Long-term operation of a compost-based biofilter for biological removal of n-butyl acetate, p-xylene and ammonia gas from an air stream

Abstract An experimental study on the removal of the mixtures of n -butyl acetate ( n -BA), p -xylene ( p -XY) and ammonia gas (NH 3 ) from an air stream was performed in a laboratory scale three-segment biofilter over a period of 4 months. The biofilter was packed with the mixture of mature pig compost, forest soil and a packing material made of polyethylene (PE) which was used in the moving bed biological reactor (MBBR) for treating wastewater. n -BA elimination capacities of 157 and 150 g m −3  h −1 were obtained at empty bed residence time (EBRT) of 60 and 30 s, respectively, corresponding to removal efficiency of approximate 100 and 96%. An approximate 100% removal of NH 3 could be achieved with inlet concentration varying from 0.043 to 0.15 g m −3 at EBRT of 30 and 90 s. For p -XY, the maximal inlet concentration (0.51 g m −3 ) with removal efficiency of 100% at EBRT of 60 s was a little higher than 0.4 g m −3 at EBRT of 90 s due to NH 3 feeding. The pH of the packing media varied in the neutral range (6.5–7.9) during the operation period. The results indicated that the mixtures of n -BA, p -XY and NH 3 were successfully eliminated simultaneously in this biofilter.

[1]  K. Chang,et al.  A Model for the Biofiltration of Butyl Acetate and Xylene Mixtures by a Trickle‐Bed Air Biofilter , 2005 .

[2]  Chungsying Lu,et al.  Effects of pH, moisture, and flow pattern on trickle-bed air biofilter performance for BTEX removal , 2002 .

[3]  P. Cloirec,et al.  Biofiltration of Air Loaded with Ammonia by Granulated Sludge , 2002 .

[4]  J. Dat,et al.  The biofiltration of indoor air: air flux and temperature influences the removal of toluene, ethylbenzene, and xylene. , 2001, Environmental science & technology.

[5]  S. Ottengraf Biological systems for waste gas elimination , 1987 .

[6]  R. Auria,et al.  Influence of water content on degradation rates for ethanol in biofiltration. , 1998, Journal of the Air & Waste Management Association.

[7]  N. J. Kim,et al.  Comparison of organic and inorganic packing materials in the removal of ammonia gas in biofilters. , 2000, Journal of hazardous materials.

[8]  U. Viesturs,et al.  Biodegradation of ammonia by two stage biofiltration system , 1998 .

[9]  Edward H. Smith,et al.  Biofiltration of BTEX contaminated air streams using compost-activated carbon filter media , 1998 .

[10]  Pratim Biswas,et al.  Development of two biomass control strategies for extended, stable operation of highly efficient biofilters with high toluene loadings , 1996 .

[11]  C. Kennes,et al.  Review: Waste gas biotreatment technology , 1998 .

[12]  M. Deshusses,et al.  Biofiltration of high loads of ethyl acetate in the presence of toluene. , 1999, Journal of the Air & Waste Management Association.

[13]  Kerry A. Kinney,et al.  Influence of Nitrogen Supply and Substrate Interactions on the Removal of Paint VOC Mixtures in a Hybrid Bioreactor , 2003 .

[14]  S. Revah,et al.  Start-up and the effect of gaseous ammonia additions on a biofilter for the elimination of toluene vapors. , 1998, Biotechnology and bioengineering.

[15]  Huimin Zhao,et al.  Removal of ternary VOCs in air streams at high loads using a compost-based biofilter , 2005 .

[16]  M. Sanati,et al.  Effects of irrigation and water content of packings on alpha-pinene vapours biofiltration performance , 2005 .

[17]  C. Lu,et al.  Biofiltration of Butyl Acetate and Xylene Mixtures Using a Trickle‐Bed Air Biofilter , 2004 .

[18]  K. Maes,et al.  Abatement of High Concentrated Ammonia Loaded Waste Gases in Compost Biofilters , 2000 .

[19]  Zarook Shareefdeen,et al.  Biofiltration of xylene emissions: bioreactor response to variations in the pollutant inlet concentration and gas flow rate , 2004 .

[20]  B. Striebig,et al.  Nutrient limitations during the biofiltration of methyl isoamyl ketone , 2005 .

[21]  H. Cox,et al.  Influence of the water content and water activity on styrene degradation by Exophiala jeanselmei in biofilters , 1996, Applied Microbiology and Biotechnology.

[22]  D. Grant Allen,et al.  Biofiltration of mixtures of hydrophilic and hydrophobic volatile organic compounds , 2000 .

[23]  R. Corsi,et al.  Biofiltration of BTEX: Media, substrate, and loadings effects , 1995 .

[24]  D. Chang,et al.  Nutrient Limitation in a Compost Biofilter Degrading Hexane. , 2012, Journal of the Air & Waste Management Association.

[25]  R. Taylor,et al.  Thermophilic biodegradation of BTEX by two Thermus Species , 1995, Biotechnology and bioengineering.

[26]  Reza Dehghanzadeh,et al.  Biodegradation of aromatic hydrocarbons in a compost biofilter , 2003 .

[27]  K. Chang,et al.  Biofiltration of butyl acetate by a trickle-bed air biofilter , 2004 .

[28]  Yingxiu Chen,et al.  Long-term operation of biofilters for biological removal of ammonia. , 2005, Chemosphere.

[29]  P. Biswas,et al.  Performance of peat biofilter: impact of the empty bed residence time, temperature and toluene loading , 1997 .

[30]  Chungsying Lu,et al.  Removal of BTEX Vapor from Waste Gases by a Trickle Bed Biofilter , 2000, Journal of the Air & Waste Management Association.