Catalyst control in a chiral borane-mediated aldol reaction. Both syn- and anti-aldols in almost optically pure state obtained from one racemic aldehyde

[1]  G. Pain,et al.  Reagent Control in the Aldol Addition Reaction of Chiral Boron Enolates with Chiral .alpha.-Amino Aldehydes. Total Synthesis of (3S,4S)-Statine , 1995 .

[2]  S. Kiyooka,et al.  Very short asymmetric synthesis of (1S, 3S, 5R)-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane via tandem enantioselective reactions promoted by one chiral borane , 1995 .

[3]  Takaomi Hayashi,et al.  Chiral Lewis Acid-Controlled Synthesis of Both Diastereomers. Enantioselective Synthesis of Both syn- and anti-2,3-Dihydroxy Ester Derivatives from the Same Starting Materials via Asymmetric Aldol Reactions by Choice of Chiral Ligands , 1995 .

[4]  E. Carreira,et al.  Catalytic, Enantioselective Aldol Additions with Methyl and Ethyl Acetate O-Silyl Enolates: A Chiral Tridentate Chelate as a Ligand for Titanium(IV) , 1994 .

[5]  Y. Hamada,et al.  Synthesis of the C13–C19 unit in the spiroketal fragment of calyculins , 1994 .

[6]  S. Kiyooka,et al.  Direct enantioselective synthesis of syn-1,3-diols by the reaction of aldehydes with enol silyl ethers in the presence of a chiral borane complex. Successive asymmetric aldol reaction and asymmetric reduction with one promoter , 1994 .

[7]  K. Mikami,et al.  Asymmetric Catalytic Aldol-type Reaction with Ketene Silyl Acetals: Possible Intervention of the Silatropic Ene Pathway , 1994 .

[8]  E. Corey,et al.  Enantioselective Mukaiyama-aldol and aldol-dihydropyrone annulation reactions catalyzed by a tryptophan-derived oxazaborolidine , 1992 .

[9]  S. Kiyooka,et al.  The catalytic asymmetric aldol reaction of silyl ketene acetals with aldehydes in the presence of a chiral borane complex. Nitroethane as a highly effective solvent for catalytic conditions , 1992 .

[10]  E. Parmee,et al.  The catalytic asymmetric aldol reaction of aldehydes with unsubstituted and monosubstituted silyl ketene acetals: formation of anti-β-hydroxy-α-methyl esters , 1992 .

[11]  Emma R. Parmee,et al.  New catalysts for the asymmetric aldol reaction: chiral boranes prepared from .alpha.,.alpha.-disubstituted glycine arenesulfonamides , 1991 .

[12]  Isamu Shiina,et al.  Asymmetric aldol reaction between achiral silyl enol ethers and achiral aldehydes by use of a chiral promoter system , 1991 .

[13]  S. Kiyooka,et al.  Enantioselective chiral borane-mediated aldol reactions of silyl ketene acetals with aldehydes. The novel effect of the trialkysilyl group of the silyl ketene acetal on the reaction course , 1991 .

[14]  Clayton H. Heathcock,et al.  Acyclic stereoselection. 16. High diastereofacial selectivity in Lewis acid mediated additions of enol silanes to chiral aldehydes , 1983 .

[15]  D. Cram,et al.  Studies in Stereochemistry. X. The Rule of “Steric Control of Asymmetric Induction” in the Syntheses of Acyclic Systems , 1952 .

[16]  K. Furuta,et al.  CATALYTIC ASYMMETRIC ALDOL REACTIONS. USE OF A CHIRAL (ACYLOXY)BORANE COMPLEX AS A VERSATILE LEWIS ACID CATALYST , 1991 .

[17]  C. Heathcock,et al.  Acyclic stereoselection. 20. High diastereofacial selectivity in the stannic chloride mediated reactions of allylsilanes with chiral α- and β-alkoxy aldehydes. , 1983 .