Preparation and characterization of [Co(tp)2(Men-en)]+ (tp=tropolonate ion; Men-en (n=1−4)=N-methyl substituted ethylenediamine), inversion and deuteration at chiral nitrogen centers of [Co(tp)2(Me-en or Me3-en)]+, and crystal structures of [Co(tp)2(N,N-Me2-en)]ClO4 and Λ(R)Δ(S)-[Co(tp)2(Me-en)]ClO4