Durability and Mechanical Properties of CNT Cement Composites

Due to their unique intrinsic properties, carbon nanotubes (CNT) are considered potential candidates for developing new functional properties when they are included into the cementitious matrix. This work has the aim of characterising the main properties of CNT Portland cement composites, regarding their mechanical properties and their durability facing corrosion processes. Variation in mechanical properties of mortars with different dosages of CNT and corrosion of embedded steel rebars in CNT cement pastes were investigated. Firstly, bending strength, compression strength, porosity and density of CNT mortars were obtained and compared with the reference (without CNT). Afterwards, CNT reinforced paste specimens were prepared to be exposed to carbonation and chloride attacks. The results on steel corrosion rate tests were related to CNT dosages. The increase in CNT addition implied no significant variations of mechanical properties but slightly higher steel corrosion intensities were found.

[1]  Oscar Galao,et al.  Multifunctional Cement Composites Strain and Damage Sensors Applied on Reinforced Concrete (RC) Structural Elements , 2013, Materials.

[2]  Raúl Fangueiro,et al.  A review on nanomaterial dispersion, microstructure, and mechanical properties of carbon nanotube and nanofiber reinforced cementitious composites , 2013 .

[3]  D.D.L. Chung,et al.  Partial replacement of carbon fiber by carbon black in multifunctional cement–matrix composites , 2007 .

[4]  Vesa Penttala,et al.  Direct Synthesis of Carbon Nanofibers on Cement Particles , 2010 .

[5]  Francis Gerard Collins,et al.  The influences of admixtures on the dispersion, workability, and strength of carbon nanotube-OPC paste mixtures , 2012 .

[6]  C. Andrade,et al.  Effect of nitrite in corrosion of reinforcing steel in neutral and acid solutions simulating the electrolytic environments of micropores of concrete in the propagation period , 2008 .

[7]  J. Payá,et al.  Corrosion rate of steel embedded in blended Portland and fluid catalytic cracking catalyst residue (FC3R) cement mortars , 2008 .

[8]  I. Martín-Gullón,et al.  Carbon nanofibers enhance the fracture toughness and fatigue performance of a structural epoxy system , 2011 .

[9]  E. Zornoza,et al.  Strain and damage sensing properties on multifunctional cement composites with CNF admixture , 2014 .

[10]  C. Andrade,et al.  Quantitative measurements of corrosion rate of reinforcing steels embedded in concrete using polarization resistance measurements , 1978 .

[11]  Rafat Siddique,et al.  Effect of carbon nanotubes on properties of cement mortars , 2014 .

[12]  Pedro Garcés,et al.  Effect of carbon fibres on the mechanical properties and corrosion levels of reinforced portland cement mortars , 2005 .

[13]  Rashid K. Abu Al-Rub,et al.  Distribution of Carbon Nanofibers and Nanotubes in Cementitious Composites , 2010 .

[14]  I. De la Varga,et al.  Corrosion of steel reinforcement in structural concrete with carbon material addition , 2007 .

[15]  D. Chung Carbon materials for structural self-sensing, electromagnetic shielding and thermal interfacing , 2012 .

[16]  F. J. Baeza,et al.  Efecto de la adición de nanofibras de carbono en las propiedades mecánicas y de durabilidad de materiales cementantes , 2012 .

[17]  Jinping Ou,et al.  Review of nanocarbon-engineered multifunctional cementitious composites , 2015 .

[18]  Zhu Pan,et al.  Carbon nanotube–cement composites: A retrospect , 2011 .

[19]  P. Garcés,et al.  Función de apantallamiento de interferencia electromagnética de pastas de cemento con materiales carbonosos y cenizas volantes procesadas , 2010 .

[20]  M. Climent,et al.  Feasibility of electrochemical chloride extraction from structural reinforced concrete using a sprayed conductive graphite powder–cement paste as anode , 2013 .

[21]  Pedro Garcés,et al.  Self-heating and deicing conductive cement. Experimental study and modeling , 2015 .

[22]  Viktor Mechtcherine,et al.  Dispersion of carbon nanotubes and its influence on the mechanical properties of the cement matrix , 2012 .

[23]  V. Shanov,et al.  Introduction to carbon nanotube and nanofiber smart materials , 2006 .