Classification and adulteration control of vegetable oils based on microwave reflectometry analysis

Abstract Olive oil production represents a big part of the Mediterranean economy, and as such it must be protected from frauds. For this reason, it is necessary to develop alternative low-cost techniques, applicable on large scale, for checking the quality of the product and for detecting adulteration. On such bases, the present work deals with the possibility of adopting microwave reflectometry for obtaining a ‘spectral signature’ of vegetable oils. For this purpose, time domain reflectometry (TDR) measurements, in combination with specific data processing, are first used for the dielectric characterization of several oil types. Successively, the acquired data are processed through the principal component analysis (for identifying clusters of oil types that exhibit common features) and through the partial least square analysis (for identifying a predictive model for detecting oil adulteration). Results confirm that the proposed procedure holds considerable potential for quality and anti-adulteration control purposes, especially in view of practical applications.

[1]  I. Ihara,et al.  Dielectric properties of edible oils and fatty acids , 2008 .

[2]  Luca Catarinucci,et al.  A frequency-domain method for extending TDR performance in quality determination of fluids , 2007 .

[3]  Ashim K. Datta,et al.  Handbook of Microwave Technology for Food Application , 2001 .

[4]  Paul Geladi,et al.  Principal Component Analysis , 1987, Comprehensive Chemometrics.

[5]  G. P. Blanch,et al.  Comparison of different methods for the evaluation of the authenticity of olive oil and hazelnut oil , 1998 .

[6]  Stuart O. Nelson,et al.  Dielectric spectroscopy of wheat from 10 MHz to 1.8 GHz , 2006 .

[7]  John Wood,et al.  Modeling and Characterization of RF and Microwave Power FETs , 2007 .

[8]  J. Danvind PLS prediction as a tool for modeling wood properties , 2002, Holz als Roh- und Werkstoff.

[9]  Willem Bouten,et al.  Accuracy of frequency domain analysis scenarios for the determination of complex dielectric permittivity , 2004 .

[10]  Elena Vittadini,et al.  Differential scanning calorimeter application to the detectionof refined hazelnut oil in extra virgin olive oil. , 2008, Food chemistry.

[11]  R N Clarke,et al.  Traceable measurements of the static permittivity of dielectric reference liquids over the temperature range 5–50 °C , 2005 .

[12]  Stuart O. Nelson,et al.  Measuring frequency- and temperature-dependent permittivities of food materials , 2002, IEEE Trans. Instrum. Meas..

[13]  Luc Martens High-frequency characterization of electronic packaging , 1998 .

[14]  Luigi Ragni,et al.  Assessment of the water content in extra virgin olive oils by Time Domain Reflectometry (TDR) and Partial Least Squares (PLS) regression methods , 2012 .

[15]  Alain Delchambre,et al.  Long-term radiation effects on fibre Bragg grating temperature sensors in a low flux nuclear reactor , 2004 .

[16]  Timo J. Heimovaara,et al.  Dielectric spectroscopy by inverse modelling of time domain reflectometry wave forms. , 1996 .

[17]  Nobuhiro Miura,et al.  Microwave Dielectric Properties of Solid and Liquid Foods Investigated by Time-domain Reflectometry , 2003 .

[18]  Dani Or,et al.  Frequency analysis of time-domain reflectometry (TDR) with application to dielectric spectroscopy of soil constituents , 1999 .

[19]  Willem Bouten,et al.  Obtaining the Spatial Distribution of Water Content along a TDR Probe Using the SCEM‐UA Bayesian Inverse Modeling Scheme , 2004 .

[20]  Hu Lizhi,et al.  Discrimination of olive oil adulterated with vegetable oils using dielectric spectroscopy , 2010 .

[21]  K. Cole,et al.  Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics , 1941 .

[22]  Francesco Addeo,et al.  1H and 13C NMR of virgin olive oil. An overview , 1997 .

[23]  Ali H. El-Hamdy,et al.  Detection of olive oil adulteration by measuring its authenticity factor using reversed-phase high-performance liquid chromatography , 1995 .

[24]  Ulf Edlund,et al.  Prediction of strength parameters for softwood kraft pulps , 1998 .

[25]  Jay P. Gore,et al.  Authentication of Olive Oil Adulterated with Vegetable Oils Using Fourier Transform Infrared Spectroscopy , 2002 .

[26]  G.S.V. Raghavan,et al.  An Overview of Microwave Processing and Dielectric Properties of Agri-food Materials , 2004 .

[27]  Emanuele Piuzzi,et al.  Quality and anti-adulteration control of vegetable oils through microwave dielectric spectroscopy , 2010 .

[28]  Sylwia Mildner-Szkudlarz,et al.  DETECTION OF OLIVE OIL ADULTERATION WITH RAPESEED AND SUNFLOWER OILS USING MOS ELECTRONIC NOSE AND SMPE‐MS , 2010 .

[29]  C. V. D. Berg,et al.  Time-domain reflectometry in carbohydrate solutions , 1995 .

[30]  E. Piuzzi,et al.  Dielectric Spectroscopy of Liquids Through a Combined Approach: Evaluation of the Metrological Performance and Feasibility Study on Vegetable Oils , 2009, IEEE Sensors Journal.

[31]  E. Piuzzi,et al.  Customized system for vegetable oils quality control based on dielectric spectroscopy analysis , 2011, 2011 IEEE International Instrumentation and Measurement Technology Conference.

[32]  Ricard Boqué,et al.  Rapid detection of olive–pomace oil adulteration in extra virgin olive oils from the protected denomination of origin “Siurana” using excitation–emission fluorescence spectroscopy and three-way methods of analysis , 2005 .

[33]  Scott B. Jones,et al.  Frequency Domain Analysis for Extending Time Domain Reflectometry Water Content Measurement in Highly Saline Soils , 2004 .

[34]  Stephen A. Dyer,et al.  Survey of instrumentation and measurement , 2001 .