Monitoring automotive oil degradation: analytical tools and onboard sensing technologies

AbstractEngine oil experiences a number of thermal and oxidative phases that yield acidic products in the matrix consequently leading to degradation of the base oil. Generally, oil oxidation is a complex process and difficult to elucidate; however, the degradation pathways can be defined for almost every type of oil because they mainly depend on the mechanical status and operating conditions. The exact time of oil change is nonetheless difficult to predict, but it is of great interest from an economic and ecological point of view. In order to make a quick and accurate decision about oil changes, onboard assessment of oil quality is highly desirable. For this purpose, a variety of physical and chemical sensors have been proposed along with spectroscopic strategies. We present a critical review of all these approaches and of recent developments to analyze the exact lifetime of automotive engine oil. Apart from their potential for degradation monitoring, their limitations and future perspectives have also been investigated. FigureOnboard assessment of oil quality: the sensors and spectroscopic strategies proposed for this are reviewed

[1]  Zheng Yang,et al.  Determination of wear metals in engine oil by mild acid digestion and energy dispersive X-ray fluorescence spectrometry using solid phase extraction disks. , 2003, Talanta.

[2]  Usman Latif,et al.  Conductometric Sensors for Monitoring Degradation of Automotive Engine Oil† , 2011, Sensors.

[3]  H. Wohltjen,et al.  Solid state microsensors for lubricant condition monitoring. II: Total base number , 1994 .

[4]  Michael B. Viola,et al.  In situ monitoring of high-temperature degraded engine oil condition with microsensors , 1994 .

[5]  J. Slater,et al.  Monitoring of Engine Oil Degradation by Voltammetric Methods Utilizing Disposable Solid Wire Microelectrodes , 1997 .

[6]  Dimitrios Peroulis,et al.  High temperature dynamic viscosity sensor for engine oil applications , 2012 .

[7]  I. Nicholls,et al.  Molecular Imprinting: The Current Status and Future Development of Polymer-Based Recognition Systems , 1996 .

[8]  Franz L. Dickert,et al.  Mass-sensitive detection of cells, viruses and enzymes with artificial receptors , 2003 .

[9]  A. Bodensohn,et al.  System Monitoring for Lifetime Prediction in Automotive Industry , 2005 .

[10]  Sarangapani Jagannathan,et al.  Remaining useful life prediction of automotive engine oils using MEMS technologies , 2000, Proceedings of the 2000 American Control Conference. ACC (IEEE Cat. No.00CH36334).

[11]  F. Dickert,et al.  Surface Nano-patterning of Polymers for Mass-Sensitive Biodetection , 2010, Nano-Bio-Sensing.

[12]  Gerhard Knothe,et al.  Kinematic viscosity of biodiesel components (fatty acid alkyl esters) and related compounds at low temperatures , 2007 .

[13]  Svend Henningsen Chapter 14 – Air Pollution from Large Two-Stroke Diesel Engines and Technologies to Control It , 1998 .

[14]  Peter A. Lieberzeit,et al.  QCM sensor array for monitoring terpene emissions from odoriferous plants , 2009 .

[15]  M. Romeo,et al.  FTIR analysis and monitoring of synthetic aviation engine oils. , 2007, Talanta: The International Journal of Pure and Applied Analytical Chemistry.

[16]  N. Nielsen,et al.  Quantitative Analysis of Constituents in Heavy Fuel Oil by 1H Nuclear Magnetic Resonance (NMR) Spectroscopy and Multivariate Data Analysis , 2008 .

[17]  N. Bings,et al.  Direct determination of metals in lubricating oils by laser ablation coupled to inductively coupled plasma time-of-flight mass spectrometry , 2002 .

[18]  Franz L. Dickert,et al.  Molecularly Imprinted Sensor Layers for the Detection of Polycyclic Aromatic Hydrocarbons in Water , 1999 .

[19]  L. Rudnick Lubricant Additives : Chemistry and Applications, Second Edition , 2009 .

[20]  A. Bratov,et al.  Recent trends in potentiometric sensor arrays--a review. , 2010, Analytica chimica acta.

