Adhesion Energies of 2D Graphene and MoS2 to Silicon and Metal Substrates

In this paper, results for the adhesion energy of graphene and MoS2 to silicon based and metal substrates using the intercalation of nanoparticles method are presented. In this method, nanoparticles are dispersed onto the substrates before transferring the 2D material onto the substrate. This causes a blister to form, the width and height of which can be measured by AFM. Using a simple model then allows for the adhesion energy to be found. The substrates tested are SiO2, Si3N4, gold, and platinum. Gold is found to have the highest adhesion energy per area of 7687.10 and 1207.26 mJ m−2 for graphene and MoS2 respectively.

[1]  Peter Beike,et al.  Intermolecular And Surface Forces , 2016 .

[2]  Tao Lu,et al.  Intermolecular Sulfur···Oxygen Interactions: Theoretical and Statistical Investigations , 2015, J. Chem. Inf. Model..

[3]  S. Seal,et al.  Recent development in 2D materials beyond graphene , 2015 .

[4]  M. Prato,et al.  Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems. , 2015, Nanoscale.

[5]  Gang Hee Han,et al.  Seeded growth of highly crystalline molybdenum disulphide monolayers at controlled locations , 2015, Nature Communications.

[6]  R. Ruoff,et al.  A blister test for interfacial adhesion of large-scale transferred graphene , 2014 .

[7]  R. Wallace,et al.  The unusual mechanism of partial Fermi level pinning at metal-MoS2 interfaces. , 2014, Nano letters.

[8]  Meicheng Li,et al.  DFT study on the atomic-scale nucleation path of graphene growth on the Cu(111) surface. , 2014, Physical chemistry chemical physics : PCCP.

[9]  Santanu Das,et al.  Measurements of the adhesion energy of graphene to metallic substrates , 2013 .

[10]  R. Dong,et al.  Record maximum oscillation frequency in C-face epitaxial graphene transistors. , 2013, Nano letters.

[11]  M. Dunn,et al.  Adhesion mechanics of graphene membranes , 2012, 1205.0199.

[12]  B. Cho,et al.  Direct measurement of adhesion energy of monolayer graphene as-grown on copper and its application to renewable transfer process. , 2012, Nano letters.

[13]  Andres Castellanos-Gomez,et al.  Elastic Properties of Freely Suspended MoS2 Nanosheets , 2012, Advanced materials.

[14]  M. Dunn,et al.  Ultrastrong adhesion of graphene membranes. , 2011, Nature nanotechnology.

[15]  K. Unterrainer,et al.  Intrinsic Response Time of Graphene Photodetectors , 2011, Nano letters.

[16]  M. Dunn,et al.  van der Waals adhesion of graphene membranes , 2010 .

[17]  Mehmet R. Dokmeci,et al.  Direct measurement of graphene adhesion on silicon surface by intercalation of nanoparticles , 2010 .

[18]  E. Yoo,et al.  Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries. , 2008, Nano letters.

[19]  F. Guinea,et al.  Substrate-limited electron dynamics in graphene , 2007, 0711.1303.

[20]  A. V. Fedorov,et al.  Substrate-induced bandgap opening in epitaxial graphene. , 2007, Nature materials.

[21]  Y. Mai,et al.  Fracture mechanics of a shaft-loaded blister of thin flexible membrane on rigid substrate , 1996 .

[22]  H. Kurokawa P‐Doped Polysilicon Film Growth Technology , 1982 .