Manganese Catalyzed C−H Halogenation Published as part of the Accounts of Chemical Research special issue "Earth Abundant Metals in Homogeneous Catalysis".

[1]  J. Groves,et al.  Targeted fluorination with the fluoride ion by manganese-catalyzed decarboxylation. , 2015, Angewandte Chemie.

[2]  J. Groves,et al.  Manganese-catalyzed late-stage aliphatic C-H azidation. , 2015, Journal of the American Chemical Society.

[3]  T. Lectka,et al.  Photocatalyzed benzylic fluorination: shedding "light" on the involvement of electron transfer. , 2014, Organic letters.

[4]  Steven H. Liang,et al.  C(sp³)-¹⁸F bond formation by transition-metal-based [¹⁸F]fluorination. , 2014, Angewandte Chemie.

[5]  E. Alexanian,et al.  Site-selective aliphatic C-H bromination using N-bromoamides and visible light. , 2014, Journal of the American Chemical Society.

[6]  Choon‐Hong Tan,et al.  Selective fluorination of alkyl C-H bonds via photocatalysis. , 2014, Chemical communications.

[7]  Chuo Chen,et al.  Vanadium-Catalyzed C(sp3)-H Fluorination Reactions. , 2014, Organic chemistry frontiers : an international journal of organic chemistry.

[8]  J. Groves,et al.  Late stage benzylic C-H fluorination with [¹⁸F]fluoride for PET imaging. , 2014, Journal of the American Chemical Society.

[9]  T. Lectka,et al.  A photocatalyzed aliphatic fluorination , 2014 .

[10]  J. Groves Enzymatic C-H bond activation: Using push to get pull. , 2014, Nature chemistry.

[11]  Michael T. Green,et al.  Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C–H Bond Activation by Cytochrome P450 , 2013, Science.

[12]  Chuo Chen,et al.  Visible light-promoted metal-free C-H activation: diarylketone-catalyzed selective benzylic mono- and difluorination. , 2013, Journal of the American Chemical Society.

[13]  J. Groves,et al.  Oxidative aliphatic C-H fluorination with manganese catalysts and fluoride ion , 2013, Nature Protocols.

[14]  J. Groves,et al.  Driving force for oxygen-atom transfer by heme-thiolate enzymes. , 2013, Angewandte Chemie.

[15]  A. Doyle,et al.  Palladium-catalyzed allylic C-H fluorination. , 2013, Journal of the American Chemical Society.

[16]  J. Groves,et al.  Manganese-catalyzed oxidative benzylic C-H fluorination by fluoride ions. , 2013, Angewandte Chemie.

[17]  M. Inoue,et al.  Metal-free fluorination of C(sp3)-H bonds using a catalytic N-oxyl radical. , 2013, Organic letters.

[18]  C. Pitts,et al.  Iron(II)-catalyzed benzylic fluorination. , 2013, Organic letters.

[19]  J. Groves,et al.  Parallel and competitive pathways for substrate desaturation, hydroxylation, and radical rearrangement by the non-heme diiron hydroxylase AlkB. , 2012, Journal of the American Chemical Society.

[20]  David C. Miller,et al.  A polycomponent metal-catalyzed aliphatic, allylic, and benzylic fluorination. , 2012, Angewandte Chemie.

[21]  Eunsung Lee,et al.  Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluoride. , 2012, Journal of the American Chemical Society.

[22]  J. Groves,et al.  Detection and kinetic characterization of a highly reactive heme-thiolate peroxygenase compound I. , 2012, Journal of the American Chemical Society.

[23]  Pierre Kennepohl,et al.  Fluorine transfer to alkyl radicals. , 2012, Journal of the American Chemical Society.

[24]  Eunsung Lee,et al.  A Fluoride-Derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging , 2011, Science.

[25]  J. Groves,et al.  Dissection of the mechanism of manganese porphyrin-catalyzed chlorine dioxide generation. , 2011, Inorganic chemistry.

[26]  T. Ritter,et al.  Catalysis for fluorination and trifluoromethylation , 2011, Nature.

[27]  C. Che,et al.  Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts. , 2011, Chemical Society reviews.

[28]  J. Groves,et al.  Catalytic generation of chlorine dioxide from chlorite using a water-soluble manganese porphyrin. , 2011, Angewandte Chemie.

[29]  Michael T. Green,et al.  Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics , 2010, Science.

[30]  J. Groves,et al.  Manganese porphyrins catalyze selective C-H bond halogenations. , 2010, Journal of the American Chemical Society.

