Characteristics of blended cements containing nano-silica

Abstract The aim of the present work is to evaluate the effect of nano-silica (NS) on physico-chemical, compressive and flexural strengths of OPC-granulated slag blended cement pastes and mortars. Different mixes were made with various amounts of NS, OPC and granulated blast-furnace slag (GBFS) and hydrated for 3, 7, 28 and 90 days. The hydration behavior was followed by estimation of free lime (FL) and combined water content at different curing ages. The required water for standard consistency, setting times and compressive strength was also determined. The results obtained were confirmed by XRD, DTA, IR and SEM techniques. The required water for standard consistency and setting times increases with NS content due to the presence of 1% of superplasticizer. As the NS content increases the values of both FL and pH decrease. The compressive and flexural strengths of cement mortars containing NS are higher than those of control OPC–GBFS mix (M3). As the NS content increases above 4 mass% NS, compressive and flexural strengths of OPC–GBFS–NS blends decrease but still more than those of the control samples (M3). The results of XRD, DSC, IR and SEM examinations are in good harmony with each other and with chemical analyses. The composite OPC–GBFS–NS cements containing 45 mass% of GBFS and 3–4 mass% of NS possess the highest improvement of mechanical properties, hydration kinetics and microstructure of hardened cement pastes and mortars.

[1]  M. Stefanidou,et al.  Nanomechanical characterization of cement-based pastes enriched with SiO2 nanoparticles , 2011 .

[2]  A. Nazari,et al.  Splitting tensile strength of concrete using ground granulated blast furnace slag and SiO2 nanoparticles as binder , 2011 .

[3]  Giovanni Andrea Blengini,et al.  The changing role of life cycle phases, subsystems and materials in the LCA of low energy buildings , 2010 .

[4]  P. Yan,et al.  Effect of blended steel slag–GBFS mineral admixture on hydration and strength of cement , 2012 .

[5]  Jong-Bin Park,et al.  Characteristics of cement mortar with nano-SiO2 particles , 2007 .

[6]  Remzi Şahin,et al.  Single and combined effects of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strength and capillary permeability of cement mortar containing silica fume , 2011 .

[7]  R. Siddique Cement Kiln Dust , 2008 .

[8]  Tao Ji,et al.  Preliminary study on the water permeability and microstructure of concrete incorporating nano-SiO2 , 2005 .

[9]  R. Errington Advanced Practical Inorganic and Metalorganic Chemistry , 1997 .

[10]  James Beaudoin,et al.  Cement and Concrete Nanoscience and Nanotechnology , 2010, Materials.

[11]  Alex Williams,et al.  Handbook of analytical techniques , 2001 .

[12]  N. Mostafa Influence of air-cooled slag on physicochemical properties of autoclaved aerated concrete , 2005 .

[13]  J. Bullard,et al.  Characterization and Modeling of Pores and Surfaces in Cement Paste: Correlations to Processing and Properties , 2008 .

[14]  Mohamed Heikal,et al.  Characteristics and durability of cements containing fly ash and limestone subjected to Caron's Lake water , 2009 .

[15]  Konstantin Sobolev,et al.  How Nanotechnology Can Change the Concrete World , 2014 .

[16]  A. Ayuela,et al.  EFFECTS OF NANOSILICA ADDITIONS ON CEMENT PASTES , 2005 .

[17]  Dachamir Hotza,et al.  Mortars with nano-SiO2 and micro-SiO2 investigated by experimental design , 2010 .

[18]  S. Aleem,et al.  Influence of delayed addition time of sodium sulfanilate phenol formaldehyde condensate on the hydration characteristics of sulfate resisting cement pastes containing silica fume , 2012 .

[19]  Alain Sellier,et al.  Hydration of slag-blended cements , 2012 .

[20]  Longtu Li,et al.  A review: The comparison between alkali-activated slag (Si + Ca) and metakaolin (Si + Al) cements , 2010 .

[21]  A. Nazari,et al.  Microstructural, thermal, physical and mechanical behavior of the self compacting concrete containing SiO2 nanoparticles , 2010 .

[22]  Rafat Siddique,et al.  Waste Materials and By-Products in Concrete , 2007 .

[23]  C. Tam,et al.  Analysis of the infrared spectrum and microstructure of hardened cement paste , 1999 .

[24]  Wei Chen,et al.  Hydration of slag cement: theory, modeling and application , 2006 .

[25]  Dachamir Hotza,et al.  Effect of nano-silica on rheology and fresh properties of cement pastes and mortars , 2009 .

