Efficient Generation of Long‐Lived Triplet Excitons in 2D Hybrid Perovskite

Triplet excitons form in quasi-2D hybrid inorganic-organic perovskites and diffuse over 100 nm before radiating with >11% photoluminescence quantum efficiency (PLQE) at low temperatures.

[1]  D. Umeyama,et al.  Red-to-Black Piezochromism in a Compressible Pb–I–SCN Layered Perovskite , 2016 .

[2]  D. Mitzi,et al.  Inorganic Perovskites : Structural Versatility for Functional Materials Design , 2016 .

[3]  D. Mitzi,et al.  Photovoltaic Properties of Two-Dimensional (CH3NH3)2Pb(SCN)2I2 Perovskite: A Combined Experimental and Density Functional Theory Study. , 2016, The journal of physical chemistry letters.

[4]  F. Castellano,et al.  Direct observation of triplet energy transfer from semiconductor nanocrystals , 2016, Science.

[5]  Dahui Zhao,et al.  Developing efficient heavy-atom-free photosensitizers applicable to TTA upconversion in polymer films† †Electronic supplementary information (ESI) available: Synthetic procedures and characterization data. CCDC 1400097. For ESI and crystallographic data in CIF or other electronic format see DOI: 10. , 2015, Chemical science.

[6]  Vladimir Bulovic,et al.  Solid-state infrared-to-visible upconversion sensitized by colloidal nanocrystals , 2015, Nature Photonics.

[7]  Kai Zhu,et al.  Comparison of Recombination Dynamics in CH3NH3PbBr3 and CH3NH3PbI3 Perovskite Films: Influence of Exciton Binding Energy. , 2015, The journal of physical chemistry letters.

[8]  D. Scanlon,et al.  (CH3NH3)2Pb(SCN)2I2: a more stable structural motif for hybrid halide photovoltaics? , 2015, The journal of physical chemistry letters.

[9]  Yang Yang,et al.  Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications , 2015 .

[10]  Jacky Even,et al.  Photophysics of Organic–Inorganic Hybrid Lead Iodide Perovskite Single Crystals , 2015 .

[11]  Tien Khee Ng,et al.  The recombination mechanisms leading to amplified spontaneous emission at the true-green wavelength in CH3NH3PbBr3 perovskites , 2015 .

[12]  Marcus L. Böhm,et al.  Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals. , 2014, Nature materials.

[13]  Yasuhiro Yamada,et al.  Photocarrier recombination dynamics in perovskite CH3NH3PbI3 for solar cell applications. , 2014, Journal of the American Chemical Society.

[14]  Mohammad Khaja Nazeeruddin,et al.  Organohalide lead perovskites for photovoltaic applications , 2014 .

[15]  Nripan Mathews,et al.  Low-temperature solution-processed wavelength-tunable perovskites for lasing. , 2014, Nature materials.

[16]  Guglielmo Lanzani,et al.  Excitons versus free charges in organo-lead tri-halide perovskites , 2014, Nature Communications.

[17]  Jae-Hong Kim,et al.  [C70] fullerene-sensitized triplet-triplet annihilation upconversion. , 2013, Chemical communications.

[18]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[19]  Qian Liu,et al.  A general strategy for biocompatible, high-effective upconversion nanocapsules based on triplet-triplet annihilation. , 2013, Journal of the American Chemical Society.

[20]  K. Burgess,et al.  BODIPY dyes in photodynamic therapy. , 2013, Chemical Society reviews.

[21]  L. Feldman,et al.  Observation of long-range exciton diffusion in highly ordered organic semiconductors. , 2010, Nature materials.

[22]  F. Castellano,et al.  Pd(II) phthalocyanine-sensitized triplet-triplet annihilation from rubrene. , 2008, The journal of physical chemistry. A.

[23]  H. Makino,et al.  Localization of triplet excitons and biexcitons in the two-dimensional semiconductor ( C H 3 C 6 H 4 C H 2 N H 3 ) 2 Pb Br 4 , 2006 .

[24]  K. Asai,et al.  Electronic and Excitonic Structures of Inorganic–Organic Perovskite-Type Quantum-Well Crystal (C4H9NH3)2PbBr4 , 2005 .

[25]  Ruomei Gao,et al.  Bis-cyclometalated Ir(III) complexes as efficient singlet oxygen sensitizers. , 2002, Journal of the American Chemical Society.

[26]  M. Fujii,et al.  Resonant electronic energy transfer from excitons confined in silicon nanocrystals to oxygen molecules. , 2002, Physical review letters.

[27]  A. S. Dhoot,et al.  Spin-dependent exciton formation in π-conjugated compounds , 2001, Nature.

[28]  Maurizio Prato,et al.  Excited-State Properties of C60 Fullerene Derivatives , 2000 .

[29]  M. Era,et al.  Enhanced phosphorescence from naphthalene-chromophore incorporated into lead bromide-based layered perovskite having organic–inorganic superlattice structure , 1998 .

[30]  S. Forrest,et al.  Highly efficient phosphorescent emission from organic electroluminescent devices , 1998, Nature.

[31]  M. Ochsner Photophysical and photobiological processes in the photodynamic therapy of tumours. , 1997, Journal of photochemistry and photobiology. B, Biology.

[32]  Steven L. Murov,et al.  Handbook of photochemistry , 1973 .