The Current Status of Hydrogen Storage Alloy Development for Electrochemical Applications

In this review article, the fundamentals of electrochemical reactions involving metal hydrides are explained, followed by a report of recent progress in hydrogen storage alloys for electrochemical applications. The status of various alloy systems, including AB5, AB2, A2B7-type, Ti-Ni-based, Mg-Ni-based, BCC, and Zr-Ni-based metal hydride alloys, for their most important electrochemical application, the nickel metal hydride battery, is summarized. Other electrochemical applications, such as Ni-hydrogen, fuel cell, Li-ion battery, air-metal hydride, and hybrid battery systems, also have been mentioned.

[1]  J. Molenda,et al.  Effect of mechanical milling on electrochemical properties of Ti45Zr38xNi17+x (x = 0, 8) quasicrystals produced by rapid-quenching , 2013 .

[2]  M. Anik,et al.  Development of the high performance magnesium based hydrogen storage alloy , 2012 .

[3]  M. Fetcenko,et al.  Pressure―composition―temperature hysteresis in C14 Laves phase alloys Part 2. Applications in NiMH batteries , 2009 .

[4]  M. Zhao,et al.  Distinct synergistic effect in Ti0.10Zr0.15V0.35Cr0.10Ni0.30 + 1.0 wt.% LaNi5 hydrogen storage composite electrode , 2012 .

[5]  O. Khyzhun,et al.  Photoelectrochemical cell for water decomposition with a hybrid photoanode and a metal-hydride cathode , 2013 .

[6]  M. Fetcenko,et al.  Structural and electrochemical properties of Ti1.5Zr5.5VxNi10−x , 2009 .

[7]  Jinli Huang,et al.  Electrochemical performance of compounds Ho6Fe23−xCox (x=0, 1, 3) , 2011 .

[8]  Y. Cai,et al.  Electrochemical performances of the as-melt La0.75−xMxMg0.25Ni3.2Co0.2Al0.1 (M = Pr, Zr; x = 0, 0.2) alloys applied to Ni/metal hydride (MH) battery , 2012 .

[9]  Jin Guo,et al.  Annealing effect on hydrogen storage property of Co-free La1.8Ti0.2MgNi8.7Al0.3 alloy , 2013 .

[10]  Kuochih Hong The development of hydrogen storage electrode alloys for nickel hydride batteries , 2001 .

[11]  Xiaofen Li,et al.  Electrochemical hydrogen absorbing properties of graphite/AB5 alloy composite electrode , 2012 .

[12]  M. Fetcenko,et al.  Studies of off-stoichiometric AB2 metal hydride alloy: Part 2. Hydrogen storage and electrochemical properties , 2011 .

[13]  Xiao Heng,et al.  NMR Detection of Structures in the HIV-1 5′-Leader RNA That Regulate Genome Packaging , 2011, Science.

[14]  V. Pavlyuk,et al.  The structural, magnetic, hydrogenation and electrode properties of REMg2Cu9−xNix alloys (RE=La, Pr,Tb) , 2011 .

[15]  Yang-huan Zhang,et al.  Electrochemical performances of as-cast and annealed La0.8-xNdxMg0.2Ni3.35Al0.1Si0.05 (x = 0–0.4) alloys applied to Ni/metal hydride (MH) battery , 2013, Rare Metals.

[16]  Limin Wang,et al.  Electrochemical performance of TiVNi-Quasicrystal and AB3-Type hydrogen storage alloy composite materials , 2011 .

[17]  Ma Liqun,et al.  Electrochemical Properties of the Amorphous Ti3Ni2 Alloy in Ni/MH Batteries , 2012 .

[18]  F. Hu,et al.  Influences of melt spinning on electrochemical hydrogen storage performance of nanocrystalline and amorphous Mg2Ni-type alloys , 2011 .

[19]  Tadayoshi Tanaka,et al.  Development of high-capacity nickel-metal hydride batteries using superlattice hydrogen-absorbing alloys , 2006 .

[20]  R. Chassagnon,et al.  Mg2−xTixNi (x = 0, 0.5) alloys prepared by mechanical alloying for electrochemical hydrogen storage: Experiments and first-principles calculations , 2012 .

[21]  J. Joubert,et al.  Influence of the C14 Ti35.4V32.3Fe32.3 Laves phase on the hydrogenation properties of the body-centered cubic compound Ti24.5V59.3Fe16.2 , 2011 .

