Self-Assembly for Semiconductor Industry

Fabrication technologies for the semiconductor industry have enabled ever-smaller devices but now face fundamental limits in creating nanoscale products. Self-assembly has recently emerged as a promising alternative fabrication technology for functional nanoscale systems. Such processes can be made parallel and are capable of producing three-dimensional structures with ~10 nm precision. This paper reviews developments, applications and challenges of self-assembly methods for the semiconductor industry. Although a fully self-assembled nanoscale system has not yet been commercially achieved, the work reviewed and discussed here demonstrates a solid scientific foundation in pursuing this goal.

[1]  M F Crommie,et al.  Confinement of Electrons to Quantum Corrals on a Metal Surface , 1993, Science.

[2]  G M Whitesides,et al.  Self-assembly of 10-microm-sized objects into ordered three-dimensional arrays. , 2001, Journal of the American Chemical Society.

[3]  G. M. Whitesides,et al.  Templated Self‐Assembly: Formation of Folded Structures by Relaxation of Pre‐stressed, Planar Tapes , 2005 .

[4]  Franco Cerrina,et al.  REVIEW ARTICLE: X-ray imaging: applications to patterning and lithography , 2000 .

[5]  Zhigang Suo,et al.  Dynamics of nanoscale pattern formation of an epitaxial monolayer , 2001 .

[6]  Z. Suo,et al.  Symmetry breaking in self-assembled monolayers on solid surfaces. II. Anisotropic substrate elasticity , 2002 .

[7]  Augustine Urbas,et al.  Bicontinuous Cubic Block Copolymer Photonic Crystals , 2002 .

[8]  Zhiqun Lin,et al.  On the Replication of Block Copolymer Templates by Poly(dimethylsiloxane) Elastomers , 2003 .

[9]  A. Ulman,et al.  Formation and Structure of Self-Assembled Monolayers. , 1996, Chemical reviews.

[10]  John A Rogers,et al.  A photocurable poly(dimethylsiloxane) chemistry designed for soft lithographic molding and printing in the nanometer regime. , 2003, Journal of the American Chemical Society.

[11]  W. Lu,et al.  Design nanocrack patterns in heterogeneous films , 2006 .

[12]  Yanchun Han,et al.  A self-assembly approach to fabricate the patterned colloidal crystals with a tunable structure , 2005 .

[13]  H. L. Stormer,et al.  Four-terminal resistance of a ballistic quantum wire , 2001, Nature.

[14]  Ullrich Steiner,et al.  Hierarchical structure formation and pattern replication induced by an electric field , 2003, Nature materials.

[15]  Dürig,et al.  The “ Millipede ” — More than one thousand tips for future AFM data storage , 2000 .

[16]  Kenneth A. Smith,et al.  Controlled deposition of individual single-walled carbon nanotubes on chemically functionalized templates , 1999 .

[17]  V. Rotello,et al.  Fabrication and characterization of nanoelectrode arrays formed via block copolymer self-assembly , 2001 .

[18]  Shuqing Sun,et al.  Generation of Nanostructures by Scanning Near-Field Photolithography of Self-Assembled Monolayers and Wet Chemical Etching , 2002 .

[19]  Marcus Müller,et al.  Fabrication of complex three-dimensional nanostructures from self-assembling block copolymer materials on two-dimensional chemically patterned templates with mismatched symmetry. , 2006, Physical review letters.

[20]  T. Russell,et al.  Electrically induced structure formation and pattern transfer , 2000, Nature.

[21]  Takayuki Hoshino,et al.  Free-space-wiring fabrication in nano-space by focused-ion-beam chemical vapor deposition , 2003 .

[22]  P. Nealey,et al.  Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates , 2003, Nature.

[23]  George M. Whitesides,et al.  Controlling local disorder in self-assembled monolayers by patterning the topography of their metallic supports , 1998, Nature.

[24]  R. Maboudian,et al.  Self-assembled monolayers as anti-stiction coatings for MEMS: characteristics and recent developments , 2000 .

