Microwave assisted synthesis of technologically important transition metal silicides

A novel, simple, clean, and fast microwave assisted method of preparing important transition metal silicides (MoSi[sb 2], WSi[sb 2], CoSi[sb 2], and TiSi[sb 2]) has been described. Amorphous carbon is used both as a microwave susceptor and as a preventer of oxidation.

[1]  A. F. Wells,et al.  Structural Inorganic Chemistry , 1971, Nature.

[2]  W. Jeitschko,et al.  Refinement of the crystal structure of TiSi2 and some comments on bonding in TiSi2 and related compounds , 1977 .

[3]  T. Meek,et al.  Microwave sintering of some oxide materials using sintering aids , 1987 .

[4]  D. Mingos,et al.  Application of microwave heating techniques for the synthesis of solid state inorganic compounds , 1988 .

[5]  D. Clark,et al.  Microwave ignition and combustion synthesis of composites , 1991 .

[6]  M. Kaufman,et al.  Intrinisic second-phase particles in powder-processed MoSi2 , 1991 .

[7]  A. Vasudévan,et al.  A comparative overview of molybdenum disilicide composites , 1992 .

[8]  C. Maggiore,et al.  Synthesis of molybdenum disilicide by mechanical alloying , 1992 .

[9]  D. Mingos,et al.  Microwave-assisted solid-state reactions involving metal powders , 1992 .

[10]  J. Petrovic MoSi_2-Based High-Temperature Structural Silicides , 1993 .

[11]  A. Barron,et al.  Synthesis of Polycrystalline Chalcopyrite Semiconductors by Microwave Irradiation , 1993, Science.

[12]  B. Vaidhyanathan,et al.  A Novel Method of Preparation of Inorganic Glasses by Microwave Irradiation , 1994 .

[13]  P. Ramesh,et al.  Microwave‐assisted synthesis of aluminum nitride , 1995 .

[14]  C. Cabral,et al.  Activation energy for CoSi and CoSi2 formation measured during rapid thermal annealing , 1995 .

[15]  Yan Xu,et al.  Accelerated microwave synthesis of magnesium sulfide with the pro-heating medium of graphite , 1995 .

[16]  W. McWhinnie,et al.  Rapid microwave pyrolysis of coal: Methodology and examination of the residual and volatile phases , 1995 .

[17]  B. Vaidhyanathan,et al.  Fast solid state synthesis of metal vanadates and chalcogenides using microwave irradiation , 1995 .

[18]  J. Petrovic Mechanical behavior of MoSi2 and MoSi2 composites , 1995 .

[19]  Q. H. Li,et al.  Microwave-hydrothermal processing of metal powders , 1995 .

[20]  B. Vaidhyanathan,et al.  Microwave-assisted selective deoxygenation of layer- and chain-containing oxides , 1996 .

[21]  M. Gasgnier,et al.  Microwave-monomode energy transfer: Chemical syntheses, crystallographic and thermal properties of mineral powders , 1996 .