Recent advances in understanding the role of supplementary cementitious materials in concrete

Supplementary cementitious materials (SCMs) are commonly used in concrete mixtures as a replacement of a portion of clinker in cement or as a replacement of a portion of cement in concrete. This practice is favorable to the industry, generally resulting in concrete with lower cost, lower environmental impact, higher long-term strength, and improved long-term durability. SCMs have been used in Portland cement concrete for decades and many of their effects are well-understood. Most recent research on SCMs has focused on a few areas: exploring new materials, increasing replacement amounts, developing better test methods, treating or modifying materials, and using additives (e.g. limestone or nanosilica) to improve performance. The advances in knowledge provided by research in these areas are reviewed in this paper, emphasizing the impact of the research on the field.

[1]  M. Frías,et al.  The Influence of Slate Waste Activation Conditions on Mineralogical Changes and Pozzolanic Behavior , 2013 .

[2]  S. Dittrich,et al.  The influence of fly ash on the hydration of OPC within the first 44 h—A quantitative in situ XRD and heat flow calorimetry study , 2014 .

[3]  G. Sant,et al.  The rheological properties of ternary binders containing Portland cement, limestone, and metakaolin or fly ash , 2013 .

[4]  Surendra P. Shah,et al.  Dispersion of CaCO3 nanoparticles by sonication and surfactant treatment for application in fly ash–cement systems , 2014 .

[5]  Thuan T. Tran,et al.  Aluminum Incorporation in the C–S–H Phase of White Portland Cement–Metakaolin Blends Studied by 27Al and 29Si MAS NMR Spectroscopy , 2014 .

[6]  Hjh Jos Brouwers,et al.  Characterization of morphology and texture of several amorphous nano-silica particles used in concrete , 2013 .

[7]  T. Y. Lo,et al.  Mechanical performance, durability, qualitative and quantitative analysis of microstructure of fly ash and Metakaolin mortar at elevated temperatures , 2013 .

[8]  K. Scrivener,et al.  Alkali fixation of C-S-H in blended cement pastes and its relation to alkali silica reaction , 2012 .

[9]  G. Saoût,et al.  Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash , 2011 .

[10]  M. Cyr,et al.  Performance-based approach to durability of concrete containing flash-calcined metakaolin as cement replacement , 2014 .

[11]  J. Olek,et al.  Effects of Sample Preparation and Interpretation of Thermogravimetric Curves on Calcium Hydroxide in Hydrated Pastes and Mortars , 2012 .

[12]  Suk-Pyo Kang,et al.  Effect of sodium silicate- and ethyl silicate-based nano-silica on pore structure of cement composites , 2014 .

[13]  Michael A. Galler,et al.  Influence of particle size distributions on yield stress and viscosity of cement–fly ash pastes , 2012 .

[14]  Kyle A. Riding,et al.  Thermochemical pretreatments for agricultural residue ash production for concrete , 2013 .

[15]  A. Pourkhorshidi,et al.  Evaluation the pozzolanic reactivity of sonochemically fabricated nano natural pozzolan. , 2012, Ultrasonics sonochemistry.

[16]  Véronique Baroghel-Bouny,et al.  Chloride binding in sound and carbonated cementitious materials with various types of binder , 2014 .

[17]  J. Payá,et al.  Mineralogical evolution of Portland cement blended with silica nanoparticles and its effect on mechanical strength , 2012 .

[18]  Abang Abdullah Abang Ali,et al.  Effect of halloysite nanoclay on mechanical properties, thermal behavior and microstructure of cement mortars. , 2013 .

[19]  A.L.A. Fraaij,et al.  The study of using rice husk ash to produce ultra high performance concrete , 2011 .

[20]  Dietmar Stephan,et al.  The influence of nano-silica on the hydration of ordinary Portland cement , 2011, Journal of Materials Science.

[21]  U. Helbig,et al.  Primary particle size and agglomerate size effects of amorphous silica in ultra-high performance concrete , 2013 .

