Facile and convenient synthesis of functionalized propargylic alcohols and amines: an InBr3–Et3N reagent system promotes the alkynylation of aldehydes and N,O- or N,S-acetals

[1]  M. Shibasaki,et al.  A new entry in catalytic alkynylation of aldehydes and ketones: dual activation of soft nucleophiles and hard electrophiles by an indium(III) catalyst. , 2005, Organic letters.

[2]  A. Baba,et al.  Triethylsilane-indium(III) chloride system as a radical reagent. , 2004, Organic letters.

[3]  A. Katritzky,et al.  A Facile and Expedient Route to Allyl and Propargyl Amines Using N-(α-Benzotriazolylalkyl)amines as Stabilized Iminium Salts , 2004 .

[4]  T. Konakahara,et al.  Palladium-catalyzed coupling reaction of terminal alkynes with aryl iodides in the presence of indium tribromide and its application to a one-pot synthesis of 2-phenylindole. , 2004, Organic letters.

[5]  Y. Kawakami,et al.  Indium triflate-catalysed double addition of heterocyclic arenes to alkynes. , 2003, Chemical communications.

[6]  E. Nakamura,et al.  Indium-catalyzed addition of active methylene compounds to 1-alkynes. , 2003, Journal of the American Chemical Society.

[7]  T. Konakahara,et al.  InBr3-Et3N promoted alkynylation of aldehydes and N, O-acetals under mild conditions: facile and simple preparation of propargylic alcohols and amines , 2003 .

[8]  J. Podlech,et al.  Indium in Organic Synthesis , 2003 .

[9]  T. Konakahara,et al.  The aminomethylation of electron-rich aromatics with an N-silyl-N,O-acetal catalyzed by a metal triflate-TMSCl system: facile synthesis of aromatic primary amines, 1-aryl-trichloroethylamines. , 2003, The Journal of organic chemistry.

[10]  B. Jiang,et al.  Alkynylation of carbonyl compounds with terminal acetylenes promoted by ZnCl2 and Et3N: simple, mild and efficient preparation of propargylic alcohols , 2002 .

[11]  L. Pu,et al.  Highly enantioselective phenylacetylene additions to both aliphatic and aromatic aldehydes. , 2002, Organic letters.

[12]  J. Yadav,et al.  Indium tribromide-catalyzed highly stereoselective synthesis of alkynylsugars , 2002 .

[13]  P. Knochel,et al.  Enantioselective synthesis of propargylamines by copper-catalyzed addition of alkynes to enamines. , 2002, Angewandte Chemie.

[14]  T. Konakahara,et al.  Friedel–Crafts reaction of indoles with N-silyl-N,O-acetal catalyzed by Cu(OTf)2 in the presence of TMSCl leading to indolyl primary amines , 2002 .

[15]  M. Yasuda,et al.  ChemInform Abstract: Indium(III) Chloride/Chlorotrimethylsilane as a Highly Active Lewis Acid Catalyst System for the Sakurai-Hosomi Reaction. , 2002 .

[16]  Chao‐Jun Li,et al.  Highly efficient Grignard-type imine additions via C-H activation in water and under solvent-free conditions. , 2002, Chemical communications.

[17]  R. Mahrwald,et al.  TiCl4-mediated amination of propargylic esters , 2001 .

[18]  B. Ranu Indium Metal and Its Halides in Organic Synthesis , 2000 .

[19]  Xu,et al.  Synthesis of trifluoromethylated amines using 1,1-bis(dimethylamino)-2,2,2-trifluoroethane , 2000, The Journal of organic chemistry.

[20]  S. Tsuboi,et al.  Generation of Acetylides by Treatment of Fluoroethylenes with LDA: Preparation of Propargyl Alcohols , 2000 .

[21]  Takeshi Maeda,et al.  Friedel–Crafts alkenylation of arenes using alkynes catalysed by metal trifluoromethanesulfonates , 2000 .

[22]  C. Frost,et al.  Advances in indium-catalysed organic synthesis , 2000 .