[22]  Limin Wang,et al.  Influence of heat treatment on electrochemical properties of Ti1.4V0.6Ni alloy electrode containing icosahedral quasicrystalline phase , 2012 .

[23]  D. Northwood,et al.  Electrochemical behaviour of intermetallic-based metal hydrides used in Ni/metal hydride (MH) batteries: a review , 2001 .

[24]  M. Anik,et al.  Effect of Al, B, Ti and Zr additive elements on the electrochemical hydrogen storage performance of , 2011 .

[25]  A. Kulka,et al.  Electrochemical properties of Ti45−xZr30+xNi25 (x = −4, 0, 4) quasicrystal and amorphous electrodes produced by mechanical alloying , 2013 .

[26]  Wenzhuo Shen,et al.  An investigation on phase transformation and electrochemical properties of as-cast and annealed La0.75Mg0.25Nix (x = 3.0, 3.3, 3.5, 3.8) alloys , 2013 .

[27]  K. Young,et al.  Effects of H2O2 addition to the cell balance and self-discharge of Ni/MH batteries with AB5 and A2B7 alloys , 2012 .

[28]  Yunfeng Zhu,et al.  Electrochemical hydrogen storage properties of Mg2−xAlxNi (x = 0, 0.3, 0.5, 0.7) prepared by hydriding combustion synthesis and mechanical milling , 2012 .

[29]  Zhi Zhang,et al.  Microstructures and electrochemical characteristics of La0.7Ce0.3Ni4.2Mn0.9−xCu0.37(V0.81Fe0.19)x hydrogen storage alloys , 2013 .

[30]  Chao Xu,et al.  The electrochemical hydrogen storage performances of Si-added La–Mg–Ni–Co-based A2B7-type electrode alloys , 2015, Rare Metals.

[31]  Y. Cai,et al.  Electrochemical hydrogen storage characteristics of as-cast and annealed La0.8-xNdxMg0.2Ni3.15Co0.2Al0.1Si0.05 (x=0-0.4) alloys , 2013 .

[32]  C. Song,et al.  Enhanced hydrogen storage kinetics of nanocrystalline and amorphous Mg2N-type alloy by substituting Ni with Co , 2011 .

[33]  M. Fetcenko,et al.  The correlation of C14/C15 phase abundance and electrochemical properties in the AB2 alloys , 2010 .

[34]  Zhi Zhang,et al.  Microstructures and electrochemical characteristics of La0.7Ce0.3Ni3.75−xCu0.75Mn0.35Al0.15(V0.81Fe0.19)x (x = 0–0.20) hydrogen storage alloys , 2012 .

[35]  D. Newbury,et al.  Ti12.5Zr21V10Cr8.5MnxCo1.5Ni46.5−x AB2-type metal hydride alloys for electrochemical storage application: Part 1. Structural characteristics , 2012 .

[36]  L. Zhiqiang,et al.  A study on hydrogen storage and electrochemical properties of , 2012 .

[37]  M. Fetcenko,et al.  Compositional optimization of vanadium-free hypo-stoichiometric AB2 metal hydride alloy for Ni/MH battery application , 2012 .

[38]  Jin Guo,et al.  Influence of magnesium on electrochemical properties of RE3–xMgx(Ni0.7Co0.2Mn0.1)9 (x=0.5–1.25) alloy electrodes , 2012 .

[39]  M. Fetcenko,et al.  The structure, hydrogen storage, and electrochemical properties of Fe-doped C14-predominating AB2 metal hydride alloys , 2011 .

[40]  O. Petrii,et al.  Hydrogen-accumulating materials in electrochemical systems , 2007 .

[41]  Suxia Yang,et al.  Effects of annealing treatment on the microstructure and electrochemical properties of low-Co hydrogen storage alloys containing Cu and Fe , 2011 .

[42]  Liqun Ma,et al.  Microstructure and electrochemical hydrogen storage characteristics of (La0.7Mg0.3)1−xCexNi2.8Co0.5 (x = 0–0.20) electrode alloys , 2011 .

[43]  Xiao-ping Dong,et al.  Effect of substitution of aluminum for nickel on electrochemical properties of La0.75Mg0.25Ni3.5−xCo0.2Alx hydrogen storage alloys , 2011 .

