Synthesis and characterization of ZnO nanoparticles prepared in gelatin media

Abstract Zinc oxide nanoparticles (ZnO-NPs) were synthesized via the sol–gel method in gelatin media. Long-chain gelatin compounds were utilized to terminate the growth of ZnO-NPs and to stabilize them. The ZnO-NPs were characterized by a number of techniques, such as X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR), and high-magnification transmission electron microscopy (TEM). The ZnO-NPs calcined at different temperatures exhibited a hexagonal (wurtzite) structure with sizes from 30 to 60 nm. The influence of the calcination temperature on the morphology of ZnO-NPs was also investigated. The results showed that gelatin is an interesting material that can be used as a stabilizer in the sol–gel technique for preparing small ZnO-NPs.

[1]  Tadatsugu Minami,et al.  Transparent and conductive multicomponent oxide films prepared by magnetron sputtering , 1999 .

[2]  Facile template-free sonochemical fabrication of hollow ZnO spherical structures , 2010 .

[3]  Hao Wang,et al.  Hydrothermal synthesis of zinc oxide powders with controllable morphology , 2004 .

[4]  G. Shi,et al.  A water-soluble cationic oligopyrene derivative : Spectroscopic studies and sensing applications , 2009 .

[5]  Takafumi Yao,et al.  Plasma assisted molecular beam epitaxy of ZnO on c -plane sapphire: Growth and characterization , 1998 .

[6]  W. Hwang,et al.  Synthesis of zinc oxide nanocrystalline powders for cosmetic applications , 2010 .

[7]  Zhidong Zhang,et al.  Characterization and optical properties of ZnO nanoparticles obtained by oxidation of Zn nanoparticles , 2009 .

[8]  Joshua E. Goldberger,et al.  SEMICONDUCTOR NANOWIRES AND NANOTUBES , 2004 .

[9]  R. T. Williams,et al.  Photoluminesence and FTIR study of ZnO nanoparticles: the impurity and defect perspective , 2006 .

[10]  E. Samulski,et al.  Hydrothermal synthesis of one-dimensional ZnO nanostructures with different aspect ratios. , 2004, Chemical communications.

[11]  G. Ho,et al.  Modification of ZnO nanorods through Au nanoparticles surface coating for dye-sensitized solar cells applications , 2010 .

[12]  P. Jajarmi Fabrication of pure ZnO nanoparticles by polymerization method , 2009 .

[13]  Yuan Zhang,et al.  Ag nanoparticle embedded-ZnO nanorods synthesized via a photochemical method and its gas-sensing properties , 2010 .

[14]  A. Morsali,et al.  Synthesis ZnO nanoparticles from a new Zinc(II) coordination polymer precursor , 2010 .

[15]  Meilin Liu,et al.  Reverse micelles template assisted fabrication of ZnO hollow nanospheres and hexagonal microtubes by a novel fast microemulsion-based hydrothermal method , 2010 .

[16]  Y. Liu,et al.  Synthesis and characterization of mercaptoacetic acid-modified ZnO nanoparticles , 2008 .

[17]  Martin Strassburg,et al.  Nitrogen-related local vibrational modes in ZnO:N , 2002 .

[18]  H. Zhai,et al.  Effects of ammonia and cetyltrimethylammonium bromide (CTAB) on morphologies of ZnO nano- and micromaterials under solvothermal process , 2008 .

[19]  E. Wang,et al.  One-step polyoxometalate-assisted solvothermal synthesis of ZnO microspheres and their photoluminescence properties , 2008 .

[20]  Dianzeng Jia,et al.  Facile synthesis of Ag/ZnO nanorods using Ag/C cables as templates and their gas-sensing properties , 2010 .

[21]  Kouhei Hosokawa,et al.  Nanoparticle Technology Handbook , 2009 .

[22]  Quanlin Liu,et al.  Structure and magnetic properties of Mn-doped ZnO nanoparticles , 2005 .