[25]  F. Švec,et al.  Patternable Protein Resistant Surfaces for Multifunctional Microfluidic Devices via Surface Hydrophilization of Porous Polymer Monoliths Using Photografting , 2006 .

[26]  E. Anderson,et al.  Soft X-ray microscopy at a spatial resolution better than 15 nm , 2005, Nature.

[27]  Yufeng Ma,et al.  Assembly of highly aligned DNA strands onto Si chips. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[28]  S. Asher,et al.  Mesoscopic monodisperse ferromagnetic colloids enable magnetically controlled photonic crystals. , 2002, Journal of the American Chemical Society.

[29]  Qiaobing Xu,et al.  Shear patterning of microdominos: a new class of procedures for making micro- and nanostructures. , 2004, Angewandte Chemie.

[30]  Geoffrey A. Ozin,et al.  Optical Properties of Colloidal Photonic Crystals Confined in Rectangular Microchannels , 2003 .

[31]  George M. Whitesides,et al.  Surface tension-powered self-assembly of microstructures - the state-of-the-art , 2003 .

[32]  Wahyu Setyawan,et al.  Nanotube electronics: Large-scale assembly of carbon nanotubes , 2003, Nature.

[33]  David L. Allara,et al.  A New Class of Organized Self- Assembled Monolayers: Alkane Thiols on GaAs (100) , 1992 .

[34]  R. Vaia,et al.  Effect of electric field on exfoliation of nanoplates , 2006 .

[35]  F. V. Roey,et al.  Introducing 157 nm Full Field Lithography , 2003 .

[36]  T. Ogino,et al.  Strain distribution control on the silicon wafer scale for advanced nanostructure fabrication , 2002 .

[37]  N. Bartelt,et al.  Identifying the forces responsible for self-organization of nanostructures at crystal surfaces , 1999, Nature.

[38]  Tien,et al.  Design and self-assembly of open, regular, 3D mesostructures , 1999, Science.

[39]  T. Weiss,et al.  Scaling behavior of the reorientation kinetics of block copolymers exposed to electric fields. , 2007, Soft matter.

[40]  W. Lu,et al.  Patterning Nanoscale Structures by Surface Chemistry , 2004 .

[41]  Jin Kon Kim,et al.  An optical waveguide study on the nanopore formation in block copolymer/homopolymer thin films by selective solvent swelling. , 2006, The journal of physical chemistry. B.

[42]  Jae Hee Song,et al.  Inorganic semiconductor nanowires: rational growth, assembly, and novel properties. , 2002, Chemistry.

[43]  E. Kramer,et al.  Blends of Poly(methacrylate) Block Copolymers with Photoaddressable Segments , 2007 .

[44]  N. Bartelt,et al.  Nanostructures: Self-assembled domain patterns , 2001, Nature.

[45]  R. Howe,et al.  Fluidic self-assembly of micromirrors onto microactuators using capillary forces , 2002 .

[46]  D. Eigler,et al.  Positioning single atoms with a scanning tunnelling microscope , 1990, Nature.

[47]  D. Allara,et al.  Self-assembly, characterization, and chemical stability of isocyanide-bound molecular wire monolayers on gold and palladium surfaces. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[48]  Daniel Esteve,et al.  Controlled deposition of carbon nanotubes on a patterned substrate , 2000 .

[49]  Joy Cheng,et al.  Formation of a Cobalt Magnetic Dot Array via Block Copolymer Lithography , 2001 .

[50]  Sun,et al.  Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices , 2000, Science.

[51]  Shuqing Sun,et al.  Matching the Resolution of Electron Beam Lithography by Scanning Near-Field Photolithography , 2004 .

[52]  Chad A Mirkin,et al.  Control of nanoparticle assembly by using DNA-modified diatom templates. , 2004, Angewandte Chemie.

[53]  J. Gray,et al.  Kinetic size selection mechanisms in heteroepitaxial quantum dot molecules. , 2004, Physical review letters.