[44]  Limin Wang,et al.  Electrochemical properties of Ti-based Quasicrystal and ZrV2 Laves phase alloy composite materials as negative electrode for Ni-MH secondly batteries , 2012 .

[45]  Wang Yan-zhi,et al.  Electrochemical hydrogen storage characteristics of Ti 0 . 10 Zr 0 . 15 V 0 . 35 Cr 0 . 10 Ni 0 . 30 − 10 % LaNi 3 composite and its synergetic effect , 2012 .

[46]  Y. Chai,et al.  Crystal structural and electrochemical properties of Ti0.17Zr0.08V0.35Cr0.10Ni0.30−xMnx (x = 0–0.12) alloys , 2008 .

[47]  M. Anik Effect of Titanium additive element on the discharging behavior of MgNi Alloy electrode , 2011 .

[48]  E. Akiba Hydrogen Absorption by Laves Phase Related BCC Solid Solution Alloys , 1997 .

[49]  Dong-liang Zhao,et al.  Structure and high-temperature electrochemical properties of La0.60Nd0.15Mg0.25Ni3.3Si0.10 hydrogen storage alloys , 2011 .

[50]  K. Young,et al.  Effects of Al- and Mn-contents in the negative MH alloy on the self-discharge and long-term storage properties of Ni/MH battery , 2012 .

[51]  M. Fetcenko,et al.  Studies of off-stoichiometric AB2 metal hydride alloy: Part 1. Structural characteristics , 2011 .

[52]  M. Fetcenko,et al.  Phase abundances in AB2 metal hydride alloys and their correlations to various properties , 2011 .

[53]  M. Fetcenko,et al.  Effects of B, Fe, Gd, Mg, and C on the structure, hydrogen storage, and electrochemical properties of vanadium-free AB2 metal hydride alloy , 2012 .

[54]  Baozhong Liu,et al.  Phase structure and electrochemical properties of La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75-xFex hydrogen storage alloys , 2012 .

[55]  M. Fetcenko,et al.  Studies of Ti1.5Zr5.5V0.5(MxNi1−x)9.5 (M = Cr, Mn, Fe, Co, Cu, Al): Part 1. Structural characteristics , 2010 .

[56]  Xuezhang Xiao,et al.  Influence of heat treatment on the microstructure and hydrogen storage properties of Ti10V77Cr6Fe6Zr alloy , 2012 .

[57]  S. Salley,et al.  Gaseous phase hydrogen storage and electrochemical properties of Zr8Ni21, Zr7Ni10, Zr9Ni11, and ZrNi metal hydride alloys , 2012 .

[58]  F. Kuijpers,et al.  REVERSIBLE ROOM-TEMPERATURE ABSORPTION OF LARGE QUANTITIES OF HYDROGEN BY INTERMETALLIC COMPOUNDS. , 1970 .

[59]  Qiang Li,et al.  Microstructures and electrochemical properties of LaNi3.8–xAlx hydrogen storage alloys , 2013 .

[60]  M. Fetcenko,et al.  Effect of molybdenum content on structural, gaseous storage, and electrochemical properties of C14-predominant AB2 metal hydride alloys , 2011 .

[61]  J. Willems Metal Hydride Electrodes: Stability of LaNi5-Related Compounds , 1986 .

[62]  Lin Hu,et al.  Effect of substituting B for Ni on electrochemical kinetic properties of AB5-type hydrogen storage alloys for high-power nickel/metal hydride batteries , 2011 .

[63]  K. Buschow,et al.  From permanent magnets to rechargeable hydride electrodes , 1987 .

[64]  Liqun Ma,et al.  Cooperative effect of Co and Al on the microstructure and electrochemical properties of AB3-type hydrogen storage electrode alloys for advanced MH/Ni secondary battery , 2011 .

[65]  Baozhong Liu,et al.  Microstructures and electrochemical properties of La0.7Ce0.3Ni3.75−xCu0.75Mn0.35Al0.15(Fe0.43B0.57)x hydrogen storage alloys , 2012 .

[66]  M. Fetcenko,et al.  Pressure–composition–temperature hysteresis in C14 Laves phase alloys: Part 3. Empirical formula , 2009 .

[67]  S. Rousselot,et al.  Comparative study on the structure and electrochemical hydriding properties of MgTi, Mg0.5Ni0.5Ti and MgTi0.5Ni0.5 alloys prepared by high energy ball milling , 2011 .