[26]  L. Torres-Martínez,et al.  Engineering of SiO 2 Nanoparticles for Optimal Performance in Nano Cement-Based Materials , 2009 .

[27]  Surendra P. Shah,et al.  Nanotechnology of Concrete: Recent Developments and Future Perspectives American Concrete Institute, ACI Special Publication: Preface , 2008 .

[28]  R. Troli,et al.  "Optimization of Silica Fume, Fly Ash and Amorphous Nano-Silica in Superplasticized High-Performance Concrete" , 2004, "SP-221: Eighth CANMET/ACI International Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete".

[29]  M. Aziz,et al.  Hydration and durability of sulphate-resisting and slag cement blends in Caron's Lake water , 2005 .

[30]  Konstantin Sobolev,et al.  How nanotechnology can change the concrete world : Part two of a two-part series , 2005 .

[31]  J. Escalante,et al.  Reactivity of blast-furnace slag in Portland cement blends hydrated under different conditions , 2001 .

[32]  Sanjay Kumar,et al.  Mechanical activation of granulated blast furnace slag and its effect on the properties and structure of portland slag cement , 2008 .

[33]  Surendra P. Shah,et al.  SP-254: Nanotechnology of Concrete: Recent Developments and Future Perspectives , 2008 .

[34]  J. Ou,et al.  Microstructure of cement mortar with nano-particles , 2004 .

[35]  Jueshi Qian,et al.  High performance cementing materials from industrial slags — a review , 2000 .

[36]  N. Roussel,et al.  Properties of fresh and hardened concrete , 2011 .

[37]  Maile Aiu The Chemistry and Physics of Nano-Cement , 2006 .

[38]  Study of the strength of very young concrete as a function of the amount of hydrates formed—influence of superplasticizer , 1994 .

[39]  Aleksandar Matic,et al.  Accelerating effects of colloidal nano-silica for beneficial calcium–silicate–hydrate formation in cement , 2004 .

[40]  Cristina Becchio,et al.  Improving environmental sustainability of concrete products: Investigation on MWC thermal and mechanical properties , 2009 .

[41]  J. Ou,et al.  Flexural fatigue performance of concrete containing nano-particles for pavement , 2007 .

[42]  Ye Qing,et al.  A comparative study on the pozzolanic activity between nano-SiO2 and silica fume , 2006 .

[43]  J. Planell,et al.  Effect of the particle size on the micro and nanostructural features of a calcium phosphate cement: a kinetic analysis. , 2004, Biomaterials.

[44]  J. Labrincha,et al.  Formulation of mortars with nano-SiO2 and nano-TiO2 for degradation of pollutants in buildings , 2013 .

[45]  J. Beaudoin,et al.  Comparison of IR Techniques for the Characterization of Construction Cement Minerals and Hydrated Products , 1996 .

[46]  Tatsuhiko Saeki,et al.  A model to predict the amount of calcium hydroxide in concrete containing mineral admixtures , 2005 .

[47]  Jamal M. Khatib,et al.  Selected engineering properties of concrete incorporating slag and metakaolin , 2005 .

[48]  Gengying Li,et al.  Properties of high-volume fly ash concrete incorporating nano-SiO2 , 2004 .

[49]  S. Aleem,et al.  Physico-chemical and mechanical characteristics of pozzolanic cement pastes and mortars hydrated at different curing temperatures , 2012 .

[50]  F. Pacheco-Torgal,et al.  Nanotechnology: Advantages and drawbacks in the field of construction and building materials , 2011 .

[51]  R. F. Blanks,et al.  The technology of cement and concrete , 1955 .

[52]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[53]  Jeffrey W. Bullard,et al.  Characterization and Modeling of Pores and Surfaces in Cement Paste , 2008 .

[54]  K. Scrivener Nanotechnology and Cementitious Materials , 2009 .

[55]  Y. Qing,et al.  Influence of nano-SiO2 addition on properties of hardened cement paste as compared with silica fume , 2007 .

[56]  H. Brouwers,et al.  Application of nano-silica (nS) in concrete mixtures , 2010 .

[57]  Sergey Vyazovkin,et al.  Thermal analysis. , 2006, Analytical chemistry.

[58]  Kae‐Long Lin,et al.  Effects of nano-SiO(2) and different ash particle sizes on sludge ash-cement mortar. , 2008, Journal of environmental management.

[59]  Michael A. Wilson,et al.  Nanotechnology: Basic Science and Emerging Technologies , 2002 .

[60]  A. Nazari,et al.  THE EFFECTS OF SIO2 NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF HIGH STRENGTH COMPACTING CONCRETE , 2010 .