论文信息 - Linear Chain Compounds of Molybdenum(II) Acetate Dimer Linked by Linear-bidentate Ligands, Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane

Linear Chain Compounds of Molybdenum(II) Acetate Dimer Linked by Linear-bidentate Ligands, Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane

Linear chain compounds, [Mo2(O2CCH3)4·L]n (L = pyrazine, 4,4′-bipyridine, 1,4-diazabicyclo[2.2.2]octane) have been prepared and characterized. The linear chain structure of alternating MO2(O2CCH3)4 units and bridging ligands L was confirmed by an X-ray structural analysis of the bpy complex.

K. Kasamatsu | M. Handa | M. Mikuriya | K. Kasuga | T. Fujii

[1] K. Vollhardt,et al. Models for organometallic polymers. Zigzag chains of tetrakis(acetate)dimolybdenum units linked by bis(dimethylphosphine)ethane and tetramethylethylenediamine ligands , 1990 .

[2] D. Ellis,et al. Spectroscopic and theoretical studies of binuclear molybdenum(II) carboxylates , 1983 .

[3] M. Hanack,et al. Synthesis and Properties of a New Kind of One-Dimensional Conductors 17. Studies on monomeric and polymeric phthalocyaninato-iron(II) and -cobalt(II) complexes , 1982 .

[4] F. Cotton,et al. Molecular and chain structures of four tetrakis(.mu.-propionato)-dirhodium(II) complexes with axial nitrogen-donor ligands , 1981 .

[5] F. Cotton,et al. Pyridine and pyrazine adducts of tetrakis(acetato)dichromium , 1980 .

[6] H. Gray,et al. Electronic spectra and photochemistry of complexes containing quadruple metal-metal bonds , 1978 .

[7] H. Gray,et al. Electronic structure of dimolybdenum tetraformate, dimolybdenum(4+) ion, and dimolybdenum , 1977 .

[8] J. S. Filippo,et al. Raman frequencies of transition metal complexes , 1973 .

[9] F. Cotton,et al. Molybdenum(II) trifluoroacetate dimer. Bispyridine adduct , 1972 .

[10] F. Cotton,et al. VIBRATIONAL STUDIES OF DINUCLEAR COMPOUNDS CONTAINING QUADRUPLY BONDED PAIRS OF MOLYBDENUM AND RHENIUM ATOMS , 1971 .