[68]  Hoda Emami,et al.  Hydrogenation properties of shape memory Ti(Ni,Pd) compounds , 2011 .

[69]  Jian-qiu Deng,et al.  Effect of Al content on structure and electrochemical properties of LaNi4.4 − xCo0.3Mn0.3Alx hydrogen storage alloys , 2013 .

[70]  Yi Cui,et al.  Investigations of the Electrochemical Stability of Aqueous Electrolytes for Lithium Battery Applications , 2010 .

[71]  Wen Hu,et al.  Quinary icosahedral quasicrystalline Ti–V–Ni–Mn–Cr alloy: A novel anode material for Ni-MH rechargeable batteries , 2011 .

[72]  Yuehui He,et al.  Effects of Co3O4 as additive on the performance of metal hydride electrode and Ni–MH battery , 2012 .

[73]  U. Köster,et al.  Thermal stability and hydriding properties of nanocrystalline melt-spun Mg63Ni30Y7 alloy , 1998 .

[74]  M. Fetcenko,et al.  Improvement in the electrochemical properties of gas atomized AB2 metal hydride alloys by hydrogen annealing , 2011 .

[75]  K. Young,et al.  Studies of copper as a modifier in C14-predominant AB2 metal hydride alloys , 2012 .

[76]  S. Salley,et al.  Determination of C14/C15 phase abundance in Laves phase alloys , 2012 .

[77]  Qingqing Zhang,et al.  Electrochemical performances of AB5-type hydrogen storage alloy modified with Co3O4 , 2011 .

[78]  Xiangyu Zhao,et al.  Recent progress in hydrogen storage alloys for nickel/metal hydride secondary batteries , 2009 .

[79]  Yongfeng Liu,et al.  Advanced hydrogen storage alloys for Ni/MH rechargeable batteries , 2011 .

[80]  M. Zhao,et al.  Electrochemical hydrogen storage characteristics of Ti0.10Zr0.15V0.35Cr0.10Ni0.30–10% LaNi3 composite and its synergetic effect , 2012 .

[81]  Ke‐long Huang,et al.  Effect of AB5 alloy on electrochemical properties of Mm0.80Mg0.20Ni2.56Co0.50Mn0.14Al0.12 hydrogen storage alloy , 2012 .

[82]  K. Young,et al.  Studies of Co, Al, and Mn substitutions in NdNi5 metal hydride alloys , 2012 .

[83]  G. Tu,et al.  Investigations on the kinetics properties of the electrochemical reactions of MlNi3.55Co0.75 − xMn0.4Al0.3(Cu0.75P0.25)x (x = 0.0, 0.1, 0.2, 0.3, 0.4) hydrogen storage alloys , 2012 .

[84]  M. Fetcenko,et al.  Improvement in the low-temperature performance of AB5 metal hydride alloys by Fe-addition , 2011 .

[85]  K. Young,et al.  Synergetic effects in electrochemical properties of ZrVxNi4.5−x (x = 0.0, 0.1, 0.2, 0.3, 0.4, and 0.5) metal hydride alloys , 2013 .

[86]  G. Tu,et al.  Study on microstructure and electrochemical performance of the MlNi3.55Co0.75−xMn0.4Al0.3(Cu0.75P0.25)x (x = 0–0.5) composite alloys , 2013 .

[87]  Yang-huan Zhang,et al.  An investigation of hydrogen storage kinetics of melt-spun nanocrystalline and amorphous Mg2Ni-type alloys , 2011 .

[88]  Yihe Zhang,et al.  Effects of annealing treatment and partial substitution of Cu for Co on phase composition and hydrogen storage performance of La0.7Mg0.3Ni3.2Co0.35 alloy , 2012 .

[89]  M. Fetcenko,et al.  Effects of aluminum substitution in C14-rich multi-component alloys for NiMH battery application , 2010 .

[90]  Yang-huan Zhang,et al.  Enhanced Electrochemical Cycle Stability of RE-Mg-Ni System A2B7-Type Alloys by Melt Spinning and Substituting La with Pr , 2011 .

[91]  Wang Dahui,et al.  Research on a New Synthesis Technology of La-Mg-Ni System Alloys and Microstructure of La0.67Mg0.33Ni3.0 Alloys , 2012 .

