An experimental comparison of the Marcus–Hush and Butler–Volmer descriptions of electrode kinetics applied to cyclic voltammetry. The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode

[1]  R. Compton,et al.  Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: A review , 2012 .

[2]  R. Compton,et al.  Influence of the diffuse double layer on steady-state voltammetry , 2011 .

[3]  Á. Molina,et al.  Quantitative weaknesses of the Marcus-Hush theory of electrode kinetics revealed by Reverse Scan Square Wave Voltammetry: The reduction of 2-methyl-2-nitropropane at mercury microelectrodes , 2011 .

[4]  K. B. Oldham,et al.  On the evaluation and analysis of the Marcus–Hush–Chidsey integral , 2011 .

[5]  Thomas S. Varley,et al.  Beyond the Butler-Volmer equation. Curved Tafel slopes from steady-state current-voltage curves. , 2011, Physical chemistry chemical physics : PCCP.

[6]  R. Compton,et al.  Cyclic voltammetry in the absence of excess supporting electrolyte offers extra kinetic and mechanistic insights: comproportionation of anthraquinone and the anthraquinone dianion in acetonitrile. , 2010, Angewandte Chemie.

[7]  S. Feldberg Implications of Marcus-Hush theory for steady-state heterogeneous electron transfer at an inlaid disk electrode. , 2010, Analytical chemistry.

[8]  Richard G. Compton,et al.  How Much Supporting Electrolyte Is Required to Make a Cyclic Voltammetry Experiment Quantitatively “Diffusional”? A Theoretical and Experimental Investigation , 2009 .

[9]  R. Compton,et al.  Potential Step Chronoamperometry at Microdisc Electrodes: Effect of Finite Electrode Kinetics , 2009 .

[10]  R. Compton,et al.  Voltammetry in Weakly Supported Media : The Stripping of Thallium from a Hemispherical Amalgam Drop. Theory and Experiment , 2008 .

[11]  O. Petrii,et al.  Life of the Tafel equation: Current understanding and prospects for the second century , 2007 .

[12]  M. Newton,et al.  A simple comparison of interfacial electron-transfer rates for surface-attached and bulk solution-dissolved redox moieties , 2006 .

[13]  D. Matyushov Reorganization asymmetry of electron transfer in ferroelectric media and principles of artificial photosynthesis. , 2006, The journal of physical chemistry. B.

[14]  R. Compton,et al.  Marcus theory of outer-sphere heterogeneous electron transfer reactions: High precision steady-state measurements of the standard electrochemical rate constant for ferrocene derivatives in alkyl cyanide solvents , 2005 .

[15]  R. G. Evans,et al.  Double potential step chronoamperometry at microdisk electrodes: simulating the case of unequal diffusion coefficients , 2004 .

[16]  R. Compton,et al.  Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: the oxidation of substituted 1,4-phenylenediamines. , 2004, ChemPhysChem.

[17]  R. Compton,et al.  Marcus Theory for Outer-Sphere Heterogeneous Electron Transfer: Predicting Electron-Transfer Rates for Quinones , 2004 .

[18]  R. Compton,et al.  Marcus theory of outer-sphere heterogeneous electron transfer reactions: dependence of the standard electrochemical rate constant on the hydrodynamic radius from high precision measurements of the oxidation of anthracene and its derivatives in nonaqueous solvents using the high-speed channel electro , 2004, Journal of the American Chemical Society.

[19]  Pradyumna S. Singh,et al.  Revisiting the heterogeneous electron-transfer kinetics of nitro compounds , 2004 .

[20]  Emily A Hueske,et al.  Scanning electrochemical microscopy. 48. Hg/Pt hemispherical ultramicroelectrodes: fabrication and characterization. , 2003, Analytical chemistry.

[21]  David W. Small,et al.  The theory of electron transfer reactions: what may be missing? , 2003, Journal of the American Chemical Society.

[22]  R. Compton,et al.  The high speed channel electrode applied to heterogeneous kinetics: the oxidation of 1,4-phenylenediamines and related species in acetonitrile , 2002 .

[23]  J. Ulstrup,et al.  Voltammetry of native and recombinant Pseudomonas aeruginosa azurin on polycrystalline Au- and single-crystal Au(111)-surfaces modified by decanethiol monolayers , 2001 .

[24]  F. Armstrong,et al.  Fast-scan cyclic voltammetry of protein films on pyrolytic graphite edge electrodes: characteristics of electron exchange. , 1998, Analytical chemistry.

[25]  A. Ravenscroft,et al.  MULTIPLE ELECTRON TUNNELING PATHS ACROSS SELF-ASSEMBLED MONOLAYERS OF ALKANETHIOLS WITH ATTACHED RUTHENIUM(II/III) REDOX CENTERS , 1996 .

[26]  R. Murray,et al.  Heterogeneous Electron-Transfer Dynamics of Decamethylferrocene from 130 to 181 K , 1994 .

[27]  Dennis H. Evans,et al.  Comparison of heterogeneous and homogeneous electron-transfer rates for some nitroalkanes and diketones , 1992 .

[28]  C. Chidsey,et al.  Free Energy and Temperature Dependence of Electron Transfer at the Metal-Electrolyte Interface , 1991, Science.

[29]  John R. Miller,et al.  Intramolecular long-distance electron transfer in radical anions. The effects of free energy and solvent on the reaction rates , 1984 .

[30]  D. Corrigan,et al.  Cyclic voltammetric study of tert-nitrobutane reduction in acetonitrile at mercury and platinum electrodes , 1980 .

[31]  T. Rabockai The influence of temperature on the diffusion coefficient of europium in aqueous formamide solutions , 1977 .

[32]  W. F. Kinard,et al.  Electrochemical studies of the EU(III)/(II) reaction by conventional and kalousek polarography , 1970 .

[33]  J. Hale The potential-dependence and the upper limits of electrochemical rate constants , 1968 .

[34]  Huan‐Xiang Zhou,et al.  Microscopic formulation of Marcus’ theory of electron transfer , 1995 .

[35]  M. Sluyters-Rehbach,et al.  On the Impedance of Galvanic Cells , 1968 .

[36]  A. Frumkin Influence of adsorption of neutral molecules and organic cations on the kinetics of electrode processes , 1964 .

[37]  Rudolph A. Marcus,et al.  On the theory of oxidation—Reduction reactions involving electron transfer. V. Comparison and properties of electrochemical and chemical rate constants , 1963 .

[38]  J. A. V. Butler,et al.  The mechanism of overvoltage and its relation to the combination of hydrogen atoms at metal electrodes , 1932 .