Techno-economic and environmental assessment of an olive stone based biorefinery

Abstract Olive tree cultivation is spreading worldwide as a consequence of beneficial effects of olive oil consumption. Olive oil production process and table olive industries are the major sources of olive stones. Currently, this by-product is used in direct combustion to produce energy as electricity or heat. However, there are other possibilities for taking full advantage of a renewable source of interesting compounds. In this work the techno-economic and environmental assessment of two biorefinery schemes and its comparison with the direct combustion (base case) of this residue are presented. The first biorefinery scheme describes the integrated production of xylitol, furfural, ethanol and poly-3-hydroxybutyrate (PHB). The second biorefinery scheme considers the production of xylitol, furfural, ethanol and PHB integrated to a cogeneration system for producing bioenergy from the solid residues resulting from the mentioned processes. The results showed that in the first biorefinery scheme, the net profit margin is approximately 53%, while the second present a net profit margin of 6%.

[1]  J M Romero-García,et al.  Biorefinery based on olive biomass. State of the art and future trends. , 2014, Bioresource technology.

[2]  J. Parajó,et al.  Biotechnological production of xylitol. Part 2 : Operation in culture media made with commercial sugars , 1998 .

[3]  P. Arias,et al.  Production of furfural from pentosan-rich biomass: analysis of process parameters during simultaneous furfural stripping. , 2013, Bioresource technology.

[4]  Y. Chisti,et al.  A model of xylitol production by the yeast Candida mogii , 2005, Bioprocess and biosystems engineering.

[5]  P. Rogers,et al.  Mathematical modelling of ethanol production from glucose/xylose mixtures by recombinant Zymomonas mobilis , 2001, Biotechnology Letters.

[6]  Liang Qu,et al.  Kinetic characterization for hemicellulose hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor at moderate conditions , 2011 .

[7]  Mohammad J. Taherzadeh,et al.  Effect of pH, time and temperature of overliming on detoxification of dilute-acid hydrolyzates for fermentation by Saccharomyces cerevisiae , 2002 .

[8]  M. Balat,et al.  Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems , 2009 .

[9]  J. Fernández-Bolaños,et al.  Hydroxytyrosol and tyrosol as the main compounds found in the phenolic fraction of steam-exploded olive stones , 1998 .

[10]  Carlos A. Cardona,et al.  Techno-Economic Analysis of the Use of Fired Cogeneration Systems Based on Sugar Cane Bagasse in South Eastern and Mid-Western Regions of Mexico , 2014 .

[11]  M. Balat,et al.  Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 2: Gasification systems , 2009 .

[12]  Yousef S.H. Najjar,et al.  Gas turbine cogeneration systems : a review of some novel cycles , 2000 .

[13]  Mohammad J Taherzadeh,et al.  Kinetic study of detoxification of dilute-acid hydrolyzates by Ca(OH)2. , 2004, Journal of biotechnology.

[14]  A Martinez,et al.  Detoxification of Dilute Acid Hydrolysates of Lignocellulose with Lime , 2001, Biotechnology progress.

[15]  Shen Ning,et al.  High efficient conversion of CO2-rich bio-syngas to CO-rich bio-syngas using biomass char: a useful approach for production of bio-methanol from bio-oil. , 2011, Bioresource technology.

[16]  Mahmoud M El-Halwagi,et al.  Techno-economic analysis for a sugarcane biorefinery: Colombian case. , 2013, Bioresource technology.

[17]  C. Cardona,et al.  Analysis of technological schemes for the efficient production of added-value products from Colombian oleochemical feedstocks , 2014 .

[18]  W W Pitt,et al.  Recovery of ethanol from fermentation broths using selective sorption–desorption , 1983, Biotechnology and bioengineering.

[19]  John R. King,et al.  Recovery of Poly-β-Hydroxybutyrate from Estuarine Microflora , 1978 .

[20]  G. Cirillo,et al.  Olive stones as a source of antioxidants for food industry , 2011 .

[21]  Ferdi Schüth,et al.  Acid hydrolysis of cellulose as the entry point into biorefinery schemes. , 2009, ChemSusChem.

[22]  N. Grimi,et al.  VALORIZATION OF MOROCCAN OLIVE STONES BY USING IT IN PARTICLEBOARD PANELS , 2012 .

[23]  Shahrokh Shahhosseini,et al.  Simulation and optimisation of PHB production in fed-batch culture of Ralstonia eutropha , 2004 .