Autogenous and engineered healing mechanisms of carbonated steel slag aggregate in concrete

Abstract The application of self-healing technology in concrete materials was widely investigated in the past decade. Although the micro-capsules and bacteria were considered as promising self-healing agents to realize durability enhancement of concrete, the high cost of micro-capsules and limited bacteria types are still big challenges that limit the widely application of this technology. As a result, it is necessary to develop cost-effective and environmentally friendly materials as self-healing agent in concrete. In this study, carbonated steel slag was used as aggregate to realize the autogenous healing of concrete. The self-healing performance of this concrete was investigated by comparing with the concretes prepared with normal aggregates and crushed steel slag aggregates. In addition, the hydration heat, X-ray diffraction, and scanning electron microscopy/energy dispersive spectroscopy results were analyzed to elucidate the self-healing mechanisms of concrete via using carbonated steel slag as healing agent. It was found that the healing products are mainly composed of CaCO 3 , Ca(OH) 2 , calcium–silicate–hydrate, calcium–aluminate–ferrite hydrate as well as amorphous silica. The cracks of aggregate have been healed to a certain extent that maximum healing width is about 20 μm and maximum healing length is about 5 mm.

[1]  Baldev Raj,et al.  Short time Fourier transform analysis for understanding frequency dependent attenuation in austenitic stainless steel , 2013 .

[2]  J. Duchesne,et al.  Effect of supplementary cementing materials on the composition of cement hydration products , 1995 .

[3]  Adam R. Brandt,et al.  CO2 mitigation potential of mineral carbonation with industrial alkalinity sources in the United States. , 2013, Environmental science & technology.

[4]  Waiching Tang,et al.  Robust evaluation of self-healing efficiency in cementitious materials – A review , 2015 .

[5]  N. Takenaka,et al.  Effects of the number of pulse repetitions and noise on the velocity data from the ultrasonic pulsed Doppler method with different algorithms , 2014 .

[6]  Ibrahim M. Asi,et al.  Use of steel slag aggregate in asphalt concrete mixes , 2007 .

[7]  Glykeria Kakali,et al.  Hydration products of C3A, C3S and Portland cement in the presence of CaCO3 , 2000 .

[8]  Eric Larose,et al.  A review of ultrasonic Coda Wave Interferometry in concrete , 2013 .

[9]  Cedric Payan,et al.  Effect of the presence and size of a real macro-crack on diffuse ultrasound in concrete , 2012 .

[10]  Björn Johannesson,et al.  A review : Self-healing in cementitious materials and engineered cementitious composite as a self-healing material , 2012 .

[11]  Ahmed Loukili,et al.  Design of polymeric capsules for self-healing concrete , 2015 .

[12]  Ahmed Loukili,et al.  Monitoring of cracking and healing in an ultra high performance cementitious material using the time reversal technique , 2009 .

[13]  Guang Ye,et al.  Characterization and quantification of self-healing behaviors of microcracks due to further hydration in cement paste , 2013 .

[14]  Victor C. Li,et al.  Robust Self-Healing Concrete for Sustainable Infrastructure , 2012 .

[15]  Carola Edvardsen,et al.  Water Permeability and Autogenous Healing of Cracks in Concrete , 1999 .

[16]  C Cerrillo,et al.  New contributions to granite characterization by ultrasonic testing. , 2014, Ultrasonics.

[17]  Liberato Ferrara,et al.  A “fracture testing” based approach to assess crack healing of concrete with and without crystalline admixtures , 2014 .

[18]  Min Zhou,et al.  Enhance hydration properties of steel slag using grinding aids by mechanochemical effect , 2012 .

[19]  A. H. M. Andreasen Ueber die Beziehung zwischen Kornabstufung und Zwischenraum in Produkten aus losen Körnern (mit einigen Experimenten) , 1930 .

[20]  Q. Lei,et al.  Monitoring of cement hydration reaction process based on ultrasonic technique of piezoelectric composite transducer , 2012 .

[21]  Erik Schlangen,et al.  Investigation the self-healing mechanism of aged bitumen using microcapsules containing rejuvenator , 2015 .

[22]  B. Pang,et al.  Utilization of carbonated and granulated steel slag aggregate in concrete , 2015 .

[23]  Byung-Hyun Lee,et al.  Effect of steel-making slag as a soil amendment on arsenic uptake by radish (Raphanus sativa L.) in an upland soil , 2010, Biology and Fertility of Soils.

[24]  Luca Rondi,et al.  Reuse of steel slag in bituminous paving mixtures. , 2012, Journal of hazardous materials.

[25]  D. Rogers,et al.  Hydrates of calcium ferrites and calcium aluminoferrites , 1977 .

[26]  P. Yan,et al.  Hydration heat evolution and kinetics of blended cement containing steel slag at different temperatures , 2015 .

[27]  Wimal Suaris,et al.  Detection of crack growth in concrete from ultrasonic intensity measurements , 1987 .

[28]  Zongjin Li Advanced Concrete Technology , 2011 .

[29]  Chung-Yue Wang,et al.  A 3-D Image Detection Method of a Surface Opening Crack in Concrete Using Ultrasonic Transducer Arrays , 1997 .

[30]  R. Baciocchi,et al.  Valorization of steel slag by a combined carbonation and granulation treatment , 2014 .

[31]  Gilles Pijaudier-Cabot,et al.  Experimental characterization of the self-healing of cracks in an ultra high performance cementitious material: Mechanical tests and acoustic emission analysis , 2007 .

[32]  A. Loukili,et al.  Modelling of autogenous healing in ultra high performance concrete , 2014 .

[33]  A. Hammond Hydration products of bauxite-waste pozzolana cement , 1987 .

[34]  Geert-Jan Witkamp,et al.  Mineral CO2 sequestration by steel slag carbonation. , 2005, Environmental science & technology.

[35]  W. Huijgen,et al.  Carbonation of steel slag for CO2 sequestration: leaching of products and reaction mechanisms. , 2006, Environmental science & technology.

[36]  Xuefeng Song,et al.  Effects of superplasticizers on the carbonation resistance of C3S and C3A hydration products , 2012 .

[37]  Xiong Zhang,et al.  Research on effect of limestone and gypsum on C3A, C3S and PC clinker system , 2008 .

[38]  N. Xie,et al.  Durability of steel reinforced concrete in chloride environments: An overview , 2012 .

[39]  Olivier Durand,et al.  Small crack detection in cementitious materials using nonlinear coda wave modulation , 2014 .

[40]  Erika Holt,et al.  Effect of coupled deterioration by freeze–thaw, carbonation and chlorides on concrete service life , 2014 .

[41]  Hubert Rahier,et al.  Influence of mix composition on the extent of autogenous crack healing by continued hydration or calcium carbonate formation , 2012 .

[42]  Feng Xing,et al.  Smart releasing behavior of a chemical self-healing microcapsule in the stimulated concrete pore solution , 2015 .

[43]  Eleftherios Anastasiou,et al.  Utilization of fine recycled aggregates in concrete with fly ash and steel slag , 2014 .

[44]  Y. Shao,et al.  Mathematical modeling of CO2 uptake by concrete during accelerated carbonation curing , 2015 .