FDTD modeling to enhance the performance of an organic solar cell embedded with gold nanoparticles

Optical enhancement is demonstrated in a bilayer P3HT-C60 solar cell by embedding gold nanoparticles directly into the P3HT layer of the photovoltaic device. FDTD simulations are used to model the observed performance gain. A qualitative agreement between the experimental and numerical results is achieved. This validates the numerical model and the simulation is subsequently extended to predict the performance gain of the bilayer device constructed with thinner P3HT layer. The numerical results reveal that the plasmonic structure has even larger effect on such thinner bilayer device. The enhancement is expected to be most significant when the p-n interface is allowed to assume the conformal hemispherical profile of the metal particles.

[1]  Hilmi Volkan Demir,et al.  Plasmonic backcontact grating for P3HT:PCBM organic solar cells enabling strong optical absorption increased in all polarizations. , 2011, Optics express.

[2]  Qiaoqiang Gan,et al.  Broadband short-range surface plasmon structures for absorption enhancement in organic photovoltaics , 2010, 2010 IEEE Photinic Society's 23rd Annual Meeting.

[3]  A. Morfa Plasmons in solar energy conversion , 2009 .

[4]  Yoon-Chae Nah,et al.  Plasmon enhanced performance of organic solar cells using electrodeposited Ag nanoparticles , 2008 .

[5]  Thomas H. Reilly,et al.  Plasmon-enhanced solar energy conversion in organic bulk heterojunction photovoltaics , 2008 .

[6]  Xiaofeng Li,et al.  Bridging electromagnetic and carrier transport calculations for three-dimensional modelling of plasmonic solar cells. , 2011, Optics express.

[7]  Albert Polman,et al.  Design principles for particle plasmon enhanced solar cells , 2008 .

[8]  Thomas H. Reilly,et al.  Surface-plasmon enhanced transparent electrodes in organic photovoltaics , 2008 .

[9]  K. Catchpole,et al.  Plasmonic solar cells. , 2008, Optics express.

[10]  Ludovic Escoubas,et al.  Improving light absorption in organic solar cells by plasmonic contribution , 2009 .

[11]  Garry Rumbles,et al.  Pathways for the degradation of organic photovoltaic P3HT:PCBM based devices , 2008 .

[12]  Y. Akimov,et al.  Enhancement of optical absorption in thin-film solar cells through the excitation of higher-order nanoparticle plasmon modes. , 2009, Optics express.

[13]  J. Baumberg,et al.  Enhancing solar cells with localized plasmons in nanovoids , 2011, CLEO: 2011 - Laser Science to Photonic Applications.

[14]  G. Whitesides,et al.  Light Trapping in Ultrathin Plasmonic Solar Cells References and Links , 2022 .

[15]  A. Kortan,et al.  Optical studies of single-crystal C60 , 1992 .