[54]  A. Zayats,et al.  Imaging with short-wavelength surface plasmon polaritons , 2005 .

[55]  Dong Ha Kim,et al.  High-temperature resistant, ordered gold nanoparticle arrays , 2006 .

[56]  Tarek El-Aguizy,et al.  Large-Scale Assembly of Carbon Nanotubes , 2004 .

[57]  Younan Xia,et al.  Optimization of elastomeric phase masks for near-field photolithography , 2001 .

[58]  Ping-Hei Chen,et al.  An ultra sensitive DNA detection by using gold nanoparticle multilayer in nano-gap electrodes , 2005 .

[59]  Kenji Gamo,et al.  Nanofabrication by FIB , 1996 .

[60]  Kenneth Y. Goldberg,et al.  Parallel microassembly with electrostatic force fields , 1998, Proceedings. 1998 IEEE International Conference on Robotics and Automation (Cat. No.98CH36146).

[61]  Chongwu Zhou,et al.  Multilevel memory based on molecular devices , 2004 .

[62]  Younan Xia,et al.  One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications , 2003 .

[63]  Jean M. J. Fréchet,et al.  High surface area nanoporous polymers for reversible hydrogen storage , 2006 .

[64]  Joy Y. Cheng,et al.  Nanostructure engineering by templated self-assembly of block copolymers , 2004, Nature materials.

[65]  George M. Whitesides,et al.  Self-Assembly of 10-μm-Sized Objects into Ordered Three-Dimensional Arrays , 2001 .

[66]  Chengde Mao,et al.  Molecular lithography with DNA nanostructures. , 2004, Angewandte Chemie.

[67]  Ralph G Nuzzo,et al.  Formation and structure of self-assembled monolayers of alkanethiolates on palladium. , 2003, Journal of the American Chemical Society.

[68]  Jeffrey Bokor,et al.  Fabrication of Sub-10-nm Silicon Nanowire Arrays by Size Reduction Lithography , 2003 .

[69]  Qiaobing Xu,et al.  Fabrication of metal structures with nanometer-scale lateral dimensions by sectioning using a microtome. , 2004, Journal of the American Chemical Society.

[70]  Interactions of metallic quantum dots on a semiconductor substrate , 2006 .

[71]  Jiandong Fang,et al.  Controlled multibatch self-assembly of microdevices , 2003 .

[72]  Dynamic in situ characterization of organic monolayer formation via a Novel substrate-mediated mechanism. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[73]  R. Howe,et al.  Modeling of capillary forces and binding sites for fluidic self-assembly , 2001, Technical Digest. MEMS 2001. 14th IEEE International Conference on Micro Electro Mechanical Systems (Cat. No.01CH37090).

[74]  M. Prentiss,et al.  Microlithography by using neutral metastable atoms and self-assembled monolayers , 1995, Science.

[75]  John C. Bean,et al.  Growth of quantum fortress structures in Si1−xGex/Si via combinatorial deposition , 2003 .

[76]  R. Krupke,et al.  Separation of Metallic from Semiconducting Single-Walled Carbon Nanotubes , 2003, Science.

[77]  H. Hatakeyama,et al.  Multiple-chip precise self-aligned assembly for hybrid integrated optical modules using Au-Sn solder bumps , 2001 .

[78]  Alan O'Riordan,et al.  Field Configured Assembly: Programmed Manipulation and Self-assembly at the Mesoscale , 2004 .

[79]  H. Yeh,et al.  Fluidic self-assembly for the integration of GaAs light-emitting diodes on Si substrates , 1994, IEEE Photonics Technology Letters.

[80]  Rashid Bashir,et al.  Dielectrophoresis and electrohydrodynamics-mediated fluidic assembly of silicon resistors , 2003 .

[81]  J. Heath,et al.  Reversible Metal-Insulator Transition in Ordered Metal Nanocrystal Monolayers Observed by Impedance Spectroscopy , 1998 .

