Design, fabrication and characterization of infrared LVOFs for measuring gas composition

This paper presents the design, fabrication and characterization of a linear-variable optical-filter (LVOF) that will be used in a micro-spectrometer operating in infrared (IR) for natural gas composition measurement. An LVOF is placed on top of an array of detectors and transforms the optical spectrum into a lateral intensity profile, which is recorded by the detectors. The IR LVOF was fabricated in an IC-compatible process using a photoresist reflow technique, followed by transfer etching of the photoresist into the optical resonator layer. The spectral range between 3 to 5 µm contains the absorption peaks for hydrocarbons, carbon-monoxide and carbon-dioxide. The resulting optical absorption is utilized to measure the gas concentrations in a sample volume. Two LVOF structures were designed and fabricated on silicon wafers using alternate layers of sputtered silicon and silicon-dioxide as the high- and low- refractive index materials. These filters consist of a Fabry–Pérot resonator combined with a band-pass filter designed to block out-of-band transmissions. Finally, the filters were fully characterized with an FTIR spectrometer and showed satisfactory agreement with the optical thin-film simulations. The characterization showed a spectral resolution of 100 nm, which can be further improved with signal processing algorithms. This method makes it possible to fabricate small and robust LVOFs with high resolving power in the IR spectral range directly on the detector array chip.

[1]  L. Rocha,et al.  Gas viscosity MEMS sensor based on pull-in , 2013, 2013 Transducers & Eurosensors XXVII: The 17th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS & EUROSENSORS XXVII).

[2]  G. de Graaf,et al.  Surface-micromachined thermal conductivity detectors for gas sensing , 2012, 2012 IEEE International Instrumentation and Measurement Technology Conference Proceedings.

[3]  Arvin Emadi,et al.  Design and implementation of a sub-nm resolution microspectrometer based on a Linear-Variable Optical Filter. , 2012, Optics express.

[4]  A. Emadi Linear-Variable Optical Filters for microspectrometer application , 2010 .

[5]  Carles Cané,et al.  Qualitative and quantitative substance discrimination using a CMOS compatible non-specific NDIR microarray , 2009 .

[6]  J. Dell,et al.  MEMS-based microspectrometer technologies for NIR and MIR wavelengths , 2009 .

[7]  S. Grabarnik,et al.  Vertically tapered layers for optical applications fabricated using resist reflow , 2009 .

[8]  Ghenadii Korotcenkov,et al.  Review of electrochemical hydrogen sensors. , 2009, Chemical reviews.

[9]  Carles Cané,et al.  Non-selective NDIR array for gas detection , 2007, SPIE Microtechnologies.

[10]  Carles Cané,et al.  Exploration of the metrological performance of a gas detector based on an array of unspecific infrared filters , 2006 .

[11]  R. Wolffenbuttel MEMS-based optical mini- and microspectrometers for the visible and infrared spectral range , 2005 .

[12]  Jan Dziuban,et al.  Portable gas chromatograph with integrated components , 2004 .

[13]  Wolfram Bremser,et al.  Analysis of natural gas by gas chromatography reduction of correlated uncertainties by normalisation. , 2004, Journal of chromatography. A.

[14]  Mohand Tazerout,et al.  Determination of the combustion properties of natural gases by pseudo-constituents☆ , 2003 .

[15]  Michael Arndt,et al.  Thermal and gas-sensing properties of a micromachined thermal conductivity sensor for the detection of hydrogen in automotive applications , 2002 .

[16]  William G. Mallard,et al.  The NIST Chemistry WebBook: A Chemical Data Resource on the Internet† , 2001 .

[17]  W. McGahan,et al.  Spectroscopic Ellipsometry and Reflectometry: A User's Guide , 1999 .

[18]  Philippe Dondon,et al.  Development of a reliable methane detector , 1997 .

[19]  Daniel Massicotte,et al.  Kalman-filter-based algorithms of spectrometric data correction-Part I: an iterative algorithm of deconvolution , 1997 .

[20]  G. Jellison,et al.  Parameterization of the optical functions of amorphous materials in the interband region , 1996 .

[21]  M. K. Andrews,et al.  Damping and gas viscosity measurements using a microstructure , 1995 .

[22]  S. Akbar,et al.  Solid‐State Gas Sensors: A Review , 1992 .

[23]  M. G. Jones,et al.  The detection of hydrogen using catalytic flammable gas sensors , 1989 .

[24]  R. Tatam,et al.  Optical gas sensing: a review , 2012 .

[25]  R. Wolffenbuttel,et al.  Sensor platform for gas composition measurement , 2011 .