[21]  Michael J. Whitcombe,et al.  A NEW METHOD FOR THE INTRODUCTION OF RECOGNITION SITE FUNCTIONALITY INTO POLYMERS PREPARED BY MOLECULAR IMPRINTING : SYNTHESIS AND CHARACTERIZATION OF POLYMERIC RECEPTORS FOR CHOLESTEROL , 1995 .

[22]  Photoacoustic Spectroscopy, Methods and Instrumentation , 1999 .

[23]  Qiang Zhao,et al.  Electrochemical sensors based on carbon nanotubes , 2002 .

[24]  G. Sauerbrey,et al.  Use of quartz vibration for weighing thin films on a microbalance , 1959 .

[25]  F. Dickert,et al.  Artificial receptor layers for detecting chemical and biological threats , 2010 .

[26]  Sergey Edward Lyshevski,et al.  Modeling and identification of induction micromachines in microelectromechanical systems applications , 2002 .

[27]  Leslie R. Rudnick,et al.  Synthetics, Mineral Oils, and Bio-Based Lubricants : Chemistry and Technology , 2005 .

[28]  Han-Sheng Lee,et al.  The application of a.c. impedance technique for detecting glycol contamination in engine oil , 1997 .

[29]  Juan Bisquert,et al.  A review of recent results on electrochemical determination of the density of electronic states of nanostructured metal-oxide semiconductors and organic hole conductors , 2008 .

[30]  Bastian E. Rapp,et al.  Surface acoustic wave biosensors: a review , 2008, Analytical and bioanalytical chemistry.

[31]  C. Rao,et al.  “LAPS Card”—A novel chip card-based light-addressable potentiometric sensor (LAPS) , 2006 .

[32]  J. Winefordner,et al.  Jet Engine Oil Analysis by Atomic Absorption Spectrometry with Graphite Filament , 1974 .

[33]  Peter A. Lieberzeit,et al.  Borderline applications of QCM-devices: synthetic antibodies for analytes in both nm- and μm-dimensions , 2003 .

[34]  D. Chasan,et al.  Ashless antioxidants, copper deactivators and corrosion inhibitors: Their use in lubricating oils , 1990 .

[35]  B. Jakoby,et al.  Viscosity sensors for engine oil condition monitoring—Application and interpretation of results , 2005 .

[36]  F. Toldrá,et al.  Development of a dielectric spectroscopy technique for the determination of key biochemical markers of meat quality , 2011 .

[37]  Peter A Lieberzeit,et al.  QCM gas phase detection with ceramic materials—VOCs and oil vapors , 2011, Analytical and bioanalytical chemistry.

[38]  S. Weinberger,et al.  Recent advancements in surface‐enhanced laser desorption/ionization‐time of flight‐mass spectrometry , 2000, Electrophoresis.

[39]  J. M. Hammond,et al.  A remote acoustic engine oil quality sensor , 1997, 1997 IEEE Ultrasonics Symposium Proceedings. An International Symposium (Cat. No.97CH36118).

[40]  M. Rapp,et al.  Vacuum-deposited wave-guiding layers on STW resonators based on LiTaO(3) substrate as love wave sensors for chemical and biochemical sensing in liquids. , 2010, Ultrasonics.

[41]  G. Sauerbrey Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung , 1959 .

[42]  Time-of-Flight Mass Spectrometry , 2005 .

[43]  Simon S. Wang Road tests of oil condition sensor and sensing technique , 2001 .

[44]  Bernhard Jakoby,et al.  The potential of microacoustic SAW- and BAW-based sensors for automotive applications - a review , 2002 .

[45]  E. Gorritxategi,et al.  Chemometric methods applied to the calibration of a Vis-NIR sensor for gas engine's condition monitoring. , 2011, Analytica chimica acta.

[46]  J. Turner,et al.  Electrical techniques for monitoring the condition of lubrication oil , 2003 .

[47]  A. Afzal,et al.  Printing materials in micro- and nano-scale: Systems for process control , 2007 .

[48]  Sergey A. Piletsky,et al.  Selective recognition of atrazine by molecularly imprinted polymer membranes. Development of conductometric sensor for herbicides detection , 1999 .

[49]  Sergey A. Piletsky,et al.  Electrochemical Sensors Based on Molecularly Imprinted Polymers , 2002 .