[22]  M. Juenger,et al.  Physical characterization methods for supplementary cementitious materials , 2014, Materials and Structures.

[23]  Kimberly E. Kurtis,et al.  Can nanotechnology be ‘green’? Comparing efficacy of nano and microparticles in cementitious materials , 2013 .

[24]  B. Samet,et al.  Effect of iron on pozzolanic activity of kaolin , 2013 .

[25]  Chunhua Shen,et al.  Effects of metakaolin, silica fume and slag on pore structure, interfacial transition zone and compressive strength of concrete , 2013 .

[26]  K. Scrivener,et al.  Methods for determination of degree of reaction of slag in blended cement pastes , 2012 .

[27]  A. Gastaldini,et al.  Total shrinkage, chloride penetration, and compressive strength of concretes that contain clear-colored rice husk ash , 2014 .

[28]  R. Snellings,et al.  In situ synchrotron X-ray powder diffraction study of the early age hydration of cements blended with zeolitite and quartzite fines and water-reducing agent , 2013 .

[29]  Wei Sun,et al.  Effects of nano-SiO2 particles on the mechanical and microstructural properties of ultra-high performance cementitious composites , 2015 .

[30]  R. Hooton,et al.  A study on hydration, compressive strength, and porosity of Portland-limestone cement mixes containing SCMs , 2014 .

[31]  R. N. Swamy,et al.  The effect of chlorides on the thaumasite form of sulfate attack of limestone cement concrete containing mineral admixtures at low temperature , 2013 .

[32]  W. Jason Weiss,et al.  Fine limestone additions to regulate setting in high volume fly ash mixtures , 2012 .

[33]  L. Raki,et al.  Reactivity of cement mixtures containing waste glass using thermal analysis , 2011 .

[34]  Hjh Jos Brouwers,et al.  Development of an eco-friendly Ultra-High Performance Concrete (UHPC) with efficient cement and mineral admixtures uses , 2015 .

[35]  A. Khaloo,et al.  The effects of a hydrochloric acid pre-treatment on the physicochemical properties and pozzolanic performance of rice husk ash , 2013 .

[36]  M. Martín-Pastor,et al.  Effect of Temperature on C3S and C3S + Nanosilica Hydration and C–S–H Structure , 2013 .

[37]  D. Bentz,et al.  Optimization of cement and fly ash particle sizes to produce sustainable concretes , 2011 .

[38]  Karen Scrivener,et al.  Cement substitution by a combination of metakaolin and limestone , 2012 .

[39]  B. Lothenbach,et al.  Hydration of Portland cement with high replacement by siliceous fly ash , 2012 .

[40]  D. Bentz Activation energies of high-volume fly ash ternary blends: Hydration and setting , 2014 .

[41]  R. García,et al.  Evolution of mineralogical phases produced during the pozzolanic reaction of different metakaolinite by-products: Influence of the activation process , 2012 .

[42]  H. Atahan,et al.  Use of mineral admixtures for enhanced resistance against sulfate attack , 2011 .

[43]  Antonio Nanni,et al.  Effect of off-white rice husk ash on strength, porosity, conductivity and corrosion resistance of white concrete , 2012 .

[44]  N. Buenfeld,et al.  Determining the slag fraction, water/binder ratio and degree of hydration in hardened cement pastes , 2014 .

[45]  F. Fernández-Martínez,et al.  TEM and SAED Characterization of Metakaolin. Pozzolanic Activity , 2012 .

[46]  Hesam Madani,et al.  The pozzolanic reactivity of monodispersed nanosilica hydrosols and their influence on the hydration characteristics of Portland cement , 2012 .

[47]  Alejandra Tironi,et al.  Assessment of pozzolanic activity of different calcined clays , 2013 .

[48]  C. Yin,et al.  Calcination of kaolinite clay particles for cement production: A modeling study , 2014 .

