Highly Stable Porous Polymer Networks with Exceptionally High Gas‐Uptake Capacities

Figure 1 . a) Synthetic route for PPN-3 (X: Adamantane), PPN-4 (X: Si), PPN-5 (X: Ge), and PAF-1 (X: C). b) The default noninterpenetrated diamondoid network of PPN-4 (black, C; pale grey, H; grey, Si). For several decades, porous materials have been exploited for their applications in gas storage. [ 1 ] Recently, several metal–organic frameworks (MOFs) with high surface area and gas-uptake capacity have been reported. [ 2 ]

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