[31]  P. R. Montellano Hydrocarbon hydroxylation by cytochrome P450 enzymes. , 2010 .

[32]  M. White,et al.  Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation , 2010, Science.

[33]  V. Grushin The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination. , 2010, Accounts of chemical research.

[34]  S. Purser,et al.  Fluorine in medicinal chemistry. , 2008, Chemical Society reviews.

[35]  Mohammed Salah Ibrahim,et al.  Trans-dioxo manganese(V) porphyrins. , 2007, Journal of the American Chemical Society.

[36]  P. Ortiz de Montellano,et al.  The diagnostic substrate bicyclohexane reveals a radical mechanism for bacterial cytochrome P450 in whole cells. , 2006, Angewandte Chemie.

[37]  J. Groves,et al.  High-valent iron in chemical and biological oxidations. , 2006, Journal of inorganic biochemistry.

[38]  J. Groves Models and Mechanisms of Cytochrome P450 Action , 2005 .

[39]  Sason Shaik,et al.  Mechanism of oxidation reactions catalyzed by cytochrome p450 enzymes. , 2004, Chemical reviews.

[40]  Harry B Gray,et al.  Oxoiron(IV) in Chloroperoxidase Compound II Is Basic: Implications for P450 Chemistry , 2004, Science.

[41]  C. Cooper,et al.  Nitric oxide synthases: structure, function and inhibition , 2001 .

[42]  M E Phelps,et al.  Positron emission tomography provides molecular imaging of biological processes. , 2000, Proceedings of the National Academy of Sciences of the United States of America.

[43]  J. Groves,et al.  Unusual Kinetic Stability of a Ground-State Singlet Oxomanganese(V) Porphyrin. Evidence for a Spin State Crossing Effect , 1999 .

[44]  A. Gold,et al.  Compound I and Compound II Analogues from Porpholactones. , 1997, Inorganic chemistry.

[45]  J. Groves,et al.  Detection and Characterization of an Oxomanganese(V) Porphyrin Complex by Rapid-Mixing Stopped-Flow Spectrophotometry , 1997 .

[46]  B. Meunier Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage , 1992 .

[47]  S. Rozen Elemental fluorine as a legitimate reagent for selective fluorination of organic compounds , 1988 .

[48]  J. Groves,et al.  Heterolytic and Homolytic O-O Bond Cleavage Reactions of (Acylperoxo)manganese(III) Porphyrins , 1987 .

[49]  J. Collman The organometallic chemistry of transition-metal porphyrin complexes , 1986 .

[50]  O. Bortolini,et al.  Catalytic hydroxylation of saturated hydrocarbons with the sodium hypohalite/manganese porphyrin system , 1985 .

[51]  T. Henly,et al.  Catalytic replacement of unactivated alkane carbon-hydrogen bonds with carbon-X bonds (X = nitrogen, oxygen, chlorine, bromine, or iodine). Coupling of intermolecular hydrocarbon activation by MnIIITPPX complexes with phase-transfer catalysis , 1983 .

[52]  J. Groves,et al.  Mössbauer effect study of tight spin coupling in oxidized chloro-5,10,15,20-tetra(mesityl)porphyrinatoiron(III) , 1983 .

[53]  R. Haushalter,et al.  Hydrocarbon Oxidations with Oxometalloporphinates. Isolation and Reactions of a (Porphinato)manganese(V) Complex , 1981 .

[54]  A. Balch,et al.  Mechanism of autoxidation of iron(II) porphyrins. Detection of a peroxo-bridged iron(III) porphyrin dimer and the mechanism of its thermal decomposition to the oxo-bridged iron(III) porphyrin dimer , 1980 .

[55]  J. Groves,et al.  Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene , 1979 .

[56]  M. J. Coon,et al.  Aliphatic hydroxylation by highly purified liver microsomal cytochrome P-450. Evidence for a carbon radical intermediate. , 1978, Biochemical and biophysical research communications.

[57]  J. Trudell,et al.  Intramolecular determination of primary kinetic isotope effects in hydroxylations catalyzed by cytochrome P-450. , 1977, Biochemical and biophysical research communications.

[58]  John T. Groves,et al.  Reactive iron porphyrin derivatives related to the catalytic cycles of cytochrome P-450 and peroxidase. Studies of the mechanism of oxygen activation , 1988 .

[59]  J. Groves,et al.  Synthesis, characterization, and reactivity of oxomanganese(IV) porphyrin complexes , 1988 .

[60]  J. Groves,et al.  Iron(IV) porphyrins from iron(III) porphyrin cation radicals , 1984 .