[49]  Yu Li,et al.  Improvement on pozzolanic reactivity of coal gangue by integrated thermal and chemical activation , 2013 .

[50]  Qijun Yu,et al.  Efficient utilization of cementitious materials to produce sustainable blended cement , 2012 .

[51]  Nataša Marjanović,et al.  External sulfate attack on alkali-activated slag , 2013 .

[52]  M. Frías,et al.  Scientific Aspects of Kaolinite Based Coal Mining Wastes in Pozzolan/Ca(OH)2 System , 2012 .

[53]  Chai Jaturapitakkul,et al.  Effect of W/B ratios on pozzolanic reaction of biomass ashes in Portland cement matrix , 2012 .

[54]  Karen L. Scrivener,et al.  The influence of aluminium on the dissolution of amorphous silica and its relation to alkali silica reaction , 2012 .

[55]  K. Riding,et al.  Use of bioethanol byproduct for supplementary cementitious material production , 2014 .

[56]  Mehmet Gesoǧlu,et al.  Strength, permeability and shrinkage cracking of silica fume and metakaolin concretes , 2012 .

[57]  M. Kunz,et al.  Characterization of morphology and hydration products of high-volume fly ash paste by monochromatic scanning x-ray micro-diffraction (μ-SXRD) , 2014 .

[58]  R. Snellings,et al.  Use of X-ray diffraction to quantify amorphous supplementary cementitious materials in anhydrous and hydrated blended cements , 2014 .

[59]  N. Belie,et al.  Performance of BFS concrete: k-Value concept versus equivalent performance concept , 2013 .

[60]  Chiara Leonardi,et al.  Modifications induced by the thermal treatment of kaolin and determination of reactivity of metakaolin , 2013 .

[61]  R. Hooton,et al.  Thaumasite sulfate attack in Portland and Portland-limestone cement mortars exposed to sulfate solution , 2013 .

[62]  J. Monzó,et al.  Assessment of the Pozzolanic Activity of a Spent Catalyst by Conductivity Measurement of Aqueous Suspensions with Calcium Hydroxide , 2014, Materials.

[63]  Tien-Tung Ngo,et al.  Evaluation of rheological parameters of mortar containing various amounts of mineral addition with polycarboxylate superplasticizer , 2014 .

[64]  J. Ninov,et al.  On the kinetics of pozzolanic reaction in metakaolin–lime–water system , 2011 .

[65]  Kyle A. Riding,et al.  The effect of zinc oxide additions on the performance of calcined sodium montmorillonite and illite shale supplementary cementitious materials , 2014 .

[66]  Rahmat Madandoust,et al.  Mechanical properties and durability assessment of rice husk ash concrete , 2011 .

[67]  Karen L. Scrivener,et al.  Straight talk with Karen Scrivener on cements, CO2 and sustainable development , 2012 .

[68]  R. Gettu,et al.  Beneficiation of Natural Zeolite through Flash Calcination for Its Use as a Mineral Admixture in Concrete , 2014 .

[69]  Karen Scrivener,et al.  The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite , 2011 .

[70]  D. Bui,et al.  Rice husk ash as both pozzolanic admixture and internal curing agent in ultra-high performance concrete , 2014 .

[71]  K. Yamada,et al.  Improvement on sulfate resistance of blended cement with high alumina slag , 2012 .

[72]  R. Vigil de la Villa,et al.  Evolution of the pozzolanic activity of a thermally treated zeolite , 2013, Journal of Materials Science.

[73]  R. Walker,et al.  Physical properties and reactivity of pozzolans, and their influence on the properties of lime–pozzolan pastes , 2011 .

[74]  Surendra P. Shah,et al.  Effects of colloidal nanosilica on rheological and mechanical properties of fly ash–cement mortar , 2013 .

[75]  Deyu Kong,et al.  Influence of nano-silica agglomeration on fresh properties of cement pastes , 2013 .