[82]  A. Gaur,et al.  Processing dependent behavior of soft imprint lithography on the 1-10-nm scale , 2006, IEEE Transactions on Nanotechnology.

[83]  Paul Zimmerman,et al.  High performance resist for EUV lithography , 2005 .

[84]  Chengde Mao,et al.  DNA-Templated Fabrication of 1D Parallel and 2D Crossed Metallic Nanowire Arrays , 2003 .

[85]  Xu,et al.  "Dip-Pen" nanolithography , 1999, Science.

[86]  T. Russell,et al.  Electrically induced patterning in block copolymer films , 2004 .

[87]  Z. Suo,et al.  Symmetry breaking in self-assembled monolayers on solid surfaces: Anisotropic surface stress , 2002 .

[88]  Yan Liu,et al.  DNA-Templated Self-Assembly of Protein Arrays and Highly Conductive Nanowires , 2003, Science.

[89]  Jonathan S. Lindsey,et al.  Capacitance and conductance characterization of ferrocene-containing self-assembled monolayers on silicon surfaces for memory applications , 2002 .

[90]  Puneet Gupta,et al.  Wafer Topography-Aware Optical Proximity Correction , 2006, IEEE Transactions on Computer-Aided Design of Integrated Circuits and Systems.

[91]  R. Howe,et al.  Microstructure to substrate self-assembly using capillary forces , 2001 .

[92]  M. Meyyappan,et al.  Effect of monolayer order and dynamics on the electronic transport of molecular wires , 2005 .

[93]  Wolfgang Porod,et al.  Quantum cellular automata , 1994 .

[94]  K. Guarini,et al.  Integration of self-assembled diblock copolymers for semiconductor capacitor fabrication , 2001 .

[95]  W. Lu,et al.  Three-dimensional model of electrostatically induced pattern formation in thin polymer films , 2006 .

[96]  Snider,et al.  Digital logic gate using quantum-Dot cellular automata , 1999, Science.

[97]  M. Bohr Nanotechnology goals and challenges for electronic applications , 2002 .

[98]  I. Shimoyama,et al.  Three-dimensional micro-self-assembly using hydrophobic interaction controlled by self-assembled monolayers , 2004, Journal of Microelectromechanical Systems.

[99]  J. Watkins,et al.  Scaling of Interdomain Spacing of Diblock Copolymers in a Selective Diluent , 2007 .

[100]  G. Krausch,et al.  Nanostructured Thin Films via Self‐Assembly of Block Copolymers , 2002 .

[101]  Charles M. Lieber,et al.  Directed assembly of one-dimensional nanostructures into functional networks. , 2001, Science.

[102]  George M Whitesides,et al.  Replication of vertical features smaller than 2 nm by soft lithography. , 2003, Journal of the American Chemical Society.

[103]  M. Stratmann,et al.  Electrochemical and electron spectroscopic investigations of iron surfaces modified with thiols , 1990 .

[104]  Heinrich M. Jaeger,et al.  Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds , 2001, Nature.

[105]  W. Lu,et al.  Pattern formation in a polymer thin film induced by an in-plane electric field , 2004 .

[106]  Nikos Hadjichristidis,et al.  Polymer‐Based Photonic Crystals , 2001 .

[107]  Yu Sun,et al.  Three-dimensional nanosprings for electromechanical sensors , 2005 .

[108]  G. Whitesides,et al.  Self-assembled aggregates of IgGs as templates for the growth of clusters of gold nanoparticles. , 2004, Angewandte Chemie.

[109]  Andrew R. Neureuther,et al.  Phase-shifting mask polarimetry: monitoring polarization at 193-nm high numerical aperture and immersion lithography with phase shifting masks , 2005 .

[110]  Jun Jiao,et al.  Floating-potential dielectrophoresis-controlled fabrication of single-carbon-nanotube transistors and their electrical properties. , 2005, The journal of physical chemistry. B.

[111]  J. Gray,et al.  Hierarchical Self-Assembly of Epitaxial Semiconductor Nanostructures , 2004 .