[92]  Yan Yao,et al.  Electrochemical hydrogen storage properties of a non-equilibrium Ti2Ni alloy , 2012 .

[93]  K. Young,et al.  Effects of annealing and stoichiometry to (Nd, Mg)(Ni, Al)3.5 metal hydride alloys , 2012 .

[94]  Min Zhang,et al.  A first-principles study on elastic properties and stability of TixV1-xC multiple carbide , 2011 .

[95]  M. Fetcenko,et al.  Improvement in high-rate dischargeability, activation, and low-temperature performance in multi-phase AB2 alloys by partial substitution of Zr with Y , 2012 .

[96]  M. Fetcenko,et al.  Electrochemical performance of AB2 metal hydride alloys measured at −40 °C , 2013 .

[97]  H. Drulis,et al.  Thermodynamic and electrochemical hydrogenation properties of LaNi5 − xInx alloys , 2012 .

[98]  F. Wei,et al.  Phase structure and electrochemical properties of La1.7+xMg1.3−x(NiCoMn)9.3(x=0–0.4) hydrogen storage alloys , 2012 .

[99]  Weikang Hu,et al.  Effect of magnesium content and quenching rate on the phase structure and composition of rapidly solidified La2MgNi9 metal hydride battery electrode alloy , 2013 .

[100]  Wang Xinlin,et al.  Enhanced Electrochemical Hydrogen Storage Characteristics of Nanocrystalline and Amorphous Mg20Ni10-xCox (x=0-4) Alloys by Melt Spinning , 2011 .

[101]  M. Anik,et al.  Electrochemical hydrogen storage characteristics of Mg–Pd–Ni ternary alloys , 2011 .

[102]  Weikang Hu,et al.  Annealing effect on phase composition and electrochemical properties of the Co-free La2MgNi9 anode for Ni-metal hydride batteries , 2013 .

[103]  L. Bendersky,et al.  Ti12.5Zr21V10Cr8.5MnxCo1.5Ni46.5−x AB2-type metal hydride alloys for electrochemical storage application: Part 2. Hydrogen storage and electrochemical properties , 2012 .

[104]  Qian Li,et al.  Influence of magnetic annealing on electrochemical performance of La0.67Mg0.33Ni3.0 hydride electrode alloy , 2013 .

[105]  Yunfeng Zhu,et al.  Hydrogen storage properties of Mg–Ni–Fe composites prepared by hydriding combustion synthesis and mechanical milling , 2012 .

[106]  B. Purushothaman,et al.  Analysis of Pressure Variations in a Low-Pressure Nickel-Hydrogen Battery- Part 2: Cells with Metal Hydride Storage. , 2012, Journal of power sources.

[107]  R. Chassagnon,et al.  Synergistic effects of multiwalled carbon nanotubes and Al on the electrochemical hydrogen storage properties of Mg2Ni-type alloy prepared by mechanical alloying , 2012 .

[108]  H. Ewe,et al.  Electrocatalysis in the nickeltitanium system , 1970 .

[109]  Wei Li,et al.  Structural and electrochemical properties of annealed La1-xYxNi3.55Mno.4Alo.3Coo.75 hydrogen storage alloys. , 2011, Journal of environmental sciences.

[110]  Yuehui He,et al.  Effects of pretreatment on MlNi4.00Co0.45Mn0.38Al0.3 hydrogen storage alloy powders and the performance of 6 Ah prismatic traction battery , 2012 .

[111]  Yongguang Wang,et al.  Phase structure and electrochemical properties of La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75−x(Fe0.43B0.57)x hydrogen storage alloys , 2012 .

[112]  Limin Wang,et al.  Ti1.4V0.6Ni quasicrystal and its composites with xV18Ti15Zr18Ni29Cr5Co7Mn alloy used as negative electrode materials for the nickel–metal hydride (Ni–MH) secondary batteries , 2012 .

[113]  Yanzhi Wang,et al.  Electrochemical characteristics and synergetic effect of Ti0.10Zr0.15V0.35Cr0.10Ni0.30-10 wt.%LaNi5 hydrogen storage composite electrode , 2012 .

[114]  S. F. Santos,et al.  Microstructures and electrode performances of Mg50Ni(50-X)Pdx alloys , 2013 .