[23]  Erick M. Carreira,et al.  Catalytic in Situ Generation of Zn(II)-Alkynilides under Mild Conditions: A Novel CN Addition Process Utilizing Terminal Acetylenes , 1999 .

[24]  A. Katritzky,et al.  A NEW METHOD OF SYNTHESIS FOR PROPARGYLIC AMINES AND ETHERS VIA BENZOTRIAZOLE DERIVATIVES USING SODIUM DIALKYNYLDIETHYLALUMINATES , 1999 .

[25]  A. Baba,et al.  Indium trichloride catalyzed reductive Friedel-Crafts alkylation of aromatics using carbonyl compounds , 1998 .

[26]  P. T. Perumal,et al.  Convenient synthesis of pyrano[3,2-c]quinolines and indeno[2,1-c] quinolines by imino Diels-Alder reactions , 1998 .

[27]  S. Dax,et al.  Mannich reactions of resin-bound substrates: 2. A versatile three-component solid-phase organic synthesis methodology , 1998 .

[28]  T. Loh,et al.  Novel one-pot Mannich-type reaction in water: Indium trichloride-catalyzed condensation of aldehydes, amines and silyl enol ethers for the synthesis of β-amino ketones and esters , 1998 .

[29]  R. Nomura,et al.  Solvent-controlled addition of alkynyltins or allylic tins to aldehydes catalyzed by indium trichloride , 1995 .

[30]  Yinglin Han,et al.  A straightforward, efficient and versatile preparation of propargylic alcohols from 1- alkynes and aldehydes via GaI3 and amine , 1995 .

[31]  N. Yoon,et al.  Sodium diethyldialkylaluminate, a new chemoselective alkynylating agent , 1995 .

[32]  K. Hinkle,et al.  Synthesis of anti-Homoallylic Alcohols and Monoprotected 1,2-Diols through InCl3-Promoted Addition of Allylic Stannanes to Aldehydes , 1995 .

[33]  M. Yamaguchi,et al.  Direct Formation of Reactive Alkynyltrichlorotins from 1-Alkynes, SnCl4, and Bu3N. A Mild Alkynylation Reagent of Aldehydes, Acetals, and Enones , 1992 .

[34]  J. Bradley,et al.  Synthesis of 2-benzylidenebenzocyclobutenones via an intramolecular Stille coupling reaction , 1991 .

[35]  M. Yamaguchi,et al.  Sn(OTf) 2 -Promoted Addition of 1-Alkynes to Aldehydes , 1991 .

[36]  T. Hirao,et al.  Versatile synthesis of α, β-acetylenic ketones by oxidative nucleophilic addition of vanadium acetylides , 1986 .

[37]  A. Katritzky,et al.  The preparation of some N- and S-acetals of benzaldehyde and terephthalaldehyde , 1986 .

[38]  M. Sekiya,et al.  Primary Aminomethylation at the α-Position of Carboxylic Acids and Esters. Trimethylsilyl Triflate-Catalyzed Reaction of Ketene Silyl Acetals with N, N-Bis (trimethylsilyl) methoxymethylamine , 1985 .

[39]  G. Molander,et al.  Organoboranes. 38. A facile and highly efficient addition of B-1-alkynyl-9-borabicyclo[3.3.1]nonanes to aldehydes and ketones: an exceptionally chemoselective synthesis of propargylic alcohols , 1985 .

[40]  S. Cacchi,et al.  The palladium-catalysed reductive addition of aryl iodides to propargyl alcohols: a route to /gg,/gg-diaryl allylic alcohols , 1985 .

[41]  T. Imamoto,et al.  Organocerium reagents. Nucleophilic addition to easily enolizable ketones , 1985 .

[42]  B. Jousseaume,et al.  A Convenient Synthesis of N,N-Disubstituted Aminomethyltri-n-butylstannanes, Precursors of the Corresponding Lithium Reagents , 1984 .

[43]  M. Domalski,et al.  Reactions of allylic Grignard reagents and unsaturated amines , 1981 .

[44]  J. Glasby Encyclopedia of the Alkaloids , 1975, Springer US.