The universal limit in dynamics of dilute polymeric solutions

The method of invariant manifold is developed for a derivation of reduced description in kinetic equations of dilute polymeric solutions. It is demonstrated that this reduced description becomes universal in the limit of small Deborah and Weissenberg numbers, and it is represented by the (revised) Oldroyd 8 constants constitutive equation for the polymeric stress tensor. Coefficients of this constitutive equation are expressed in terms of the microscopic parameters. A systematic procedure of corrections to the revised Oldroyd 8 constants equations is developed. Results are tested with simple flows.

[1]  Tosio Kato Perturbation theory for linear operators , 1966 .

[2]  T. G. Cowling,et al.  The mathematical theory of non-uniform gases , 1939 .

[3]  P. J. Dotson,et al.  Polymer solution rheology based on a finitely extensible bead—spring chain model , 1980 .

[4]  R. Bird,et al.  Constitutive equations for polymeric liquids , 1995 .

[5]  Walter Noll,et al.  A mathematical theory of the mechanical behavior of continuous media , 1958 .

[6]  D. Joseph,et al.  Principles of non-Newtonian fluid mechanics , 1974 .

[7]  Alexander N. Gorban,et al.  Method of invariant manifolds and regularization of acoustic spectra , 1994 .

[8]  Bruce W. Char,et al.  Maple V Language Reference Manual , 1993, Springer US.

[9]  Raphael Aronson,et al.  Theory and application of the Boltzmann equation , 1976 .

[10]  R. Bird Dynamics of Polymeric Liquids , 1977 .

[11]  J. G. Oldroyd,et al.  Non-Newtonian effects in steady motion of some idealized elastico-viscous liquids , 1958, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[12]  S. Prager,et al.  Variational Treatment of Hydrodynamic Interaction in Polymers , 1969 .

[13]  Hans Christian Öttinger,et al.  Stochastic Processes in Polymeric Fluids , 1996 .

[14]  Hiromi Yamakawa,et al.  Transport Properties of Polymer Chains in Dilute Solution: Hydrodynamic Interaction , 1970 .

[15]  Hans Christian Öttinger,et al.  A detailed comparison of various FENE dumbbell models , 1997 .

[16]  Alexander N. Gorban,et al.  Dynamic correction to moment approximations , 1998 .

[17]  H. R. Warner,et al.  Kinetic Theory and Rheology of Dilute Suspensions of Finitely Extendible Dumbbells , 1972 .