[50]  Jyrki Kauppinen,et al.  Extremely sensitive trace gas analysis with modern photoacoustic spectroscopy , 2006 .

[51]  Han-Sheng Lee,et al.  An electrochemical sensor for distinguishing two-stroke-engine oils , 1997 .

[52]  J. M. Hammond,et al.  An acoustic automotive engine oil quality sensor , 1997, Proceedings of International Frequency Control Symposium.

[53]  L. Rudnick Lubricant Additives: Chemistry and Applications , 2007 .

[54]  T. David Binnie,et al.  Application of pulsed laser photoacoustic sensors in monitoring oil contamination in water , 1995 .

[55]  F. Dickert,et al.  Softlithography in Chemical Sensing – Analytes from Molecules to Cells , 2005, Sensors (Basel, Switzerland).

[56]  F. Dickert,et al.  Molecular Fingerprints Using Imprinting Techniques , 2000 .

[58]  Peter A. Lieberzeit,et al.  SAW RFID-Tags for Mass-Sensitive Detection of Humidity and Vapors , 2009, Sensors.

[59]  Franz L. Dickert,et al.  Molecular imprinting in chemical sensing , 1999 .

[60]  A. Leidl,et al.  Nanostructured polymers for detecting chemical changes during engine oil degradation , 2006, IEEE Sensors Journal.

[61]  Jiri Janata,et al.  Diagnosis of used engine oil based on gas phase analysis , 2004 .

[62]  J. M. Hammond,et al.  An acoustic automotive engine oil quality sensor , 1997, Proceedings of International Solid State Sensors and Actuators Conference (Transducers '97).

[63]  John C. Lindon,et al.  Encyclopedia of spectroscopy and spectrometry , 2000 .

[64]  M. Ichikawa,et al.  Headspace gas chromatography analysis of uncombusted gasoline diluent in used gasoline engine oils , 1995 .

[65]  D. Cozzolino,et al.  Feasibility study on the use of visible and near-infrared spectroscopy together with chemometrics to discriminate between commercial white wines of different varietal origins. , 2003, Journal of agricultural and food chemistry.

[66]  Peter A Lieberzeit,et al.  Dual and tetraelectrode QCMs using imprinted polymers as receptors for ions and neutral analytes , 2011, Analytical and bioanalytical chemistry.

[67]  P. Burg,et al.  Prediction of kinematic viscosity of crude oil from chromatographic data , 1997 .

[68]  Andrzej Szczurek,et al.  Electronic nose applied to automotive fuel qualification , 2006 .

[69]  Franz L. Dickert,et al.  SAW devices : sensitivity enhancement in going from 80 MHz to 1 GHz , 1998 .

[70]  James E. Amonette,et al.  Detection of trace levels of water in oil by photoacoustic spectroscopy , 2001 .

[71]  Peter A. Lieberzeit,et al.  Chemical Sensors Based on Molecularly Imprinted Sol-Gel Materials † , 2010, Materials.

[72]  Simon S. Wang,et al.  A new technique for detecting antifreeze in engine oil during early stage of leakage , 2003 .

[73]  Y. Roggo,et al.  A review of near infrared spectroscopy and chemometrics in pharmaceutical technologies. , 2007, Journal of pharmaceutical and biomedical analysis.

[74]  L. Zeller,et al.  Characterisation of humidity dependence of a metal oxide semiconductor sensor array using partial least squares , 2008 .

[75]  Sang Myung Chun,et al.  Simulation of engine life time related with abnormal oil consumption , 2011 .

[76]  Franz L. Dickert,et al.  Sol–Gel‐Coated Quartz Crystal Microbalances for Monitoring Automotive Oil Degradation , 2001 .

[77]  George E. Totten,et al.  Fuels and Lubricants Handbook: Technology, Properties, Performance, and Testing , 2003 .

[78]  Olof Ramström,et al.  The Emerging Technique of Molecular Imprinting and Its Future Impact on Biotechnology , 1996, Bio/Technology.

[79]  Margaret West,et al.  X-ray fluorescence spectrometry , 1999 .

[80]  X. L. Feng,et al.  Application of dielectric spectroscopy for engine lubricating oil degradation monitoring , 2011 .