[115]  Jing-Chie Lin,et al.  Influence of Mg3AlNi2 content on the cycling stability of Mg2Ni–Mg3AlNi2 hydrogen storage alloy electrodes , 2011 .

[116]  Yang-huan Zhang,et al.  Electrochemical hydrogen storage characteristics of nanocrystalline and amorphous Mg2Ni-type alloys prepared by melt-spinning , 2011 .

[117]  Jin Guo,et al.  Effect of annealing treatment on hydrogen storage properties of La-Ti-Mg-Ni-based alloy , 2012 .

[118]  R. K. Upadhyay,et al.  Investigations of AB5-type negative electrode for nickel-metal hydride cell with regard to electrochemical and microstructural characteristics , 2010 .

[119]  A. Takasaki,et al.  Electrochemical properties of Ti45Zr38−xNi17+x (0 ≤ x ≤ 8) quasicrystals produced by rapid-quenching , 2011 .

[120]  M. Fetcenko,et al.  Pressure–composition–temperature hysteresis in C14 Laves phase alloys: Part 1. Simple ternary alloys , 2009 .

[121]  Comparative study of electrochemical performances of the as-melt Mg20Ni10−xMx (M = None, Cu, Co, Mn; x = 0, 4) alloys applied to Ni/metal hydride (MH) battery , 2013 .

[122]  Junli Xu,et al.  Electrochemical hydrogen storage performance of Mg2−xAlxNi thin films , 2012 .

[123]  R. Regmi,et al.  Comparisons of metallic clusters imbedded in the surface oxide of AB2, AB5, and A2B7 alloys , 2010 .

[124]  L. Roué,et al.  On the decrepitation mechanism of MgNi and LaNi 5-based electrodes studied by in situ acoustic emiss , 2011 .

[125]  Chen Yungui,et al.  Improvement in high-temperature performance of Co-free high-Fe AB5-type hydrogen storage alloys , 2012 .

[126]  S. Salley,et al.  Effects of annealing on Zr8Ni19X2 (X = Ni, Mg, Al, Sc, V, Mn, Co, Sn, La, and Hf): Hydrogen storage and electrochemical properties , 2012 .

[127]  S. Salley,et al.  Effects of annealing on Zr8Ni19X2 (X = Ni, Mg, Al, Sc, V, Mn, Co, Sn, La, and Hf): Structural characteristics , 2012 .

[128]  Chan‐Jin Park,et al.  Hydrogen storage and electrochemical properties of the Ti0.32Cr0.43−x−yV0.25FexMny (x = 0–0.055, y = 0–0.080) alloys and their composites with MmNi3.99Al0.29Mn0.3Co0.6 alloy , 2013 .

[129]  L. Roué,et al.  Effect of Ti and Al on the pulverization resistance of MgNi-based metal hydride electrodes evaluated by acoustic emission , 2013 .

[130]  B. Knosp,et al.  Structural and chemical analyses of the new ternary La5MgNi24 phase synthesized by Spark Plasma Sintering and used as negative electrode material for Ni-MH batteries , 2012 .

[131]  J. R. Johnson,et al.  Alloys for hydrogen storage in nickel/hydrogen and nickel/metal hydride batteries , 1994 .

[132]  Zuming Liu,et al.  Enhanced electrochemical performance of Mg2Ni alloy prepared by rapid quenching in magnetic field , 2013 .

[133]  G. Eggeler,et al.  Synthesis and hydriding/dehydriding properties of Mg2Ni–AB (AB = TiNi or TiFe) nanocomposites , 2011 .

[134]  Wenzhuo Shen,et al.  Effects of electroless composite plating Ni–Cu–P on the electrochemical properties of La–Mg–Ni-based hydrogen storage alloy , 2013 .

[135]  Yong-chun Luo,et al.  Phase structures and electrochemical properties of La0.8−xGd0.2MgxNi3.1Co0.3Al0.1 hydrogen storage alloys , 2013 .

[136]  Yongguang Wang,et al.  Microstructures and electrochemical properties of LaNi3.55Co0.2−xMn0.35Al0.15Cu0.75(Fe0.43B0.57)x (x = 0–0.20) hydrogen storage alloys , 2013 .

[137]  M. Fetcenko,et al.  Studies of Ti1.5Zr5.5V0.5(MxNi1−x)9.5 (M = Cr, Mn, Fe, Co, Cu, Al): Part 2. Hydrogen storage and electrochemical properties , 2010 .