[112]  F. Favier,et al.  Hydrogen Sensors and Switches from Electrodeposited Palladium Mesowire Arrays , 2001, Science.

[113]  K. Guarini,et al.  Ultrahigh-density nanowire arrays grown in self-assembled diblock copolymer templates. , 2000, Science.

[114]  Wei Lu,et al.  Monolayer pattern evolution via substrate strain-mediated spinodal decomposition. , 2004, Physical review letters.

[115]  Supriyo Datta,et al.  Molecular conductance spectroscopy of conjugated, phenyl-based molecules on Au(111): the effect of end groups on molecular conduction , 2000 .

[116]  G. Whitesides,et al.  Printing, molding, and near-field photolithographic methods for patterning organic lasers, smart pixels and simple circuits , 2000 .

[117]  Combined experimental and theoretical DFT study of molecular nanowires negative differential resistance and interaction with gold clusters , 2005, The European physical journal. E, Soft matter.

[118]  J. Watkins,et al.  Fabrication of Device Nanostructures Using Supercritical Fluids , 2005 .

[119]  Markus Antonietti,et al.  Amphiphilic Block Copolymers in Structure-Controlled Nanomaterial Hybrids , 1998 .

[120]  Y. Zhang,et al.  Directed Assembly of Lamellae‐ Forming Block Copolymers by Using Chemically and Topographically Patterned Substrates , 2007 .

[121]  Babak A. Parviz,et al.  Self-assembled single-crystal silicon circuits on plastic , 2006, Proceedings of the National Academy of Sciences.

[122]  Jean-Marie Lehn,et al.  Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐Organization , 1990 .

[123]  Veena Misra,et al.  Redox-active monolayers on nano-scale silicon electrodes , 2005, Nanotechnology.

[124]  C. Hawker,et al.  Fabrication of densely packed, well-ordered, high-aspect-ratio silicon nanopillars over large areas using block copolymer lithography , 2006 .

[125]  N. Melosh,et al.  Ultrahigh-Density Nanowire Lattices and Circuits , 2003, Science.

[126]  Ginger M. Denison,et al.  High-resolution soft lithography: enabling materials for nanotechnologies. , 2004, Angewandte Chemie.

[127]  Kyung-Man Choi Photopatternable silicon elastomers with enhanced mechanical properties for high-fidelity nanoresolution soft lithography. , 2005, The journal of physical chemistry. B.

[128]  Wei Zheng,et al.  Sequential shape-and-solder-directed self-assembly of functional microsystems. , 2004, Proceedings of the National Academy of Sciences of the United States of America.

[129]  M. Pileni,et al.  Nanocrystal Self-Assemblies: Fabrication and Collective Properties , 2001 .

[130]  W. Lu,et al.  Engineering nanophase self-assembly with elastic field , 2005 .

[131]  T. Ogino,et al.  Wafer-scale strain engineering on silicon for fabrication of ultimately controlled nanostructures , 2003 .

[132]  S. Shi,et al.  Polymer-Based Photonic Crystals , 2005 .

[133]  C. Gorman,et al.  Negative Differential Resistance in Patterned Electroactive Self-Assembled Monolayers , 2001 .

[134]  P. A. Smith,et al.  Electric-field assisted assembly and alignment of metallic nanowires , 2000 .

[135]  Heinrich M. Jaeger,et al.  Overcoming Interfacial Interactions with Electric Fields , 2000 .

[136]  A. Shanzer,et al.  Stable room-temperature molecular negative differential resistance based on molecule-electrode interface chemistry. , 2004, Journal of the American Chemical Society.

[137]  Hong,et al.  A nanoplotter with both parallel and serial writing capabilities , 2000, Science.

[138]  T. Nagata,et al.  GaN nanostructure fabrication by focused-ion-beam-assisted chemical vapor deposition , 2005 .

[139]  A. Dodabalapur,et al.  Organic smart pixels and complementary inverter circuits formed on plastic substrates by casting and rubber stamping , 2000, IEEE Electron Device Letters.