwater contamination. , 2007, Journal of environmental management.

[23]  Eungyu Park,et al.  Modeling field‐scale dense nonaqueous phase liquid dissolution kinetics in heterogeneous aquifers , 2004 .

[24]  S. Steven Chang,et al.  Implementing Probabilistic Risk Assessment in USEPA Superfund Program , 1999 .

[25]  Ronald W Falta,et al.  Assessing the impacts of partial mass depletion in DNAPL source zones I. Analytical modeling of source strength functions and plume response. , 2005, Journal of contaminant hydrology.

[26]  Ronald W Falta,et al.  Methodology for Comparing Source and Plume Remediation Alternatives , 2008, Ground water.

[27]  P. A. Domenico,et al.  An analytical model for multidimensional transport of a decaying contaminant species , 1987 .

[28]  J. Jawitz,et al.  DNAPL source depletion: linking architecture and flux response. , 2006, Journal of contaminant hydrology.

[29]  Gary A. Pope,et al.  Chemical flooding compositional simulator , 1978 .

[30]  G. B. Davis,et al.  Natural attenuation of fuels and chlorinated solvents in the subsurface. , 2000 .