[138]  S. Rousselot,et al.  Influence of Pd addition on the electrochemical performance of Mg–Ni–Ti–Al-based metal hydride for Ni–MH batteries , 2013 .

[139]  J. Skowronski,et al.  Electrochemical behavior of metal hydrides , 2001 .

[140]  M. Fetcenko,et al.  Effects of Mo additive on the structure and electrochemical properties of low-temperature AB5 metal hydride alloys , 2011 .

[141]  A. Arenillas,et al.  Electrochemical effect of carbon nanospheres on an AB5 alloy , 2012 .

[142]  M. Fetcenko,et al.  The role of Mn in C14 Laves phase multi-component alloys for NiMH battery application , 2009 .

[143]  E. Higuchi,et al.  Charge–discharge performance of Cr-substituted V-based hydrogen storage alloy negative electrodes for use in nickel-metal hydride batteries , 2012 .

[144]  Zhiqiang Lan,et al.  A study on hydrogen storage and electrochemical properties of La0.55Pr0.05Nd0.15Mg0.25Ni3.5 (Co0.5Al0.5)x (x=0.0, 0.1, 0.3, 0.5) alloys , 2012 .

[145]  K. Young,et al.  Effects of La-addition to the structure, hydrogen storage, and electrochemical properties of C14 metal hydride alloys , 2015 .

[146]  Ping Li,et al.  Structure and electrochemical hydrogen storage characteristics of the as-cast and annealed La0.8-xSmxMg0.2Ni3.15Co0.2Al0.1Si0.05 (x=0-0.4) alloys , 2012 .

[147]  M. Fetcenko,et al.  Study of AB2 alloy electrodes for Ni/MH battery prepared by centrifugal casting and gas atomization , 2010 .

[148]  J. Joubert,et al.  Intermetallic compounds as negative electrodes of Ni/MH batteries , 2001 .

[149]  Jae-Ho Kim,et al.  Effects of Ni-PTFE composite plating on AB5-type hydrogen storage alloy , 2012 .

[150]  Studies of Sn, Co, Al, and Fe additives in C14/C15 Laves alloys for NiMH battery application by orthogonal arrays , 2009 .

[151]  Zhang Guofang,et al.  Electrochemical and Hydrogen Absorption/Desorption Properties of Nanocrystalline Mg2Ni-type Alloys Prepared by Melt Spinning , 2012 .

[152]  K. Nishimura,et al.  Cobalt-free nickel–metal hydride battery for industrial applications , 2013 .

[153]  Q. Peng,et al.  Microstructures and electrochemical hydrogen storage characteristics of La0.7Ce0.3Ni4.2Mn0.9−xCu0.37(Fe0.43B0.57)x (x = 0–0.20) alloys , 2013 .

[154]  Jinwei Wang,et al.  Corrosion Inhibition of LaFe11.6Si1.4 Alloy by BTA/Sodium Benzoate , 2011 .

[155]  Chunfu Lin,et al.  Effect of Mg3MnNi2 on the electrochemical characteristics of Mg2Ni electrode alloy , 2010 .

[156]  Hoda Emami,et al.  Electronic and structural influence of Ni by Pd substitution on the hydrogenation properties of TiNi , 2013 .

[157]  L. Shuhui,et al.  The influence of Co content on LaNi3.2-xMn03Cox (x=0.2∼0.8) Alloy Hydrogen Storage and Electrochemical Properties , 2011 .

[158]  Yongfeng Liu,et al.  Rare earth–Mg–Ni-based hydrogen storage alloys as negative electrode materials for Ni/MH batteries , 2011 .

[159]  M. Fetcenko,et al.  Effect of Sn-substitution in C14 Laves phase alloys for NiMH battery application , 2009 .

[160]  Yuanzhen Chen,et al.  Structure and electrochemical properties of (La1−xDyx)0.8Mg0.2Ni3.4Al0.1 (x = 0.0–0.20) hydrogen storage alloys , 2012 .

[161]  Yuan Li,et al.  Influences of molybdenum substitution for cobalt on the phase structure and electrochemical kinetic properties of AB5-type hydrogen storage alloys , 2011 .