[81]  F. Dickert,et al.  Chemical Sensors – from Molecules, Complex Mixtures to Cells – Supramolecular Imprinting Strategies , 2003 .

[82]  Jürgen Valldorf,et al.  Advanced Microsystems for Automotive Applications 2006 , 2006 .

[83]  H. Wohltjen,et al.  Solid-state microsensors for lubricant condition monitoring. I: Fuel dilution meter , 1994 .

[84]  Byeong Kwon Ju,et al.  Multiwall Carbon Nanotube Sensor for Monitoring Engine Oil Degradation , 2006 .

[85]  Vadim F. Lvovich,et al.  Iridium oxide sensors for acidity and basicity detection in industrial lubricants , 2003 .

[86]  Axel H. Berndorfer,et al.  “Smart sensing” of Oil Degradation and Oil Level Measurements in Gasoline Engines , 2000 .

[87]  The nature of electrochemical reactions between several zinc organodithiophosphate antiwear additives and cast iron surfaces , 1988 .

[88]  H. Bowen,et al.  Symyx Technologies, Inc. , 2008 .

[89]  Simon S. Wang Engine oil condition sensor: method for establishing correlation with total acid number , 2002 .

[90]  Oleg Kolosov,et al.  New Solid State Oil Condition Sensor for Real Time Engine Oil Condition Monitoring , 2006 .

[91]  F. Dickert,et al.  Synthetic receptors for chemical sensors--subnano- and micrometre patterning by imprinting techniques. , 2004, Biosensors & bioelectronics.

[92]  Gabriele Reich,et al.  Near-infrared spectroscopy and imaging: basic principles and pharmaceutical applications. , 2005, Advanced drug delivery reviews.

[93]  Luca Francioso,et al.  Metal oxide gas sensor array for the detection of diesel fuel in engine oil , 2008 .

[94]  Peter A. Lieberzeit,et al.  Molecularly imprinted sol–gel nanoparticles for mass-sensitive engine oil degradation sensing , 2007, Analytical and bioanalytical chemistry.

[95]  Peter A Lieberzeit,et al.  Imprinted sol-gel materials for monitoring degradation products in automotive oils by shear transverse wave. , 2010, Analytica chimica acta.

[96]  E. Marguí,et al.  Application of X-ray fluorescence spectrometry to determination and quantitation of metals in vegetal material , 2009 .

[97]  B Heron USED ENGINE OIL ANALYSIS , 1986 .

[98]  Peter Hauptmann,et al.  Supramolecular interactions on mass sensitive sensors in gas phases and liquids , 1996 .

[99]  D. J. Smolenski,et al.  Automotive engine-oil condition monitoring , 1994 .

[100]  G. Korotcenkov,et al.  Instability of metal oxide-based conductometric gas sensors and approaches to stability improvement (short survey) , 2011 .

[101]  Christian Ulrich,et al.  Simultaneous estimation of soot and diesel contamination in engine oil using electrochemical impedance spectroscopy , 2007 .

[102]  Vijay Srinivasan,et al.  Visual modeling and design of microelectromechanical system transducers , 2001 .

[103]  Z. Strnad,et al.  Composition and oxidation stability of SAE 15W-40 engine oils , 2001 .

[104]  Koji Asami,et al.  Characterization of heterogeneous systems by dielectric spectroscopy , 2002 .

[105]  B. Jakoby,et al.  An automotive engine oil viscosity sensor , 2003 .

[106]  G. Voigt,et al.  Quality control of automotive engine oils with mass-sensitive chemical sensors – QCMs and molecularly imprinted polymers , 2000, Fresenius' journal of analytical chemistry.

[107]  B. Sharma,et al.  Chemically functionalized vegetable oils , 2005 .

[108]  Peter A Lieberzeit,et al.  Real-life application of a QCM-based e-nose: quantitative characterization of different plant-degradation processes , 2008, Analytical and bioanalytical chemistry.

[109]  W.J. Fleming,et al.  New Automotive Sensors—A Review , 2008, IEEE Sensors Journal.

[110]  Przemyslaw M. Szecowka,et al.  Application of sensor array and neural networks for quantification of organic solvent vapours in air , 1999 .

[111]  M. Fox,et al.  Chemistry and Technology of Lubricants , 1992 .