Characterization and Dielectric Properties of Nanocomposite Made of Lead Zirconate Nanofibers and Polyvinylidene Fluoride Improved with Carbon Nanotubes

A three-phase PZ/CNT/PVDF nanocomposite comprising lead zirconate (PZ) nanofibers, polyvinylidene fluoride (PVDF) and a small volume fraction of carbon nanotubes (CNT) was prepared by the solvent casting technique followed by composite heating at 80°C. The PZ/CNT/PVDF composites were characterized by X-ray diffraction, FT-IR and scanning electron microscopy (SEM). The dielectric properties of the composite were studied as a function of the frequency by an LCR meter. The dielectric constant of the PZ/CNT/PVDF nanocomposite was found to be in the range of 18–61 within the measurement frequencies from 100 Hz to 2 MHz. This value is higher than the dielectric constant of the PZ/PVDF nanocomposite. The measured dielectric properties demonstrate that the addition of CNT can improve the dielectric property appearance of the composite.

[1]  N. Vittayakorn,et al.  Synthesis and phase evolution of electrospun antiferroelectric lead zirconate (PbZrO3) nanofibers , 2012 .

[2]  Minbaek Lee,et al.  Flexible Nanocomposite Generator Made of BaTiO3 Nanoparticles and Graphitic Carbons , 2012, Advanced materials.

[3]  N. Joshi Studies of nano sized high dielectric constant materials , 2012 .

[4]  C. Baudot,et al.  Characteristics of the Electrical Percolation in Carbon Nanotubes/Polymer Nanocomposites , 2011 .

[5]  Z. Dang,et al.  Tailored Dielectric Properties based on Microstructure Change in BaTiO3-Carbon Nanotube/Polyvinylidene Fluoride Three-Phase Nanocomposites , 2010 .

[6]  Tong-Yi Zhang,et al.  Tuning the Ferroelectric and Piezoelectric Properties of 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 Single Crystals and Lead Zirconate Titanate Ceramics by Doping Hydrogen , 2010 .

[7]  F. Fisher,et al.  Deformation-induced crystallization and associated morphology development of carbon nanotube-PVDF nanocomposites. , 2009, Journal of nanoscience and nanotechnology.

[8]  D. S. Misra,et al.  Thermogravimetric analysis of cobalt-filled carbon nanotubes deposited by chemical vapour deposition , 2006 .

[9]  Gary W. Bohannan,et al.  Damping and electromechanical energy losses in the piezoelectric polymer PVDF , 2004 .

[10]  Ji Liang,et al.  X-ray diffraction characterization on the alignment degree of carbon nanotubes , 2001 .

[11]  A. Safari Development of piezoelectric composites for transducers , 1994 .

[12]  I. Milašauskait,et al.  Experimental characterization of material structure of piezoelectric PVDF polymer , 2010 .

[13]  Yu Wang,et al.  Synthesis of lead zirconate titanate nanofibres and the Fourier-transform infrared characterization of their metallo-organic decomposition process , 2003 .