Prediction of Gray-King coke type from radical concentration and basic properties of coal blends

Abstract Metallurgical coke is mainly produced from coal blends. The coke qualities have been related with or predicted by numerous polynomials with one or a few coal parameters from the proximate and ultimate analyses, maximum vitrinite reflectance (Rmax) and quantity of plastic matters. More fundamental and intrinsic prediction of coke quality, such as that required by artificial intelligence in the future, calls for relations between coke quality and its intermediate state, such as the coke type (CT) determined by the well-known Gray King (GK) assay, and consequently the relations between GKCT with the basic properties of coal blends. This work studies the GKCT of 68 coal blends and predicts the G type coke (G-coke), the best coke form defined by GK, with the parameters from the ultimate and proximate analyses, and the radical concentration (Cr) of coals because Cr is found correlating well with Rmax. The prediction methods include the traditional single- and multi-parameter range (MPR) methods and 3 machine learning models, namely K-Nearest Neighbors (KNN), Linear Discriminant Analysis (LDA), and Support Vector Machine (SVM). It is found that the readily measurable Cr of coals is an important parameter in GKCT prediction. MPR, KNN, LDA and SVM are capable to predict G-coke with no more than 5 parameters, and SVM is more effective than other models.

[1]  Zhenyu Liu,et al.  Heat effects of pyrolysis of 15 acid washed coals in a DSC/TGA-MS system , 2020 .

[2]  H. P. Tiwari,et al.  Effect of Indian Medium Coking Coal on Coke Quality in Non-recovery Stamp Charged Coke Oven , 2014 .

[3]  Chun-Zhu Li,et al.  Effects of volatile–char interactions on in-situ destruction of nascent tar during the pyrolysis and gasification of biomass. Part II. Roles of steam , 2014 .

[4]  Debadi Chakraborty,et al.  Prediction of Coke CSR from Coal Blend Characteristics using Various Techniques: A Comparative Evaluation , 2012 .

[5]  Meiren Shi,et al.  Prediction of coke quality at Baosteel , 2004 .

[6]  Ugur Ozveren,et al.  An artificial intelligence approach to predict gross heating value of lignocellulosic fuels , 2017 .

[7]  M. Seehra,et al.  Free radicals, kinetics and phase changes in the pyrolysis of eight american coals , 1988 .

[8]  S. A. Ryemshak,et al.  Proximate analysis, rheological properties and technological applications of some Nigerian coals , 2013, International Journal of Industrial Chemistry.

[9]  Na Liao,et al.  A rapid and accurate method for on-line measurement of straw-coal blends using near infrared spectroscopy. , 2012, Bioresource technology.

[10]  R. Fisher THE USE OF MULTIPLE MEASUREMENTS IN TAXONOMIC PROBLEMS , 1936 .

[11]  Jixin Qian,et al.  Predicting coal ash fusion temperature based on its chemical composition using ACO-BP neural network , 2007 .

[12]  Christopher J. C. Burges,et al.  A Tutorial on Support Vector Machines for Pattern Recognition , 1998, Data Mining and Knowledge Discovery.

[13]  H. Shui,et al.  Modification of a Sub-bituminous Coal by Hydrothermal Treatment with the Addition of CaO: Extraction and Caking Properties , 2012 .

[14]  Peter E. Hart,et al.  Nearest neighbor pattern classification , 1967, IEEE Trans. Inf. Theory.

[16]  Molecular oxygenates from the thermal degradation of tobacco and material characterization of tobacco char , 2019, Scientific African.

[17]  G. Maciel,et al.  EPR Investigations of Charring and Char/Air Interaction of Cellulose, Pectin, and Tobacco , 2004 .

[18]  Lei Zhang,et al.  Destruction of tar during volatile-char interactions at low temperature. , 2018 .

[19]  Zhenyu Liu,et al.  Behaviors of radical fragments in tar generated from pyrolysis of 4 coals , 2014 .

[20]  H. Shui,et al.  Hydrothermal Treatment of a Sub-bituminous Coal and Its Use in Coking Blends , 2013 .