[162]  Limin Wang,et al.  Icosahedral quasicrystalline (Ti1.6V0.4Ni)100−xScx alloys: Synthesis, structure and their application in Ni-MH batteries , 2013 .

[163]  Chen Yang,et al.  Structural and electrochemical hydrogen storage properties of Mg2Ni-based alloys , 2011 .

[164]  Limin Wang,et al.  A composite based on Fe substituted TiVNi alloy: Synthesis, structure and electrochemical hydrogen storage property , 2013 .

[165]  Xiangdong Liu,et al.  Structure and Electrochemical Properties of Rapidly Quenched Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3 Hydrogen Storage Alloy , 2013, Journal of Materials Engineering and Performance.

[166]  K. Young,et al.  Hydrogen storage properties of ZrVxNi3.5−x (x = 0.0–0.9) metal hydride alloys , 2013 .

[167]  W. Boettinger,et al.  Examination of Multiphase (Zr,Ti)(V,Cr,Mn,Ni)2 Ni-MH Electrode Alloys: Part I. Dendritic Solidification Structure , 2010 .

[168]  M. Fetcenko,et al.  Roles of Ni, Cr, Mn, Sn, Co, and Al in C14 Laves phase alloys for NiMH battery application , 2009 .

[169]  Dong-Cheol Yang,et al.  Mechanism for the degradation of MmNi3.9Co0.6Mn0.3Al0.2 electrode and effects of additives on electrode degradation for Ni-MH secondary batteries , 2011 .

[170]  M. Anik Improvement of the electrochemical hydrogen storage performance of magnesium based alloys by various additive elements , 2012 .

[171]  K. Young,et al.  Degradation mechanisms of high-energy bipolar nickel metal hydride battery with AB5 and A2B7 alloys , 2013 .

[172]  M. Fetcenko,et al.  Structural and electrochemical properties of TixZr7−xNi10 , 2009 .

[173]  L. Roué,et al.  In situ investigation of the volume change and pulverization of hydride materials for Ni-MH batteries by concomitant generated force and acoustic emission measurements , 2012 .

[174]  M. Fetcenko,et al.  Annealing effects on structural and electrochemical properties of (LaPrNdZr)0.83Mg0.17(NiCoAlMn)3.3 alloy , 2009 .

[175]  Baozhong Liu,et al.  Microstructure and electrochemical characteristics of La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75-x(V0.81Fe0.19)x hydrogen storage alloys , 2012 .

[176]  M. Fetcenko,et al.  Gas atomization of Cu-modified AB5 metal hydride alloys , 2011 .

[177]  Yongguang Wang,et al.  Microstructures and electrochemical characteristics of LaNi3.70Co0.2-xMn0.30Al0.15Cu0.65(Mo0.46Fe0.54)(x) hydrogen storage alloys , 2015 .

[178]  H. Bor,et al.  Effect of Mg 3 MnNi 2 on the electrochemical characteristics of Mg 2 Ni electrode alloy , 2009 .

[179]  M. Fetcenko,et al.  Optimization of Co-content in C14 Laves phase multi-component alloys for NiMH battery application , 2010 .

[180]  R. Chassagnon,et al.  Structural characterization and electrochemical hydrogen storage properties of Ti2−xZrxNi (x = 0, 0.1, 0.2) alloys prepared by mechanical alloying , 2013 .

[181]  M. Fetcenko,et al.  Structural, thermodynamic, and electrochemical properties of TixZr1−x(VNiCrMnCoAl)2 C14 Laves phase alloys , 2008 .

[182]  Wenzhuo Shen,et al.  Effect of electroplating polyaniline on electrochemical kinetics of La–Mg–Ni-based hydrogen storage alloy , 2012 .

[183]  Chao Xu,et al.  The electrochemical hydrogen storage characteristics of as-spun nanocrystalline and amorphous Mg20Ni10−xMx (M=Cu, Co, Mn; x = 0–4) alloys , 2014, Rare Metals.

[184]  Liqun Ma,et al.  Structure and electrochemical hydrogen storage properties of A2B-type Ti–Zr–Ni alloys , 2012 .

[185]  Yan Yao,et al.  Ti2Ni alloy: a potential candidate for hydrogen storage in nickel/metal hydride secondary batteries , 2010 .

[186]  K. Young,et al.  Improvement in −40 °C electrochemical properties of AB2 metal hydride alloy by silicon incorporation , 2013 .