BLEVE prevention using vent devices

Abstract The main features of accidents involving BLEVEs (boiling liquid expanding vapour explosions) occurring in fires are analysed. Simple mathematical models describing liquid or vapour discharge through the perforation of vessels by superheated liquids and liquid behaviour in a vessel heated by fire are formulated. These models are verified on the basis of experimental data available in the literature. An analysis of the well known accident at Alma-Ata in 1989 is presented. This accident involved the BLEVE of a railway tank engulfed by fire, with the resulting formation of a fireball. It is shown that this accident could have been prevented by means of a vent device (safety valve or breaking diaphrgm) with cross-sectional area greater than 77 cm2 and operational pressure below 1.6 MPa. The use of such vent devices could prevent the occurrence of BLEVEs when tanks containing superheated liquids or liquefied gases are subjected to thermal loading from fires.

[1]  Antonio C. M. Sousa,et al.  Thermal response analysis of LPG tanks exposed to fire , 1988 .

[2]  V. C. Marshall Major Chemical Hazards , 1987 .

[3]  Antonio C. M. Sousa,et al.  A study of the effect of the tank diameter on the thermal stratification in LPG tanks subjected to fire engulfment , 1990 .

[4]  R. Reid,et al.  The Properties of Gases and Liquids , 1977 .

[5]  D. W. Sallet Critical two-phase mass flow rates of liquefied gases , 1990 .

[6]  A. M. Birk Modelling the response of tankers exposed to external fire impingement , 1988 .

[7]  L. T. Cowley,et al.  Fire engulement of LPG tanks: heatup, a predictive model , 1988 .

[8]  David Dancer,et al.  Pressure and temperature response of liquefied gases in containers and pressure vessels which are subjected to accidental heat input , 1990 .

[9]  K. Moodie,et al.  Experiments and modelling:- an overview with particular reference to fire engulfment , 1988 .

[10]  R C Reid,et al.  Possible Mechanism for Pressurized-Liquid Tank Explosions or BLEVE's , 1979, Science.

[11]  K. Moodie,et al.  Fire engulfment tests on a 5 tonne LPG tank , 1988 .

[12]  A. M. Birk,et al.  A computer simulation of a derailment accident: Part I - model basis , 1990 .

[13]  F. R. Steward,et al.  Initiation step of boiling liquid expanding vapour explosions , 1990 .

[14]  J. McQuaid,et al.  Heavy gas and risk assessment: edited by Sylvius Hartwig, published by D. Reidel Publishing Company, 1980 , 1981 .

[15]  A. M. Birk,et al.  State of the art review of pressure liquefied gas container failure modes and associated projectile hazards , 1991 .

[16]  A. M. Birk,et al.  The boiling liquid expanding vapour explosion , 1994 .