Mechanical characterization of the interfacial strength of glass‐reinforced composites

A mechanical test system using a monofilament pullout technique has been utilized to investigate the interfacial bond strength of glass monofilament-epoxy resin composites. The factors influencing the interfacial strength and hydrothermal stability of the glass monofilament-epoxy resin composites have been studied including: varying the amount of thickness of the N-2-aminoethyl-3-aminopropyl trimethoxysilane (AAPS) coupling agent layers between the two substrates of the composite; the debonding effect of moisture and heat as the result of long term exposure; and the partial removal of the deposited silane coupling agent on glass by water, prior to composite preparation. It is found that a critical amount of the bifunctional silane coupling agent is necessary to improve the mechanical strength and hydrothermal stability of the composite interface. Partial removal by washing of the deposited aminosilane on glass, prior to composite preparation, irrespective of its original thickness, enhances the interfacial strength of the composite.

[1]  J. Koenig,et al.  The structure of aminofunctional silane coupling agents: 1. γ-Aminopropyltriethoxysilane and its analogues , 1982 .

[2]  J. Koenig,et al.  Comparison of primary and secondary aminosilance coupling agents in anhuydride‐curde epoxy fiberglass composites , 1981 .

[3]  J. Koenig,et al.  Fourier transform infrared spectroscopic study of the adsorption of multiple amino silane coupling agents on glass surfaces , 1981 .

[4]  J. Koenig,et al.  Irreversible effects of moisture on the epoxy matrix in glass-reinforced composites , 1981 .

[5]  J. Koenig,et al.  A fourier‐transform infrared spectroscopic study of the hydrolytic stability of silane coupling agents on E‐glass fibers , 1980 .

[6]  R. Subramanian,et al.  Silane coupling agents in basalt-reinforced polyester composites , 1980 .

[7]  J. Koenig,et al.  The structure of γ-aminopropyltriethoxysilane on glass surfaces , 1980 .

[8]  J. Koenig,et al.  Effect of hydrolysis and drying on the siloxane bonds of a silane coupling agent deposited on E‐glass fibers , 1980 .

[9]  J. Koenig,et al.  Molecular organization of the coupling agent interphase of fiber‐glass reinforced plastics , 1979 .

[10]  Jack L. Koenig,et al.  An investigation of the coupling agent/matrix interface of fiberglass reinforced plastics by fourier transform infrared spectroscopy , 1979 .

[11]  J. Lenhard,et al.  Chemically Modified Electrodes. IX. X-Ray Photoelectron Spectroscopy of Alkylaminesilanes Bound to Metal Oxide Electrodes. , 1978 .

[12]  J. Koenig,et al.  The reinforcement mechanism of fiber‐glass reinforced plastics under wet conditions: A review , 1978 .

[13]  O. Ishai,et al.  The Effect of Environmental-Loading History on the Transverse Strength of GRP Laminate , 1975 .

[14]  K. Kendall Model experiments illustrating fibre pull-out , 1975 .

[15]  R. Arridge,et al.  The effect of interfacial radial and shear stress on fibre pull-out in composite materials , 1973 .

[16]  A. Blaga,et al.  Mechanism of breakdown in the interface region of glass reinforced polyester by artificial weathering , 1973 .

[17]  J. Koenig,et al.  Raman studies of the glass fiber-silane-resin interface , 1971 .

[18]  M. Schrader Radioisotopic Studies of Bonding at the Interface , 1970 .

[19]  E. Plueddemann Adhesion Through Silane Coupling Agents , 1970 .

[20]  R. C. Wyatt,et al.  Water damage in glass fibre/resin composites , 1969, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[21]  W. Zisman SURFACE CHEMISTRY OF PLASTICS REINFORCED BY STRONG FIBERS , 1969 .

[22]  W. Bascom The wettability of fluoro- and chlorocarbon trialkoxysilane films adsorbed on glass and metal surfaces , 1968 .

[23]  L. Lee Wettability and conformation of reactive polysiloxanes , 1968 .

[24]  F. O. Stark,et al.  Evidence for Chemical Bond Formation at Silane Coupling Agent Interfaces , 1967 .

[25]  A. Kelly,et al.  Tensile properties of fibre-reinforced metals: Copper/tungsten and copper/molybdenum , 1965 .

[26]  A. Jonath New Approach to the Understanding of Adhesive Interface Phenomena and Bond Strength , 1980 .

[27]  J. B. Shortall,et al.  The Interfacial Bond Strength in Glass Fibre-Polyester Resin Composite Systems Part 2. The Effect of Surface Treatment , 1976 .

[28]  P. Dynes,et al.  Interfacial Mechanisms of Moisture Degradation in Graphite-Epoxy Composites , 1975 .

[29]  J. Koenig,et al.  Raman and infrared spectroscopic studies of the reactions of silica and glass surfaces , 1975 .

[30]  P. Lawrence,et al.  Some theoretical considerations of fibre pull-out from an elastic matrix , 1972 .