[21]  R. Friedel,et al.  Electron spin resonance in American coals , 1968 .

[22]  K. Nesbitt,et al.  Methods of coke quality prediction: A review , 2018 .

[23]  Zhenyu Liu,et al.  Electron spin resonance studies of coals and coal conversion processes: A review , 2019, Fuel Processing Technology.

[24]  Zhenyu Liu,et al.  A study on the new type of radicals in corncob derived biochars , 2020 .

[25]  Issouf Fofana,et al.  Measurement of the Relative Free Radical Content of Insulating Oils of Petroleum Origin , 2015 .

[26]  Supriya Ghosh,et al.  Maximisation of non-coking coals in coke production from non-recovery coke ovens , 2008 .

[27]  Daniel W. Davies,et al.  Machine learning for molecular and materials science , 2018, Nature.

[28]  John L. Smith,et al.  A relationship between the carbon and hydrogen content of coals and their vitrinite reflectance , 2007 .

[29]  Chun-Zhu Li Some recent advances in the understanding of the pyrolysis and gasification behaviour of Victorian brown coal , 2007 .

[30]  Ramon Alvarez,et al.  Coal for metallurgical coke production: predictions of coke quality and future requirements for cokemaking , 2002 .

[31]  Marta Skiba,et al.  The application of artificial intelligence for the identification of the maceral groups and mineral components of coal , 2017, Comput. Geosci..

[32]  K. Nesbitt,et al.  Models of coke quality prediction and the relationships to input variables: A review , 2018 .

[33]  M. Diez,et al.  On the relationship between coal plasticity and thermogravimetric analysis , 2003 .

[34]  Zhenyu Liu,et al.  Understanding the stability of pyrolysis tars from biomass in a view point of free radicals. , 2014, Bioresource technology.

[35]  N. Obaje,et al.  Petrographic evaluation of the depositional environments of the Cretaceous Obi/Lafia coal deposits in the Benue trough of Nigeria , 1996 .

[36]  Prakhar Mishra,et al.  Data mining – new perspectives on predicting coke quality in recovery stamp charged coke making process , 2015 .

[37]  H. P. Tiwari,et al.  A novel technique for assessing the coking potential of coals/coal blends for non-recovery coke making process , 2013 .

[38]  Takashi Arima,et al.  Coal blending theory for dry coal charging process , 2004 .

[39]  S. Pusz,et al.  Reflectance parameters of cokes in relation to their reactivity index (CRI) and the strength after reaction (CSR), from coals of the Upper Silesian Coal Basin, Poland , 2012 .

[40]  H. P. Tiwari,et al.  Producing high coke strength after reactivity in stamp charged coke making , 2014, Coke and Chemistry.

[41]  Maria Mastalerz,et al.  ABSTRACT: Quality of Selected Coal Seams from Indiana; Implications for Carbonization , 2001 .

[42]  R. R. Gilyazetdinov,et al.  Predicting CSR and CRI of coke on the basis of the chemical and petrographic parameters of the coal batch and the coking conditions , 2008 .

[43]  Y. Zolotukhin,et al.  Determining the technological value of coal on the basis of coke-quality predictions , 2015, Coke and Chemistry.

[44]  By-Product from Pyrolysis of Tar-Sand in Blend with Gray-King Assessed Nigerian Coals for Coke Production , 2015 .

[45]  Rashmi Singh,et al.  Microtextural analysis of coke from single and binary blend and its impact on coke quality , 2018 .

[46]  A. E. Bazegskiy,et al.  Optimizing coke production at OAO EVRAZ ZSMK on the basis of the available coal , 2013, Coke and Chemistry.

[47]  Arash Tahmasebi,et al.  In-situ study of plastic layers during coking of six Australian coking coals using a lab-scale coke oven , 2019, Fuel Processing Technology.

[48]  S. Nomura The effect of binder (coal tar and pitch) on coking pressure , 2018 .

[49]  Subrajeet Mohapatra,et al.  Machine learning approach for automated coal characterization using scanned electron microscopic images , 2016, Comput. Ind..