Crystal structure of N,N-dimethyl-4-((7-nitrobenzo[c][1,2,5]thiadiazol-4-yl)ethynyl)aniline, C16H12N4O2S

<jats:p>C<jats:sub>16</jats:sub>H<jats:sub>12</jats:sub>N<jats:sub>4</jats:sub>O<jats:sub>2</jats:sub>S, triclinic, <jats:italic>P</jats:italic>1̄ (no. 2), <jats:italic>a</jats:italic> = 7.249(2) Å, <jats:italic>b</jats:italic> = 8.265(3) Å, <jats:italic>c</jats:italic> = 12.786(4) Å, <jats:italic>α</jats:italic> = 82.449(11)°, <jats:italic>β</jats:italic> = 75.210(10)°, <jats:italic>γ</jats:italic> = 83.977(11)°, <jats:italic>V</jats:italic> = 732.3(4) Å<jats:sup>3</jats:sup>, <jats:italic>Z</jats:italic> = 2, <jats:italic>R</jats:italic><jats:sub>gt</jats:sub>(<jats:italic>F</jats:italic>) = 0.0669, <jats:italic>wR</jats:italic><jats:sub>ref</jats:sub>(<jats:italic>F</jats:italic><jats:sup>2</jats:sup>) = 0.1726, <jats:italic>T</jats:italic> = 173.15 K.</jats:p>

[1]  Ben Zhong Tang,et al.  Aggregation-induced emission: fundamental understanding and future developments , 2019, Materials Horizons.

[2]  Yulong Duan,et al.  Solvent dependent linear and nonlinear optical properties of triphenylamine unit incorporated difluoroboron β-diketonate complexes , 2019, Dyes and Pigments.

[3]  Chen Songhua,et al.  Crystal structure of 2-(4-(dimethylamino)phenyl)-10-methylacridin-9(10H)-one, C22H20N2O , 2018, Zeitschrift für Kristallographie - New Crystal Structures.

[4]  Chen Songhua,et al.  Crystal structure of 2-bromo-7-(4-(dimethylamino)phenyl)-10-methylacridin-9 (10H)-one, C22H19BrN2O , 2018, Zeitschrift für Kristallographie - New Crystal Structures.

[5]  Zhaoquan Yao,et al.  Multi-Stimuli-Responsive Fluorescence Switching from a Pyridine-Functionalized Tetraphenylethene AIEgen. , 2018, ACS applied materials & interfaces.

[6]  M. Liptak,et al.  Suppression of Kasha's rule as a mechanism for fluorescent molecular rotors and aggregation-induced emission , 2016, Nature Chemistry.

[7]  T. Ebbesen,et al.  Controlling Microsized Polymorphic Architectures with Distinct Linear and Nonlinear Optical Properties , 2015 .

[8]  G. Sheldrick.  SHELXT – Integrated space-group and crystal-structure determination , 2015, Acta crystallographica. Section A, Foundations and advances.

[9]  Yinglin Song,et al.  Aggregation-induced emission on benzothiadiazole dyads with large third-order optical nonlinearity. , 2013, Physical chemistry chemical physics : PCCP.

[10]  Y. Zhao,et al.  Controlling growth of molecular crystal aggregates for efficient optical waveguides. , 2012, Chemical communications.

[11]  Chunjie Zhou,et al.  Crystal Hierarchical Supramolecular Architectures from 1-D Precursor Single-Crystal Seeds , 2010 .

[12]  Richard J. Gildea,et al.  OLEX2: a complete structure solution, refinement and analysis program , 2009 .

[13]  Changshui Huang,et al.  Morphology transition and aggregation-induced emission of an intramolecular charge-transfer compound. , 2008, Langmuir : the ACS journal of surfaces and colloids.