[76]  P. Nimityongskul,et al.  Effects of temperature and alkaline solution on electrical conductivity measurements of pozzolanic activity , 2011 .

[77]  N. Belie,et al.  Supplementary Cementitious Materials for Concrete: Characterization Needs , 2012 .

[78]  Kasım Mermerdaş,et al.  Experimental evaluation and modeling of drying shrinkage behavior of metakaolin and calcined kaolin blended concretes , 2013 .

[79]  Abang Abdullah Abang Ali,et al.  Characterization of high strength mortars with nano alumina at elevated temperatures , 2013 .

[80]  Arpad Horvath,et al.  Life-cycle inventory analysis of concrete production: A critical review , 2014 .

[81]  John A. Bickley,et al.  Design for durability: The key to improving concrete sustainability , 2014 .

[82]  P. Van den Heede,et al.  Environmental impact and life cycle assessment (LCA) of traditional and ‘green’ concretes: Literature review and theoretical calculations , 2012 .

[83]  Hjh Jos Brouwers,et al.  Effect of nano-silica on the hydration and microstructure development of Ultra-High Performance Concrete (UHPC) with a low binder amount , 2014 .

[84]  Muhammad Kalimur Rahman,et al.  Nanosilica effects on composition and silicate polymerization in hardened cement paste cured under high temperature and pressure , 2013 .

[85]  Xianming Shi,et al.  Strength and corrosion properties of Portland cement mortar and concrete with mineral admixtures , 2011 .

[86]  S. Kosmatka,et al.  Design and Control of Concrete Mixtures , 2002 .

[87]  R. Zerbino,et al.  Alkali–silica reaction in mortars and concretes incorporating natural rice husk ash , 2012 .

[88]  Shuangzhen Wang Quantitative kinetics of pozzolanic reactions in coal/cofired biomass fly ashes and calcium hydroxide (CH) mortars , 2014 .

[89]  Jeffrey W. Bullard,et al.  The Filler Effect: The Influence of Filler Content and Surface Area on Cementitious Reaction Rates , 2013 .

[90]  Rafat Siddique,et al.  Effect of metakaolin and foundry sand on the near surface characteristics of concrete , 2011 .

[91]  M. Palou,et al.  Investigation on early hydration of ternary Portland cement-blast-furnace slag–metakaolin blends , 2014 .

[92]  Gaurav Sant,et al.  Hydration and strength development in ternary portland cement blends containing limestone and fly ash or metakaolin , 2013 .

[93]  Barbara Lothenbach,et al.  Hydration of a low-alkali CEM III/B–SiO2 cement (LAC) , 2012 .

[94]  Kyle A. Riding,et al.  Increasing the reactivity of metakaolin-cement blends using zinc oxide , 2012 .

[95]  M. Cyr,et al.  Effect of cement type on metakaolin efficiency , 2014 .

[96]  T. Almusallam,et al.  Effect of nano-metakaolin addition on the hydration characteristics of fly ash blended cement mortar , 2014, Journal of Thermal Analysis and Calorimetry.

[97]  J. Provis,et al.  Structure of Portland Cement Pastes Blended with Sonicated Silica Fume , 2012 .

[98]  Sarah C. Taylor-Lange,et al.  Calcined kaolinite–bentonite clay blends as supplementary cementitious materials , 2015 .

[99]  Fang Liu,et al.  Preparation of Ultra-High Performance Concrete with common technology and materials , 2012 .

[100]  B. Lothenbach,et al.  Supplementary cementitious materials , 2011 .

[101]  Martin Schneider,et al.  Sustainable cement production—present and future , 2011 .

[102]  J. Tobón,et al.  An alternative thermal method for identification of pozzolanic activity in Ca(OH)2/pozzolan pastes , 2013, Journal of Thermal Analysis and Calorimetry.

[103]  G. Kakali,et al.  Use of mineral admixtures to improve the resistance of limestone cement concrete against thaumasite form of sulfate attack , 2013 .