Research Update: Overview of progress about efficiency and stability on perovskite solar cells

Due to the high conversion efficiency, organic-inorganic hybrid perovskite (CH3NH3PbI3) solar cells are investigated for new practical energy resources for our future society. However, the perovskite solar cells have been quite unstable devices. In this manuscript, the history of perovskite solar cells is introduced, and then, the efforts to improve and understand the stability issue of perovskite solar cells are summarized.

[1]  Sang Il Seok,et al.  High-performance photovoltaic perovskite layers fabricated through intramolecular exchange , 2015, Science.

[2]  Seigo Ito,et al.  Effects of Surface Blocking Layer of Sb2S3 on Nanocrystalline TiO2 for CH3NH3PbI3 Perovskite Solar Cells , 2014 .

[3]  Y. Qi,et al.  Pinhole-free hole transport layers significantly improve the stability of MAPbI3-based perovskite solar cells under operating conditions , 2015 .

[4]  Ulrike Diebold,et al.  The surface science of titanium dioxide , 2003 .

[5]  Peter K. J. Robertson,et al.  In situ ATR-FTIR study of H2O and D2O adsorption on TiO2 under UV irradiation. , 2015, Physical chemistry chemical physics : PCCP.

[6]  H. L. Wells Über die Cäsium‐ und Kalium‐Bleihalogenide , 1893 .

[7]  T. Miyasaka,et al.  Stability of solution-processed MAPbI3 and FAPbI3 layers. , 2016, Physical chemistry chemical physics : PCCP.

[8]  Nam-Gyu Park,et al.  6.5% efficient perovskite quantum-dot-sensitized solar cell. , 2011, Nanoscale.

[9]  Young Chan Kim,et al.  Compositional engineering of perovskite materials for high-performance solar cells , 2015, Nature.

[10]  M. Grätzel,et al.  A hole-conductor–free, fully printable mesoscopic perovskite solar cell with high stability , 2014, Science.

[11]  J. Berry,et al.  Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys , 2016 .

[12]  Nam-Gyu Park,et al.  Stability Issues on Perovskite Solar Cells , 2015 .

[13]  Leone Spiccia,et al.  A fast deposition-crystallization procedure for highly efficient lead iodide perovskite thin-film solar cells. , 2014, Angewandte Chemie.

[14]  Aron Walsh,et al.  Ionic transport in hybrid lead iodide perovskite solar cells , 2015, Nature Communications.

[15]  H. Wenk,et al.  Minerals: Their Constitution and Origin , 2004 .

[16]  D. Mitzi,et al.  Synthesis, Resistivity, and Thermal Properties of the Cubic Perovskite NH2CH=NH2SnI3and Related Systems , 1997 .

[17]  M. Grätzel,et al.  Sequential deposition as a route to high-performance perovskite-sensitized solar cells , 2013, Nature.

[18]  N. Park,et al.  Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% , 2012, Scientific Reports.

[19]  Mohammad Khaja Nazeeruddin,et al.  Outdoor Performance and Stability under Elevated Temperatures and Long‐Term Light Soaking of Triple‐Layer Mesoporous Perovskite Photovoltaics , 2015 .

[20]  S. Ito,et al.  Substrate-preheating Effects on PbI2 Spin Coating for Perovskite Solar Cells via Sequential Deposition , 2015 .

[21]  D. Mitzi,et al.  Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets , 1995, Science.

[22]  S. Ito,et al.  Light stability tests of methylammonium and formamidinium Pb-halide perovskites for solar cell applications , 2015 .

[23]  Thomas Rath,et al.  The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers. , 2015, Angewandte Chemie.

[24]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.

[25]  Yongbo Yuan,et al.  Photovoltaic Switching Mechanism in Lateral Structure Hybrid Perovskite Solar Cells , 2015 .

[26]  P. Lund,et al.  Carbon-double-bond-free printed solar cells from TiO₂/CH₃NH₃PbI₃/CuSCN/Au: structural control and photoaging effects. , 2014, Chemphyschem : a European journal of chemical physics and physical chemistry.

[27]  H. Rensmo,et al.  Chemical and Electronic Structure Characterization of Lead Halide Perovskites and Stability Behavior under Different Exposures—A Photoelectron Spectroscopy Investigation , 2015 .

[28]  Juan Bisquert,et al.  Temperature Effects on the Photovoltaic Performance of Planar Structure Perovskite Solar Cells , 2015 .

[29]  Nam-Gyu Park,et al.  Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide. , 2015, Journal of the American Chemical Society.

[30]  Qingfeng Dong,et al.  Giant switchable photovoltaic effect in organometal trihalide perovskite devices. , 2015, Nature materials.

[31]  S. Ito,et al.  Material Exchange Property of Organo Lead Halide Perovskite with Hole-Transporting Materials , 2015 .

[32]  T. Miyasaka,et al.  100 °C Thermal Stability of Printable Perovskite Solar Cells Using Porous Carbon Counter Electrodes. , 2016, ChemSusChem.

[33]  Peng Gao,et al.  Efficient luminescent solar cells based on tailored mixed-cation perovskites , 2016, Science Advances.

[34]  Hironori Fujisawa,et al.  Light stability tests of CH3NH3PbI3 perovskite solar cells using porous carbon counter electrodes. , 2016, Physical chemistry chemical physics : PCCP.

[35]  J. Noh,et al.  Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells. , 2013, Nano letters.

[36]  Eric T. Hoke,et al.  A layered hybrid perovskite solar-cell absorber with enhanced moisture stability. , 2014, Angewandte Chemie.

[37]  Wei Chen,et al.  Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers , 2015, Science.

[38]  Sung Min Cho,et al.  Formamidinium and Cesium Hybridization for Photo‐ and Moisture‐Stable Perovskite Solar Cell , 2015 .

[39]  Tomas Leijtens,et al.  Carbon nanotube/polymer composites as a highly stable hole collection layer in perovskite solar cells. , 2014, Nano letters.

[40]  T. Miyasaka,et al.  HC(NH2)2PbI3 as a thermally stable absorber for efficient ZnO-based perovskite solar cells , 2016 .

[41]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[42]  Henry J. Snaith,et al.  Stability of Metal Halide Perovskite Solar Cells , 2015 .