Rhodium-Catalyzed Coupling Reaction of Aroyl Chlorides with Alkenes

Aroyl chlorides react with acyclic and cyclic alkenes in the presence of a rhodium catalyst to give Mizoroki–Heck type and cyclization products, respectively. A rhodium-ethylene complex, [{RhCl(C2H4)2}2], showed excellent performance for these reactions. Notably, the reactions can be conducted effectively under base- and phosphane-free conditions.

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