Organic substances in the subsurface: Delineation, migration, and remediation☆

Abstract The Electric Power Research Institute (EPRI) and Niagara Mohawk Power Corporation are sponsoring a research program concerning the release, transformation, and migration of organic compounds at a site where coal tar from former manufactured gas plant (MGP) operations was disposed nearly thirty years ago. Work at this site, referred to as EBOS Site 24, has included: determination of the location and chemical content of the tarry source material, delineation of the groundwater contaminant plume, evaluation and implementation of innovative methods for sampling and analysis, and the remediation and restoration of the site. The results of the initial phase of research provided several important insights into the mechanisms of contaminant release and migration. For example, the shape of the groundwater contaminant plume at EBOS Site 24 was dominated by longitudinal advection with little contribution from transverse or vertical dispersion. A long-term monitoring program at EBOS Site 24 was initiated prior to the removal of the source material. The results of the baseline groundwater monitoring along the plume centerline were similar to the values predicted using EPRI's MYGRT TM model for migration of contaminants. After the baseline monitoring was completed, all of the tarry source material was removed in 1991 and used in the production of asphalt and portland cement. The groundwater monitoring program will continue for several years and the field results generated during this time will be used to evaluate and/or calibrate the MYGRT TM model.